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Title: One-step catalytic conversion of biomass-derived carbohydrates to liquid fuels

Abstract

The invention relates to a method for manufacture of hydrocarbon fuels and oxygenated hydrocarbon fuels such as alkyl substituted tetrahydrofurans such as 2,5-dimethyltetrahydrofuran, 2-methyltetrahydrofuran, 5-methylfurfural and mixtures thereof. The method generally entails forming a mixture of reactants that includes carbonaceous material, water, a metal catalyst and an acid reacting that mixture in the presence of hydrogen. The reaction is performed at a temperature and for a time sufficient to produce a furan type hydrocarbon fuel. The process may be adapted to provide continuous manufacture of hydrocarbon fuels such as a furan type fuel.

Inventors:
;
Issue Date:
Research Org.:
Pennsylvania State Univ., University Park, PA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1127128
Patent Number(s):
8674150
Application Number:
12/930,602
Assignee:
Penn State Research Foundation (University Park, PA)
Patent Classifications (CPCs):
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10L - FUELS NOT OTHERWISE PROVIDED FOR
DOE Contract Number:  
FG02-84ER13295
Resource Type:
Patent
Resource Relation:
Patent File Date: 2011 Jan 11
Country of Publication:
United States
Language:
English
Subject:
09 BIOMASS FUELS

Citation Formats

Sen, Ayusman, and Yang, Weiran. One-step catalytic conversion of biomass-derived carbohydrates to liquid fuels. United States: N. p., 2014. Web.
Sen, Ayusman, & Yang, Weiran. One-step catalytic conversion of biomass-derived carbohydrates to liquid fuels. United States.
Sen, Ayusman, and Yang, Weiran. Tue . "One-step catalytic conversion of biomass-derived carbohydrates to liquid fuels". United States. https://www.osti.gov/servlets/purl/1127128.
@article{osti_1127128,
title = {One-step catalytic conversion of biomass-derived carbohydrates to liquid fuels},
author = {Sen, Ayusman and Yang, Weiran},
abstractNote = {The invention relates to a method for manufacture of hydrocarbon fuels and oxygenated hydrocarbon fuels such as alkyl substituted tetrahydrofurans such as 2,5-dimethyltetrahydrofuran, 2-methyltetrahydrofuran, 5-methylfurfural and mixtures thereof. The method generally entails forming a mixture of reactants that includes carbonaceous material, water, a metal catalyst and an acid reacting that mixture in the presence of hydrogen. The reaction is performed at a temperature and for a time sufficient to produce a furan type hydrocarbon fuel. The process may be adapted to provide continuous manufacture of hydrocarbon fuels such as a furan type fuel.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2014},
month = {3}
}

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Works referenced in this record:

Direct, High-Yield Conversion of Cellulose into Biofuel
journal, September 2008


Production of Liquid Alkanes by Aqueous-Phase Processing of Biomass-Derived Carbohydrates
journal, June 2005


Metal Chlorides in Ionic Liquid Solvents Convert Sugars to 5-Hydroxymethylfurfural
journal, June 2007


Production of dimethylfuran for liquid fuels from biomass-derived carbohydrates
journal, June 2007


Simple Chemical Transformation of Lignocellulosic Biomass into Furans for Fuels and Chemicals
journal, February 2009


Effect of particle size based separation of milled corn stover on AFEX pretreatment and enzymatic digestibility
journal, January 2006


Efficient Catalytic System for the Selective Production of 5-Hydroxymethylfurfural from Glucose and Fructose
journal, October 2008


Catalytic Conversion of Biomass to Monofunctional Hydrocarbons and Targeted Liquid-Fuel Classes
journal, October 2008