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Title: Regenerable solid imine sorbents

Abstract

Two new classes of amine-based sorbents are disclosed. The first class comprises new polymer-immobilized tertiary amine sorbents; the second class new polymer-bound amine sorbents. Both classes are tailored to facilitate removal of acid anhydrides, especially carbon dioxide (CO.sub.2), from effluent gases. The amines adsorb acid anhydrides in a 1:1 molar ratio. Both classes of amine sorbents adsorb in the temperature range from about 20.degree. C. upwards to 90.degree. C. and can be regenerated by heating upwards to 100.degree. C.

Inventors:
; ; ;
Issue Date:
Research Org.:
National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1092942
Patent Number(s):
8530375
Application Number:
12/549,661
Assignee:
U.S. Department of Energy (Washington, DC) ; University of Pittsburgh--Of the Commonwealth System of Higher Education (Pittsburgh, PA)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Gray, McMahan, Champagne, Kenneth J., Fauth, Daniel, and Beckman, Eric. Regenerable solid imine sorbents. United States: N. p., 2013. Web.
Gray, McMahan, Champagne, Kenneth J., Fauth, Daniel, & Beckman, Eric. Regenerable solid imine sorbents. United States.
Gray, McMahan, Champagne, Kenneth J., Fauth, Daniel, and Beckman, Eric. Tue . "Regenerable solid imine sorbents". United States. https://www.osti.gov/servlets/purl/1092942.
@article{osti_1092942,
title = {Regenerable solid imine sorbents},
author = {Gray, McMahan and Champagne, Kenneth J. and Fauth, Daniel and Beckman, Eric},
abstractNote = {Two new classes of amine-based sorbents are disclosed. The first class comprises new polymer-immobilized tertiary amine sorbents; the second class new polymer-bound amine sorbents. Both classes are tailored to facilitate removal of acid anhydrides, especially carbon dioxide (CO.sub.2), from effluent gases. The amines adsorb acid anhydrides in a 1:1 molar ratio. Both classes of amine sorbents adsorb in the temperature range from about 20.degree. C. upwards to 90.degree. C. and can be regenerated by heating upwards to 100.degree. C.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Sep 10 00:00:00 EDT 2013},
month = {Tue Sep 10 00:00:00 EDT 2013}
}

Works referenced in this record:

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journal, June 2005


Improved immobilized carbon dioxide capture sorbents
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Regenerable solid amine sorbent
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Amine enriched solid sorbents for carbon dioxide capture
patent, April 2003


Method of separating carbon dioxide from a gas mixture using a fluid dynamic instability
patent, June 2003


Amine-Grafted MCM-48 and Silica Xerogel as Superior Sorbents for Acidic Gas Removal from Natural Gas
journal, June 2003


Regenerable supported amine-polyol sorbent
patent, February 1996