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Title: Iron-sulfide redox flow batteries

Abstract

Iron-sulfide redox flow battery (RFB) systems can be advantageous for energy storage, particularly when the electrolytes have pH values greater than 6. Such systems can exhibit excellent energy conversion efficiency and stability and can utilize low-cost materials that are relatively safer and more environmentally friendly. One example of an iron-sulfide RFB is characterized by a positive electrolyte that comprises Fe(III) and/or Fe(II) in a positive electrolyte supporting solution, a negative electrolyte that comprises S.sup.2- and/or S in a negative electrolyte supporting solution, and a membrane, or a separator, that separates the positive electrolyte and electrode from the negative electrolyte and electrode.

Inventors:
; ; ; ; ;
Issue Date:
Research Org.:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1111112
Patent Number(s):
8609270
Application Number:
13/071,688
Assignee:
Battelle Memorial Institute (Richland, WA)
Patent Classifications (CPCs):
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Xia, Guan-Guang, Yang, Zhenguo, Li, Liyu, Kim, Soowhan, Liu, Jun, and Graff, Gordon L. Iron-sulfide redox flow batteries. United States: N. p., 2013. Web.
Xia, Guan-Guang, Yang, Zhenguo, Li, Liyu, Kim, Soowhan, Liu, Jun, & Graff, Gordon L. Iron-sulfide redox flow batteries. United States.
Xia, Guan-Guang, Yang, Zhenguo, Li, Liyu, Kim, Soowhan, Liu, Jun, and Graff, Gordon L. Tue . "Iron-sulfide redox flow batteries". United States. https://www.osti.gov/servlets/purl/1111112.
@article{osti_1111112,
title = {Iron-sulfide redox flow batteries},
author = {Xia, Guan-Guang and Yang, Zhenguo and Li, Liyu and Kim, Soowhan and Liu, Jun and Graff, Gordon L},
abstractNote = {Iron-sulfide redox flow battery (RFB) systems can be advantageous for energy storage, particularly when the electrolytes have pH values greater than 6. Such systems can exhibit excellent energy conversion efficiency and stability and can utilize low-cost materials that are relatively safer and more environmentally friendly. One example of an iron-sulfide RFB is characterized by a positive electrolyte that comprises Fe(III) and/or Fe(II) in a positive electrolyte supporting solution, a negative electrolyte that comprises S.sup.2- and/or S in a negative electrolyte supporting solution, and a membrane, or a separator, that separates the positive electrolyte and electrode from the negative electrolyte and electrode.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2013},
month = {12}
}

Works referenced in this record:

Electrically rechargeable battery
patent, December 1979


A comparative study of carbon felt and activated carbon based electrodes for sodium polysulfide/bromine redox flow battery
journal, September 2006


Ion conducting electrolyte brush additives
patent, July 2009


Battery with bifunctional electrolyte
patent-application, March 2006


Concentration cell energy storage device
patent-application, September 2010