High permeance sulfur tolerant Pd/Cu alloy membranes
Abstract
A method of making a membrane permeable to hydrogen gas (H.sub.2.uparw.) is disclosed. The membrane is made by forming a palladium layer, depositing a layer of copper on the palladium layer, and galvanically displacing a portion of the copper with palladium. The membrane has improved resistance to poisoning by H.sub.2S compared to a palladium membrane. The membrane also has increased permeance of hydrogen gas compared to palladium-copper alloys. The membrane can be annealed at a lower temperature for a shorter amount of time.
- Inventors:
- Issue Date:
- Research Org.:
- Worcester Polytechnic Institute, Worcester, MA, USA
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1124795
- Patent Number(s):
- 8652239
- Application Number:
- 13/099,688
- Assignee:
- Worcester Polytechnic Institute (Worcester, MA)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
- DOE Contract Number:
- FC26-07NT43058; FG26-04NT42194
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2011 May 03
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Ma, Yi Hua, and Pomerantz, Natalie. High permeance sulfur tolerant Pd/Cu alloy membranes. United States: N. p., 2014.
Web.
Ma, Yi Hua, & Pomerantz, Natalie. High permeance sulfur tolerant Pd/Cu alloy membranes. United States.
Ma, Yi Hua, and Pomerantz, Natalie. Tue .
"High permeance sulfur tolerant Pd/Cu alloy membranes". United States. https://www.osti.gov/servlets/purl/1124795.
@article{osti_1124795,
title = {High permeance sulfur tolerant Pd/Cu alloy membranes},
author = {Ma, Yi Hua and Pomerantz, Natalie},
abstractNote = {A method of making a membrane permeable to hydrogen gas (H.sub.2.uparw.) is disclosed. The membrane is made by forming a palladium layer, depositing a layer of copper on the palladium layer, and galvanically displacing a portion of the copper with palladium. The membrane has improved resistance to poisoning by H.sub.2S compared to a palladium membrane. The membrane also has increased permeance of hydrogen gas compared to palladium-copper alloys. The membrane can be annealed at a lower temperature for a shorter amount of time.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2014},
month = {2}
}
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