Carbonation of metal silicates for long-term CO2 sequestration
Abstract
In a preferred embodiment, the invention relates to a process of sequestering carbon dioxide. The process comprises the steps of: (a) reacting a metal silicate with a caustic alkali-metal hydroxide to produce a hydroxide of the metal formerly contained in the silicate; (b) reacting carbon dioxide with at least one of a caustic alkali-metal hydroxide and an alkali-metal silicate to produce at least one of an alkali-metal carbonate and an alkali-metal bicarbonate; and (c) reacting the metal hydroxide product of step (a) with at least one of the alkali-metal carbonate and the alkali-metal bicarbonate produced in step (b) to produce a carbonate of the metal formerly contained in the metal silicate of step (a).
- Inventors:
- Issue Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1128516
- Patent Number(s):
- 8673256
- Application Number:
- 13/361,215
- Assignee:
- UT-Battelle, LLC (Oak Ridge, TN); University of Tennessee Research Foundation (Knoxville, TN); Virginia Museum of Natural History (Martinsville, VA)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01F - COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
- DOE Contract Number:
- AC05-00OR22725
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Blencoe, James G, Palmer, Donald A, Anovitz, Lawrence M, and Beard, James S. Carbonation of metal silicates for long-term CO2 sequestration. United States: N. p., 2014.
Web.
Blencoe, James G, Palmer, Donald A, Anovitz, Lawrence M, & Beard, James S. Carbonation of metal silicates for long-term CO2 sequestration. United States.
Blencoe, James G, Palmer, Donald A, Anovitz, Lawrence M, and Beard, James S. Tue .
"Carbonation of metal silicates for long-term CO2 sequestration". United States. https://www.osti.gov/servlets/purl/1128516.
@article{osti_1128516,
title = {Carbonation of metal silicates for long-term CO2 sequestration},
author = {Blencoe, James G and Palmer, Donald A and Anovitz, Lawrence M and Beard, James S},
abstractNote = {In a preferred embodiment, the invention relates to a process of sequestering carbon dioxide. The process comprises the steps of: (a) reacting a metal silicate with a caustic alkali-metal hydroxide to produce a hydroxide of the metal formerly contained in the silicate; (b) reacting carbon dioxide with at least one of a caustic alkali-metal hydroxide and an alkali-metal silicate to produce at least one of an alkali-metal carbonate and an alkali-metal bicarbonate; and (c) reacting the metal hydroxide product of step (a) with at least one of the alkali-metal carbonate and the alkali-metal bicarbonate produced in step (b) to produce a carbonate of the metal formerly contained in the metal silicate of step (a).},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2014},
month = {3}
}
Works referenced in this record:
Progress on binding CO2 in mineral substrates
journal, January 1997
- Lackner, Klaus S.; Butt, Darryl P.; Wendt, Christopher H.
- Energy Conversion and Management, Vol. 38, p. S259-S264
Carbon dioxide sequestration as stable carbonate minerals – environmental barriers
journal, August 2001
- Haywood, H.; Eyre, J.; Scholes, H.
- Environmental Geology, Vol. 41, Issue 1-2, p. 11-16
Mitigation of CO2 by Chemical Conversion: Plausible Chemical Reactions and Promising Products
journal, March 1996
- Xiaoding, Xu; Moulijn, J. A.
- Energy & Fuels, Vol. 10, Issue 2, p. 305-325
Magnesium Hydroxide Dehydroxylation/Carbonation Reaction Processes: Implications for Carbon Dioxide Mineral Sequestration
journal, April 2002
- Béarat, Hamdallah; McKelvy, Michael J.; Chizmeshya, Andrew V. G.
- Journal of the American Ceramic Society, Vol. 85, Issue 4, p. 742-748
Feasibility of CO2 Fixation via Artificial Rock Weathering
journal, September 2001
- Wu, Jeffrey C.-S.; Sheen, Jenn-Der; Chen, Shyan-Yeh
- Industrial & Engineering Chemistry Research, Vol. 40, Issue 18, p. 3902-3905
A new CO2 disposal process via artificial weathering of calcium silicate accelerated by acetic acid
journal, April 2001
- Kakizawa, M.; Yamasaki, A.; Yanagisawa, Y.
- Energy, Vol. 26, Issue 4, p. 341-354
Absorption and fixation of carbon dioxide by rock weathering
journal, January 1997
- Kojima, T.; Nagamine, A.; Ueno, N.
- Energy Conversion and Management, Vol. 38, p. S461-S466
Carbon dioxide disposal in carbonate minerals
journal, January 1995
- Lackner, Klaus S.; Wendt, Christopher H.; Butt, Darryl P.
- Energy, Vol. 20, Issue 11, p. 1153-1170
A Guide to CO2 Sequestration
journal, June 2003
- Lackner, K. S.
- Science, Vol. 300, Issue 5626, p. 1677-1678