SE-72/AS-72 generator system based on Se extraction/ As reextraction
Abstract
The preparation of a .sup.72Se/.sup.72As radioisotope generator involves forming an acidic aqueous solution of an irradiated alkali bromide target such as a NaBr target, oxidizing soluble bromide in the solution to elemental bromine, removing the elemental bromine, evaporating the resulting solution to a residue, removing hydrogen chloride from the residue, forming an acidic aqueous solution of the residue, adding a chelator that selectively forms a chelation complex with selenium, and extracting the chelation complex from the acidic aqueous solution into an organic phase. As the .sup.72Se generates .sup.72As in the organic phase, the .sup.72As may be extracted repeatedly from the organic phase with an aqueous acid solution.
- Inventors:
- Issue Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1092935
- Patent Number(s):
- 8529873
- Application Number:
- 13/216,964
- Assignee:
- Los Alamos National Security, LLC (Los Alamos, NM)
- Patent Classifications (CPCs):
-
A - HUMAN NECESSITIES A61 - MEDICAL OR VETERINARY SCIENCE A61K - PREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
- DOE Contract Number:
- AC52-06NA25396
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Fassbender, Michael Ernst, and Ballard, Beau D. SE-72/AS-72 generator system based on Se extraction/ As reextraction. United States: N. p., 2013.
Web.
Fassbender, Michael Ernst, & Ballard, Beau D. SE-72/AS-72 generator system based on Se extraction/ As reextraction. United States.
Fassbender, Michael Ernst, and Ballard, Beau D. Tue .
"SE-72/AS-72 generator system based on Se extraction/ As reextraction". United States. https://www.osti.gov/servlets/purl/1092935.
@article{osti_1092935,
title = {SE-72/AS-72 generator system based on Se extraction/ As reextraction},
author = {Fassbender, Michael Ernst and Ballard, Beau D},
abstractNote = {The preparation of a .sup.72Se/.sup.72As radioisotope generator involves forming an acidic aqueous solution of an irradiated alkali bromide target such as a NaBr target, oxidizing soluble bromide in the solution to elemental bromine, removing the elemental bromine, evaporating the resulting solution to a residue, removing hydrogen chloride from the residue, forming an acidic aqueous solution of the residue, adding a chelator that selectively forms a chelation complex with selenium, and extracting the chelation complex from the acidic aqueous solution into an organic phase. As the .sup.72Se generates .sup.72As in the organic phase, the .sup.72As may be extracted repeatedly from the organic phase with an aqueous acid solution.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Sep 10 00:00:00 EDT 2013},
month = {Tue Sep 10 00:00:00 EDT 2013}
}
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