High permeance sulfur tolerant Pd/Cu alloy membranes

Title: High permeance sulfur tolerant Pd/Cu alloy membranes

Abstract

A method of making a membrane permeable to hydrogen gas (H.sub.2.uparw.) is disclosed. The membrane is made by forming a palladium layer, depositing a layer of copper on the palladium layer, and galvanically displacing a portion of the copper with palladium. The membrane has improved resistance to poisoning by H.sub.2S compared to a palladium membrane. The membrane also has increased permeance of hydrogen gas compared to palladium-copper alloys. The membrane can be annealed at a lower temperature for a shorter amount of time.

Inventors:: Ma, Yi Hua; Pomerantz, Natalie

Issue Date:: 2014-02-18

Research Org.:: Worcester Polytechnic Institute, Worcester, MA, USA

Sponsoring Org.:: USDOE

OSTI Identifier:: 1124795

Patent Number(s):: 8,652,239

Application Number:: 13/099,688

Assignee:: Worcester Polytechnic Institute (Worcester, MA)

DOE Contract Number:: FC26-07NT43058; FG26-04NT42194

Resource Type:: Patent

Resource Relation:: Patent File Date: 2011 May 03

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Ma, Yi Hua, and Pomerantz, Natalie. High permeance sulfur tolerant Pd/Cu alloy membranes.  United States: N. p., 2014. 
        Web.

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                    Ma, Yi Hua, & Pomerantz, Natalie. High permeance sulfur tolerant Pd/Cu alloy membranes.  United States.

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                    Ma, Yi Hua, and Pomerantz, Natalie. Tue .  
        "High permeance sulfur tolerant Pd/Cu alloy membranes".  United States.  https://www.osti.gov/servlets/purl/1124795.

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@article{osti_1124795,

  title        = {High permeance sulfur tolerant Pd/Cu alloy membranes},

  author       = {Ma, Yi Hua and Pomerantz, Natalie},

  abstractNote = {A method of making a membrane permeable to hydrogen gas (H.sub.2.uparw.) is disclosed. The membrane is made by forming a palladium layer, depositing a layer of copper on the palladium layer, and galvanically displacing a portion of the copper with palladium. The membrane has improved resistance to poisoning by H.sub.2S compared to a palladium membrane. The membrane also has increased permeance of hydrogen gas compared to palladium-copper alloys. The membrane can be annealed at a lower temperature for a shorter amount of time.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2014},

  month        = {2}

}

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Title: High permeance sulfur tolerant Pd/Cu alloy membranes

Abstract

Citation Formats

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Diffusion in copper and copper alloys part IV. Diffusion in systems involving elements of group VIII journal, January 1976

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Kinetics of Electroless Copper Plating journal, January 1981

Kinetics of Electroless Copper Plating journal, January 1980

The Rate of Electroless Copper Depositionby Formaldehyde Reduction journal, January 1974

The relationship between intermetallic diffusion and flux decline in composite-metal membranes: implications for achieving long membrane lifetime journal, November 1995

Electroless plating synthesis, characterization and permeation properties of Pd–Cu membranes supported on ZrO modified porous stainless steel journal, November 2005

Metal Containing Membranes for the Production of Ultrapure Hydrogen and the Recovery of Hydrogen Isotopes journal, October 2000

Preparation and catalysis over palladium composite membranes journal, March 1993

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Pd and Pd–Cu membranes: inhibition of H permeation by HS journal, June 2005

Characterization of Intermetallic Diffusion Barrier and Alloy Formation for Pd/Cu and Pd/Ag Porous Stainless Steel Composite Membranes journal, June 2004

Thin Composite Palladium and Palladium/Alloy Membranes for Hydrogen Separation journal, March 2003

Dependence of hydrogen flux on the pore size and plating surface topology of asymmetric Pd-porous stainless steel membranes journal, September 2002

Defect-free palladium membranes on porous stainless-steel support journal, February 1998

Effect of hydrogen-sulfide on the hydrogen permeance of palladium?copper alloys at elevated temperatures journal, October 2004

Dense inorganic membranes for production of hydrogen from methane and coal with carbon dioxide sequestration journal, October 2006

Hydrogen separation by Pd alloy composite membranes: introduction of diffusion barrier journal, October 2001

Preparation of palladium-coated V and V?15Ni membranes for hydrogen purification by electroless plating technique journal, March 2003

Low-temperature H2 and N2 transport through thin Pd66Cu34Hx layers journal, June 2005

Isothermal solid-state transformation kinetics applied to Pd/Cu alloy membrane fabrication journal, November 2010

Effect of H 2 S on the Performance and Long-Term Stability of Pd/Cu Membranes journal, April 2009

Preparation and characterization of Pd–Cu composite membranes for hydrogen separation journal, May 2003

Influence of Alloy Composition and Membrane Fabrication on the Pressure Dependence of the Hydrogen Flux of Palladium−Copper Membranes journal, November 2003

The influence of alloy composition on the H2 flux of composite PdCu membranes journal, September 2002

Development of membrane reformer system for highly efficient hydrogen production from natural gas journal, May 2009

Structurally stable composite PdAg alloy membranes: Introduction of a diffusion barrier journal, September 1996

Cu-Pd (Copper-Palladium) journal, April 1991

High flux palladium–copper composite membranes for hydrogen separations journal, May 2006

Separation of hydrogen through palladium thin film supported on a porous glass tube journal, March 1991

Hydrogen transport through thin palladium–copper alloy composite membranes at low temperatures journal, February 2008

Membrane reparation and poer size reduction using interfacial ozone assisted chemical vapor deposition
patent, September 1997

Treating gas separation membrane with aqueous reagent dispersion
patent, May 2004

Supported metal membrane, a process for its preparation and use
patent-application, February 2002

Metal gas separation membrane
patent-application, October 2002

Membrane and a Method for Making a Membrane
patent-application, November 2002

Integrated flameless distributed combustion/steam reforming membrane reactor for hydrogen production and use thereof in zero emissions hybrid power system
patent-application, April 2003

Process for Preparing Palladium Alloy Composite Membranes for Use in Hydrogen Separation, Palladium Alloy Composite Membranes and Products Incorporating or Made from the Membranes
patent-application, October 2003

Hydrogen-permeable structure and method for manufacture thereof or repair thereof
patent-application, February 2004

Dense, layered membranes for hydrogen separation
patent-application, July 2004

Composite structure for high efficiency hydrogen separation and its associated methods of manufacture and use
patent-application, December 2004

Composite gas separation modules having a layer of particles with a uniform binder metal distribution
patent-application, January 2006

Porous substrates and arrays comprising the same
patent-application, June 2006

Nanostructures synthesized using anodic aluminum oxide
patent-application, December 2006

Method of fabricating porous AIO2 mold having sub-micro structure
patent-application, June 2008

Composite Structures with Porous Anodic Oxide Layers and Methods of Fabrication
patent-application, June 2010

Method fir Preparing a Palladium-Gold Alloy Gas Separation Membrane System
patent-application, May 2013

Electroless Pd and Ag deposition kinetics of the composite Pd and Pd/Ag membranes synthesized from agitated plating baths
journal, March 2009

Synthesis of composite Pd-porous stainless steel (PSS) membranes with a Pd/Ag intermetallic diffusion barrier
journal, November 2006

High-temperature membranes in power generation with CO₂ capture
journal, September 2004

Diffusion in copper and copper alloys part IV. Diffusion in systems involving elements of group VIII
journal, January 1976

Kinetics of Electroless Copper Plating
journal, January 1980

Kinetics of Electroless Copper Plating
journal, January 1981

Kinetics of Electroless Copper Plating
journal, January 1980

The Rate of Electroless Copper Depositionby Formaldehyde Reduction
journal, January 1974

The relationship between intermetallic diffusion and flux decline in composite-metal membranes: implications for achieving long membrane lifetime
journal, November 1995

Electroless plating synthesis, characterization and permeation properties of Pd–Cu membranes supported on ZrO modified porous stainless steel
journal, November 2005

Metal Containing Membranes for the Production of Ultrapure Hydrogen and the Recovery of Hydrogen Isotopes
journal, October 2000

Preparation and catalysis over palladium composite membranes
journal, March 1993

Leak growth mechanism in composite Pd membranes prepared by the electroless deposition method
journal, January 2008

Microstrains and Stresses Analysis in Electroless Deposited Thin Pd Films
journal, November 2006

Hydrogen permeance of palladium?copper alloy membranes over a wide range of temperatures and pressures
journal, October 2004

Stability and hydrogen permeation behavior of supported platinum membranes in presence of hydrogen sulfide
journal, September 1999

Pd and Pd–Cu membranes: inhibition of H permeation by HS
journal, June 2005

Characterization of Intermetallic Diffusion Barrier and Alloy Formation for Pd/Cu and Pd/Ag Porous Stainless Steel Composite Membranes
journal, June 2004

Thin Composite Palladium and Palladium/Alloy Membranes for Hydrogen Separation
journal, March 2003

Dependence of hydrogen flux on the pore size and plating surface topology of asymmetric Pd-porous stainless steel membranes
journal, September 2002

Defect-free palladium membranes on porous stainless-steel support
journal, February 1998

Effect of hydrogen-sulfide on the hydrogen permeance of palladium?copper alloys at elevated temperatures
journal, October 2004

Dense inorganic membranes for production of hydrogen from methane and coal with carbon dioxide sequestration
journal, October 2006

Hydrogen separation by Pd alloy composite membranes: introduction of diffusion barrier
journal, October 2001

Preparation of palladium-coated V and V?15Ni membranes for hydrogen purification by electroless plating technique
journal, March 2003

Low-temperature H₂ and N₂ transport through thin Pd₆₆Cu₃₄H_x layers
journal, June 2005

Isothermal solid-state transformation kinetics applied to Pd/Cu alloy membrane fabrication
journal, November 2010

Effect of H ₂ S on the Performance and Long-Term Stability of Pd/Cu Membranes
journal, April 2009

Preparation and characterization of Pd–Cu composite membranes for hydrogen separation
journal, May 2003

Influence of Alloy Composition and Membrane Fabrication on the Pressure Dependence of the Hydrogen Flux of Palladium−Copper Membranes
journal, November 2003

The influence of alloy composition on the H₂ flux of composite PdCu membranes
journal, September 2002

Development of membrane reformer system for highly efficient hydrogen production from natural gas
journal, May 2009

Structurally stable composite PdAg alloy membranes: Introduction of a diffusion barrier
journal, September 1996

Cu-Pd (Copper-Palladium)
journal, April 1991

High flux palladium–copper composite membranes for hydrogen separations
journal, May 2006

Separation of hydrogen through palladium thin film supported on a porous glass tube
journal, March 1991

Hydrogen transport through thin palladium–copper alloy composite membranes at low temperatures
journal, February 2008