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Title: Layered zeolite materials and methods related thereto

Abstract

A novel oxide material (MIN-I) comprising YO.sub.2; and X.sub.2O.sub.3, wherein Y is a tetravalent element and X is a trivalent element, wherein X/Y=O or Y/X=30 to 100 is provided. Surprisingly, MIN-I can be reversibly deswollen. MIN-I can further be combined with a polymer to produce a nanocomposite, depolymerized to produce predominantly fully exfoliated layers (MIN-2), and pillared to produce a pillared oxide material (MIN-3), analogous to MCM-36. The materials are useful in a wide range of applications, such as catalysts, thin films, membranes, and coatings.

Inventors:
; ; ;
Issue Date:
Research Org.:
University of Minnesota (St. Paul, MN)
Sponsoring Org.:
USDOE
OSTI Identifier:
1089413
Patent Number(s):
8501068
Application Number:
12/741,178
Assignee:
Regents of the University of Minnesota (St. Paul, MN); Georgia Institute of Technology (Atlanta, GA)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
DOE Contract Number:  
FG26-04NT42119
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Tsapatsis, Michael, Maheshwari, Sudeep, Bates, Frank S, and Koros, William J. Layered zeolite materials and methods related thereto. United States: N. p., 2013. Web.
Tsapatsis, Michael, Maheshwari, Sudeep, Bates, Frank S, & Koros, William J. Layered zeolite materials and methods related thereto. United States.
Tsapatsis, Michael, Maheshwari, Sudeep, Bates, Frank S, and Koros, William J. Tue . "Layered zeolite materials and methods related thereto". United States. https://www.osti.gov/servlets/purl/1089413.
@article{osti_1089413,
title = {Layered zeolite materials and methods related thereto},
author = {Tsapatsis, Michael and Maheshwari, Sudeep and Bates, Frank S and Koros, William J},
abstractNote = {A novel oxide material (MIN-I) comprising YO.sub.2; and X.sub.2O.sub.3, wherein Y is a tetravalent element and X is a trivalent element, wherein X/Y=O or Y/X=30 to 100 is provided. Surprisingly, MIN-I can be reversibly deswollen. MIN-I can further be combined with a polymer to produce a nanocomposite, depolymerized to produce predominantly fully exfoliated layers (MIN-2), and pillared to produce a pillared oxide material (MIN-3), analogous to MCM-36. The materials are useful in a wide range of applications, such as catalysts, thin films, membranes, and coatings.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2013},
month = {8}
}

Works referenced in this record:

Ultrastable porous aluminosilicate structures and compositions derived therefrom
patent, January 2005


Laminated zeolite composite and method for production thereof
patent, August 2007


MCM-22 Family Molecular Sieve Composition, Its Method of Making, and Use for Hydrocarbon Conversions
patent, February 2011


Layer Structure Preservation during Swelling, Pillaring, and Exfoliation of a Zeolite Precursor
journal, January 2008


Crystalline oxide material
patent, November 1993


Method for preparing a pillared layered oxide material
patent, January 1994


Zeolite laminated composite and zeolite membrane reactor using the same
patent, August 2005