Polymer compositions, polymer films and methods and precursors for forming same

Klaehn, John R; Peterson, Eric S; Orme, Christopher J

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A - human necessities
A01 - agriculture
A21 - baking
A22 - butchering
A23 - foods or foodstuffs
A24 - tobacco
A41 - wearing apparel
A42 - headwear
A43 - footwear
A44 - haberdashery
A45 - hand or travelling articles
A46 - brushware
A47 - furniture
A61 - medical or veterinary science
A62 - life-saving
A63 - sports
A99 - subject matter not otherwise provided for in this section
B - performing operations
B01 - physical or chemical processes or apparatus in general
B02 - crushing, pulverising, or disintegrating
B03 - separation of solid materials using liquids or using pneumatic tables or jigs
B04 - centrifugal apparatus or machines for carrying-out physical or chemical processes
B05 - spraying or atomising in general
B06 - generating or transmitting mechanical vibrations in general
B07 - separating solids from solids
B08 - cleaning
B09 - disposal of solid waste
B21 - mechanical metal-working without essentially removing material
B22 - casting
B23 - machine tools
B24 - grinding
B25 - hand tools
B26 - hand cutting tools
B27 - working or preserving wood or similar material
B28 - working cement, clay, or stone
B29 - working of plastics
B30 - presses
B31 - making articles of paper, cardboard or material worked in a manner analogous to paper
B32 - layered products
B33 - additive manufacturing technology
B41 - printing
B42 - bookbinding
B43 - writing or drawing implements
B44 - decorative arts
B60 - vehicles in general
B61 - railways
B62 - land vehicles for travelling otherwise than on rails
B63 - ships or other waterborne vessels
B64 - aircraft
B65 - conveying
B66 - hoisting
B67 - opening, closing {or cleaning} bottles, jars or similar containers
B68 - saddlery
B81 - microstructural technology
B82 - nanotechnology
B99 - subject matter not otherwise provided for in this section
C - chemistry
C01 - inorganic chemistry
C02 - treatment of water, waste water, sewage, or sludge
C03 - glass
C04 - cements
C05 - fertilisers
C06 - explosives
C07 - organic chemistry
C08 - organic macromolecular compounds
C09 - dyes
C10 - petroleum, gas or coke industries
C11 - animal or vegetable oils, fats, fatty substances or waxes
C12 - biochemistry
C13 - sugar industry
C14 - skins
C21 - metallurgy of iron
C22 - metallurgy
C23 - coating metallic material
C25 - electrolytic or electrophoretic processes
C30 - crystal growth
C40 - combinatorial technology
C99 - subject matter not otherwise provided for in this section
D - textiles
D01 - natural or man-made threads or fibres
D02 - yarns
D03 - weaving
D04 - braiding
D05 - sewing
D06 - treatment of textiles or the like
D07 - ropes
D10 - indexing scheme associated with sublasses of section d, relating to textiles
D21 - paper-making
D99 - subject matter not otherwise provided for in this section
E - fixed constructions
E01 - construction of roads, railways, or bridges
E02 - hydraulic engineering
E03 - water supply
E04 - building
E05 - locks
E06 - doors, windows, shutters, or roller blinds in general
E21 - earth drilling
E99 - subject matter not otherwise provided for in this section
F - mechanical engineering
F01 - machines or engines in general
F02 - combustion engines
F03 - machines or engines for liquids
F04 - positive - displacement machines for liquids
F05 - indexing schemes relating to engines or pumps in various subclasses of classes f01-f04
F15 - fluid-pressure actuators
F16 - engineering elements and units
F17 - storing or distributing gases or liquids
F21 - lighting
F22 - steam generation
F23 - combustion apparatus
F24 - heating
F25 - refrigeration or cooling
F26 - drying
F27 - furnaces
F28 - heat exchange in general
F41 - weapons
F42 - ammunition
F99 - subject matter not otherwise provided for in this section
G - physics
G01 - measuring
G02 - optics
G03 - photography
G04 - horology
G05 - controlling
G06 - computing
G07 - checking-devices
G08 - signalling
G09 - education
G10 - musical instruments
G11 - information storage
G12 - instrument details
G16 - information and communication technology [ict] specially adapted for specific application fields
G21 - nuclear physics
G99 - subject matter not otherwise provided for in this section
H - electricity
H01 - basic electric elements
H02 - generation
H03 - basic electronic circuitry
H04 - electric communication technique
H05 - electric techniques not otherwise provided for
H99 - subject matter not otherwise provided for in this section
Y - new / cross sectional technologies
Y02 - technologies or applications for mitigation or adaptation against climate change
Y04 - information or communication technologies having an impact on other technology areas
Y10 - technical subjects covered by former uspc

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Title: Polymer compositions, polymer films and methods and precursors for forming same

Abstract

Stable, high performance polymer compositions including polybenzimidazole (PBI) and a melamine-formaldehyde polymer, such as methylated, poly(melamine-co-formaldehyde), for forming structures such as films, fibers and bulky structures. The polymer compositions may be formed by combining polybenzimidazole with the melamine-formaldehyde polymer to form a precursor. The polybenzimidazole may be reacted and/or intertwined with the melamine-formaldehyde polymer to form the polymer composition. For example, a stable, free-standing film having a thickness of, for example, between about 5 .mu.m and about 30 .mu.m may be formed from the polymer composition. Such films may be used as gas separation membranes and may be submerged into water for extended periods without crazing and cracking. The polymer composition may also be used as a coating on substrates, such as metal and ceramics, or may be used for spinning fibers. Precursors for forming such polymer compositions are also disclosed.

Inventors:: Klaehn, John R; Peterson, Eric S; Orme, Christopher J

Issue Date:: 2013-09-24

Research Org.:: Idaho National Laboratory (INL), Idaho Falls, ID (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1096017

Patent Number(s):: 8541517

Application Number:: 13/045,195

Assignee:: Battelle Energy Alliance, LLC (Idaho Falls, ID)

Patent Classifications (CPCs):: C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08L - COMPOSITIONS OF MACROMOLECULAR COMPOUNDS

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

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C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08L - COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
C08L61/28 - with melamine
C08L79/04 - Polycondensates having nitrogen-containing heterocyclic rings in the main chain

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T428/31862 - Melamine-aldehyde

Show less

DOE Contract Number:: AC07-05ID14517

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Klaehn, John R, Peterson, Eric S, and Orme, Christopher J. Polymer compositions, polymer films and methods and precursors for forming same.  United States: N. p., 2013. 
        Web.

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                    Klaehn, John R, Peterson, Eric S, & Orme, Christopher J. Polymer compositions, polymer films and methods and precursors for forming same.  United States.

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                    Klaehn, John R, Peterson, Eric S, and Orme, Christopher J. Tue .  
        "Polymer compositions, polymer films and methods and precursors for forming same".  United States.  https://www.osti.gov/servlets/purl/1096017.

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@article{osti_1096017,

  title        = {Polymer compositions, polymer films and methods and precursors for forming same},

  author       = {Klaehn, John R and Peterson, Eric S and Orme, Christopher J},

  abstractNote = {Stable, high performance polymer compositions including polybenzimidazole (PBI) and a melamine-formaldehyde polymer, such as methylated, poly(melamine-co-formaldehyde), for forming structures such as films, fibers and bulky structures. The polymer compositions may be formed by combining polybenzimidazole with the melamine-formaldehyde polymer to form a precursor. The polybenzimidazole may be reacted and/or intertwined with the melamine-formaldehyde polymer to form the polymer composition. For example, a stable, free-standing film having a thickness of, for example, between about 5 .mu.m and about 30 .mu.m may be formed from the polymer composition. Such films may be used as gas separation membranes and may be submerged into water for extended periods without crazing and cracking. The polymer composition may also be used as a coating on substrates, such as metal and ceramics, or may be used for spinning fibers. Precursors for forming such polymer compositions are also disclosed.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2013},

  month        = {9}

}

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Works referenced in this record:

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Method for producing a membrane from a crosslinked polymer blend, and corresponding fuel cell
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Kiefer, Joachim; Uensal, Oemer
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Polybenzimidazole resin-based new chelating agents. Ferric ion selectivity of resins with immobilized oligoamines
journal, December 1988

Chanda, M.; O'Driscoll, K. F.; Rempel, G. L.
Reactive Polymers, Ion Exchangers, Sorbents, Vol. 9, Issue 3, p. 277-284
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Polybenzimidazole resin-based new chelating agents. Uranyl and ferric ion selectivity of resins with anchored dimethylglyoxime
journal, January 1989

Chanda, M.; Rempel, G. L.
Reactive Polymers, Vol. 11, p. 165-176
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Meniscus membranes for separations
patent, January 2004

Dye, Robert C.; Jorgensen, Betty S.; Pesiri, David
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patent, February 2010

Carbajal, Leopoldo Alejandro; Egres, Jr., Ronald G.
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Substituted tetraamino heterocyclic compounds, useful in the preparation of substituted polybenzimidazoles and poly-imidazopyrrolones
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patent, August 2010

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Cross-linked polybenzimidazole membrane for gas separation
patent, September 2005

Jorgensen, Betty S.; Young, Jennifer; Espinoza, Brent F.
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patent, August 2007

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Meniscus membranes for separations
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Similar Records

Title: Polymer compositions, polymer films and methods and precursors for forming same

Abstract

Citation Formats

Polyazole-based polymer films patent, February 2009

Substituted aliphatic polybenzimidazoles as membrane separator materials journal, January 1969

Electrically conductive polybenzimidazole fibrous material patent, July 1988

Chemical modification of polybenzimidazole semipermeable patent, April 1977

Method for producing a membrane from a crosslinked polymer blend, and corresponding fuel cell patent, December 2008

Polybenzimidazole resin-based new chelating agents. Ferric ion selectivity of resins with immobilized oligoamines journal, December 1988

Polybenzimidazole resin-based new chelating agents. Uranyl and ferric ion selectivity of resins with anchored dimethylglyoxime journal, January 1989

Meniscus membranes for separations patent, January 2004

Ballistic resistant body armor articles patent, February 2010

Substituted tetraamino heterocyclic compounds, useful in the preparation of substituted polybenzimidazoles and poly-imidazopyrrolones patent, March 1976

Polybenzimidazole compounds patent, August 2010

Cross-linked polybenzimidazole membrane for gas separation patent, September 2005

Polybenzimidazole compounds, polymeric media, and methods of post-polymerization modifications patent, August 2007

Meniscus membranes for separations patent, September 2005

Preparation of N-substituted phenyl polybenzimidazole polymers patent, June 1990

Polybenzimidazole compounds, polymeric media, and methods of post-polymerization modifications patent, December 2007

Process for preparing electrically conductive shaped articles from polybenzimidazoles patent, May 1991

Polymeric media comprising polybenzimidazoles N-substituted with organic-inorganic hybrid moiety patent, December 2009

N-substituted polybenzimidazole polymer patent, February 1990

Non-Fluorinated Polymer Materials for Proton Exchange Membrane Fuel Cells journal, August 2003

Cross-linked polybenzimidazole membrane for gas separation patent, February 2006

Anhydrous Proton-Conducting Polymers journal, August 2003

High performance UV and heat crosslinked or chain extended polymers patent, November 2001

Polyazole-based polymer films
patent, February 2009

Substituted aliphatic polybenzimidazoles as membrane separator materials
journal, January 1969

Electrically conductive polybenzimidazole fibrous material
patent, July 1988

Chemical modification of polybenzimidazole semipermeable
patent, April 1977

Method for producing a membrane from a crosslinked polymer blend, and corresponding fuel cell
patent, December 2008

Polybenzimidazole resin-based new chelating agents. Ferric ion selectivity of resins with immobilized oligoamines
journal, December 1988

Polybenzimidazole resin-based new chelating agents. Uranyl and ferric ion selectivity of resins with anchored dimethylglyoxime
journal, January 1989

Meniscus membranes for separations
patent, January 2004

Ballistic resistant body armor articles
patent, February 2010

Substituted tetraamino heterocyclic compounds, useful in the preparation of substituted polybenzimidazoles and poly-imidazopyrrolones
patent, March 1976

Polybenzimidazole compounds
patent, August 2010

Cross-linked polybenzimidazole membrane for gas separation
patent, September 2005

Polybenzimidazole compounds, polymeric media, and methods of post-polymerization modifications
patent, August 2007

Meniscus membranes for separations
patent, September 2005

Preparation of N-substituted phenyl polybenzimidazole polymers
patent, June 1990

Polybenzimidazole compounds, polymeric media, and methods of post-polymerization modifications
patent, December 2007

Process for preparing electrically conductive shaped articles from polybenzimidazoles
patent, May 1991

Polymeric media comprising polybenzimidazoles N-substituted with organic-inorganic hybrid moiety
patent, December 2009

N-substituted polybenzimidazole polymer
patent, February 1990

Non-Fluorinated Polymer Materials for Proton Exchange Membrane Fuel Cells
journal, August 2003

Cross-linked polybenzimidazole membrane for gas separation
patent, February 2006

Anhydrous Proton-Conducting Polymers
journal, August 2003

High performance UV and heat crosslinked or chain extended polymers
patent, November 2001