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Title: Mild and selective vanadium-catalyzed oxidation of benzylic, allylic, and propargylic alcohols using air

Abstract

The invention concerns processes for oxidizing an alcohol to produce a carbonyl compound. The processes comprise contacting the alcohol with (i) a gaseous mixture comprising oxygen; and (ii) an amine compound in the presence of a catalyst, having the formula: ##STR00001## where each of R.sup.1-R.sup.12 are independently H, alkyl, aryl, CF.sub.3, halogen, OR.sup.13, SO.sub.3R.sup.14, C(O)R.sup.15, CONR.sup.16R.sup.17 or CO.sub.2R.sup.18; each of R.sup.13-R.sup.18 is independently alkyl or aryl; and Z is alkl or aryl.

Inventors:
; ;
Issue Date:
Research Org.:
LANL (Los Alamos National Laboratory (LANL), Los Alamos, NM (United States))
Sponsoring Org.:
USDOE
OSTI Identifier:
1093286
Patent Number(s):
8,519,132
Application Number:
13/414,975
Assignee:
Los Alamos National Security, LLC (Los Alamos, NM)
DOE Contract Number:  
AC52-06NA25396
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Hanson, Susan Kloek, Silks, Louis A, and Wu, Ruilian. Mild and selective vanadium-catalyzed oxidation of benzylic, allylic, and propargylic alcohols using air. United States: N. p., 2013. Web.
Hanson, Susan Kloek, Silks, Louis A, & Wu, Ruilian. Mild and selective vanadium-catalyzed oxidation of benzylic, allylic, and propargylic alcohols using air. United States.
Hanson, Susan Kloek, Silks, Louis A, and Wu, Ruilian. Tue . "Mild and selective vanadium-catalyzed oxidation of benzylic, allylic, and propargylic alcohols using air". United States. https://www.osti.gov/servlets/purl/1093286.
@article{osti_1093286,
title = {Mild and selective vanadium-catalyzed oxidation of benzylic, allylic, and propargylic alcohols using air},
author = {Hanson, Susan Kloek and Silks, Louis A and Wu, Ruilian},
abstractNote = {The invention concerns processes for oxidizing an alcohol to produce a carbonyl compound. The processes comprise contacting the alcohol with (i) a gaseous mixture comprising oxygen; and (ii) an amine compound in the presence of a catalyst, having the formula: ##STR00001## where each of R.sup.1-R.sup.12 are independently H, alkyl, aryl, CF.sub.3, halogen, OR.sup.13, SO.sub.3R.sup.14, C(O)R.sup.15, CONR.sup.16R.sup.17 or CO.sub.2R.sup.18; each of R.sup.13-R.sup.18 is independently alkyl or aryl; and Z is alkl or aryl.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2013},
month = {8}
}

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