Hydrogen production using ammonia borane
Abstract
Hydrogen ("H.sub.2") is produced when ammonia borane reacts with a catalyst complex of the formula L.sub.nM-X wherein M is a base metal such as iron, X is an anionic nitrogen- or phosphorus-based ligand or hydride, and L is a neutral ancillary ligand that is a neutral monodentate or polydentate ligand.
- Inventors:
- Issue Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1111472
- Patent Number(s):
- 8613902
- Application Number:
- 12/416,835
- Assignee:
- Los Alamos National Security, LLC (Los Alamos, NM)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- DOE Contract Number:
- AC52-06NA25396
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 08 HYDROGEN
Citation Formats
Hamilton, Charles W, Baker, R. Thomas, Semelsberger, Troy A, and Shrestha, Roshan P. Hydrogen production using ammonia borane. United States: N. p., 2013.
Web.
Hamilton, Charles W, Baker, R. Thomas, Semelsberger, Troy A, & Shrestha, Roshan P. Hydrogen production using ammonia borane. United States.
Hamilton, Charles W, Baker, R. Thomas, Semelsberger, Troy A, and Shrestha, Roshan P. Tue .
"Hydrogen production using ammonia borane". United States. https://www.osti.gov/servlets/purl/1111472.
@article{osti_1111472,
title = {Hydrogen production using ammonia borane},
author = {Hamilton, Charles W and Baker, R. Thomas and Semelsberger, Troy A and Shrestha, Roshan P},
abstractNote = {Hydrogen ("H.sub.2") is produced when ammonia borane reacts with a catalyst complex of the formula L.sub.nM-X wherein M is a base metal such as iron, X is an anionic nitrogen- or phosphorus-based ligand or hydride, and L is a neutral ancillary ligand that is a neutral monodentate or polydentate ligand.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2013},
month = {12}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Efficient Catalysis of Ammonia Borane Dehydrogenation
journal, September 2006
- Denney, Melanie C.; Pons, Vincent; Hebden, Travis J.
- Journal of the American Chemical Society, Vol. 128, Issue 37
Amineborane-Based Chemical Hydrogen Storage: Enhanced Ammonia Borane Dehydrogenation in Ionic Liquids
journal, June 2006
- Bluhm, Martin E.; Bradley, Mark G.; Butterick, Robert
- Journal of the American Chemical Society, Vol. 128, Issue 24
Process for preparing optically active cyclohexanol derivatives
patent, May 1998
- Murayama, Toshiyuki; Matsumoto, Takaji; Miura, Takashi
- US Patent Document 5,756,863
Acid Initiation of Ammonia–Borane Dehydrogenation for Hydrogen Storage
journal, January 2007
- Stephens, Frances H.; Baker, R. Tom; Matus, Myrna H.
- Angewandte Chemie International Edition, Vol. 46, Issue 5
Thermal decomposition of B–N–H compounds investigated by using combined thermoanalytical methods
journal, August 2002
- Baitalow, F.; Baumann, J.; Wolf, G.
- Thermochimica Acta, Vol. 391, Issue 1-2
4-methoxybiphenyl hydrazone derivatives
patent, March 2004
- Park, Sheldon B.; Chee, Gaik-Lean; Dekeyser, Mark A.
- US Patent Document 6,706,895
Base Metal Catalyzed Dehydrogenation of Ammonia−Borane for Chemical Hydrogen Storage
journal, February 2007
- Keaton, Richard J.; Blacquiere, Johanna M.; Baker, R. Tom
- Journal of the American Chemical Society, Vol. 129, Issue 7
Transition Metal-Catalyzed Formation of Boron−Nitrogen Bonds: Catalytic Dehydrocoupling of Amine-Borane Adducts to Form Aminoboranes and Borazines
journal, August 2003
- Jaska, Cory A.; Temple, Karen; Lough, Alan J.
- Journal of the American Chemical Society, Vol. 125, Issue 31
The Metal−Ligand Bifunctional Catalysis: A Theoretical Study on the Ruthenium(II)-Catalyzed Hydrogen Transfer between Alcohols and Carbonyl Compounds
journal, February 2000
- Yamakawa, Masashi; Ito, Hisashi; Noyori, Ryoji
- Journal of the American Chemical Society, Vol. 122, Issue 7
Hydrogen storage material and related processes
patent, July 2010
- Soloveichik, Grigorii Lev; Andrus, Matthew John
- US Patent Document 7,754,641
Ruthenium-Catalyzed Dehydrogenation of Ammonia Boranes
journal, October 2008
- Blaquiere, Nicole; Diallo-Garcia, Sarah; Gorelsky, Serge I.
- Journal of the American Chemical Society, Vol. 130, Issue 43
Ruthenium Complexes with Cooperative PNP Ligands: Bifunctional Catalysts for the Dehydrogenation of Ammonia-Borane
journal, January 2009
- Käß, Martina; Friedrich, Anja; Drees, Markus
- Angewandte Chemie International Edition, Vol. 48, Issue 5