Preparation of functionalized zeolitic frameworks
Abstract
The disclosure provides zeolitic frameworks for gas separation, gas storage, catalysis and sensors. More particularly the disclosure provides zeolitic frameworks (ZIFs). The ZIF of the disclosure comprises any number of transition metals or a homogenous transition metal composition.
- Inventors:
- Issue Date:
- Research Org.:
- DOEEE (USDOE Office of Energy Efficiency and Renewable Energy (EE) (United States))
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1088299
- Patent Number(s):
- 8480792
- Application Number:
- 12/669,616
- Assignee:
- The Regents of the University of California (Oakland, CA)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
- DOE Contract Number:
- FG36-05GO15001:A005
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Yaghi, Omar M, Furukawa, Hiroyasu, and Wang, Bo. Preparation of functionalized zeolitic frameworks. United States: N. p., 2013.
Web.
Yaghi, Omar M, Furukawa, Hiroyasu, & Wang, Bo. Preparation of functionalized zeolitic frameworks. United States.
Yaghi, Omar M, Furukawa, Hiroyasu, and Wang, Bo. Tue .
"Preparation of functionalized zeolitic frameworks". United States. https://www.osti.gov/servlets/purl/1088299.
@article{osti_1088299,
title = {Preparation of functionalized zeolitic frameworks},
author = {Yaghi, Omar M and Furukawa, Hiroyasu and Wang, Bo},
abstractNote = {The disclosure provides zeolitic frameworks for gas separation, gas storage, catalysis and sensors. More particularly the disclosure provides zeolitic frameworks (ZIFs). The ZIF of the disclosure comprises any number of transition metals or a homogenous transition metal composition.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2013},
month = {7}
}
Works referenced in this record:
Synthesis and Structure of Chemically Stable Metal−Organic Polyhedra
journal, September 2009
- Lu, Zheng; Knobler, Carolyn B.; Furukawa, Hiroyasu
- Journal of the American Chemical Society, Vol. 131, Issue 35, p. 12532-12533
Strategies for Hydrogen Storage in Metal-Organic Frameworks
journal, July 2005
- Rowsell, Jesse L. C.; Yaghi, Omar M.
- Angewandte Chemie International Edition, Vol. 44, Issue 30, p. 4670-4679
Tailored Porous Materials
journal, October 1999
- Barton, Thomas J.; Bull, Lucy M.; Klemperer, Walter G.
- Chemistry of Materials, Vol. 11, Issue 10, p. 2633-2656
Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks
journal, April 2001
- Eddaoudi, Mohamed; Moler, David B.; Li, Hailian
- Accounts of Chemical Research, Vol. 34, Issue 4, p. 319-330
Exceptional H2 Saturation Uptake in Microporous Metal−Organic Frameworks
journal, March 2006
- Wong-Foy, Antek G.; Matzger, Adam J.; Yaghi, Omar M.
- Journal of the American Chemical Society, Vol. 128, Issue 11, p. 3494-3495
A Combined Experimental−Computational Investigation of Carbon Dioxide Capture in a Series of Isoreticular Zeolitic Imidazolate Frameworks
journal, August 2010
- Morris, William; Leung, Belinda; Furukawa, Hiroyasu
- Journal of the American Chemical Society, Vol. 132, Issue 32, p. 11006-11008
Hydrogen Storage in Microporous Metal-Organic Frameworks
journal, May 2003
- Rosi, Nathaniel L.; Eckert, Juergen; Eddaoudi, Mohamed
- Science, Vol. 300, Issue 5622, p. 1127-1129
Assembly of Metal−Organic Frameworks from Large Organic and Inorganic Secondary Building Units: New Examples and Simplifying Principles for Complex Structures
journal, August 2001
- Kim, Jaheon; Chen, Banglin; Reineke, Theresa M.
- Journal of the American Chemical Society, Vol. 123, Issue 34, p. 8239-8247
Ultrahigh Porosity in Metal-Organic Frameworks
journal, July 2010
- Furukawa, H.; Ko, N.; Go, Y. B.
- Science, Vol. 329, Issue 5990, p. 424-428
Synthetic Strategies, Structure Patterns, and Emerging Properties in the Chemistry of Modular Porous Solids†
journal, August 1998
- Yaghi, Omar M.; Li, Hailian; Davis, Charles
- Accounts of Chemical Research, Vol. 31, Issue 8, p. 474-484
Design of New Materials for Methane Storage
journal, March 2004
- Düren, Tina; Sarkisov, Lev; Yaghi, Omar M.
- Langmuir, Vol. 20, Issue 7, p. 2683-2689
Azulene based metal–organic frameworks for strong adsorption of H2
journal, January 2010
- Barman, Samir; Furukawa, Hiroyasu; Blacque, Olivier
- Chemical Communications, Vol. 46, Issue 42, p. 7981-7983
Metal–organic Frameworks: A tale of two entanglements
journal, February 2007
- Yaghi, Omar M.
- Nature Materials, Vol. 6, Issue 2, p. 92-93
Transformation of Germanium Dioxide to Microporous Germanate 4-Connected Nets
journal, October 1998
- Li, Hailian; Yaghi, O. M.
- Journal of the American Chemical Society, Vol. 120, Issue 40, p. 10569-10570
Hydrogen Sorption in Functionalized Metal−Organic Frameworks
journal, May 2004
- Rowsell, Jesse L. C.; Millward, Andrew R.; Park, Kyo Sung
- Journal of the American Chemical Society, Vol. 126, Issue 18, p. 5666-5667
Conversion of hydrogen-bonded manganese(II) and zinc(II) squarate (C4O42–) molecules, chains and sheets to three-dimensional cage networks
journal, January 1995
- Yaghi, Omar M.; Li, Guangming; Groy, Thomas L.
- Journal of the Chemical Society, Dalton Transactions, Vol. 0, Issue 5, p. 727-732
Control of Vertex Geometry, Structure Dimensionality, Functionality, and Pore Metrics in the Reticular Synthesis of Crystalline Metal−Organic Frameworks and Polyhedra
journal, September 2008
- Furukawa, Hiroyasu; Kim, Jaheon; Ockwig, Nathan W.
- Journal of the American Chemical Society, Vol. 130, Issue 35, p. 11650-11661
Reticular Chemistry and Metal-Organic Frameworks for Clean Energy
journal, September 2009
- Yaghi, Omar M.; Li, Qiaowei
- MRS Bulletin, Vol. 34, Issue 9, p. 682-690
Topological Control in Heterometallic Metal−Organic Frameworks by Anion Templating and Metalloligand Design
journal, November 2006
- Halper, Sara R.; Do, Loi; Stork, Jay R.
- Journal of the American Chemical Society, Vol. 128, Issue 47, p. 15255-15268
Selective binding and removal of guests in a microporous metal–organic framework
journal, December 1995
- Yaghi, O. M.; Li, Guangming; Li, Hailian
- Nature, Vol. 378, Issue 6558, p. 703-706
Advances in the chemistry of metal–organic frameworks
journal, January 2002
- Rosi, Nathaniel L.; Eddaoudi, Mohamed; Kim, Jaheon
- CrystEngComm, Vol. 4, Issue 68, p. 401-404
Metal-Organic Frameworks Based on Trigonal Prismatic Building Blocks and the New “acs” Topology
journal, May 2005
- Sudik, Andrea C.; Côté, Adrien P.; Yaghi, Omar M.
- Inorganic Chemistry, Vol. 44, Issue 9, p. 2998-3000
Three-periodic nets and tilings: regular and quasiregular nets
journal, December 2002
- Delgado Friedrichs, Olaf; O'Keeffe, Michael; Yaghi, Omar M.
- Acta Crystallographica Section A Foundations of Crystallography, Vol. 59, Issue 1, p. 22-27
Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties
journal, March 2009
- Banerjee, Rahul; Furukawa, Hiroyasu; Britt, David
- Journal of the American Chemical Society, Vol. 131, Issue 11, p. 3875-3877
Metal Insertion in a Microporous Metal−Organic Framework Lined with 2,2′-Bipyridine
journal, October 2010
- Bloch, Eric D.; Britt, David; Lee, Chain
- Journal of the American Chemical Society, Vol. 132, Issue 41, p. 14382-14384
A Metal–Organic Framework with a Hierarchical System of Pores and Tetrahedral Building Blocks
journal, April 2006
- Sudik, Andrea C.; Côté, Adrien P.; Wong-Foy, Antek G.
- Angewandte Chemie International Edition, Vol. 45, Issue 16, p. 2528-2533
The pervasive chemistry of metal–organic frameworks
journal, January 2009
- Long, Jeffrey R.; Yaghi, Omar M.
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1213-1214
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999
- Li, Hailian; Eddaoudi, Mohamed; M., O'Keeffe
- Nature, Vol. 402, Issue 6759, p. 276-279
Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks
journal, January 2010
- Phan, Anh; Doonan, Christian J.; Uribe-Romo, Fernando J.
- Accounts of Chemical Research, Vol. 43, Issue 1, p. 58-67
Polycatenation, polythreading and polyknotting in coordination network chemistry
journal, November 2003
- Carlucci, Lucia; Ciani, Gianfranco; Proserpio, Davide M.
- Coordination Chemistry Reviews, Vol. 246, Issue 1-2, p. 247-289
What do we know about three-periodic nets?
journal, August 2005
- Delgado-Friedrichs, Olaf; Foster, Martin D.; O’Keeffe, Michael
- Journal of Solid State Chemistry, Vol. 178, Issue 8, p. 2533-2554
Determination of the hydrogen absorption sites in Zn4O(1,4-benzenedicarboxylate) by single crystal neutron diffraction
journal, January 2006
- Spencer, Elinor C.; Howard, Judith A. K.; McIntyre, Garry J.
- Chemical Communications, Vol. 0, Issue 3, p. 278-280
Zeolite A imidazolate frameworks
journal, May 2007
- Hayashi, Hideki; Côté, Adrien P.; Furukawa, Hiroyasu
- Nature Materials, Vol. 6, Issue 7, p. 501-506
Docking in Metal-Organic Frameworks
journal, August 2009
- Li, Qiaowei; Zhang, Wenyu; Miljanic, Ognjen S.
- Science, Vol. 325, Issue 5942, p. 855-859
Three-periodic nets and tilings: edge-transitive binodal structures
journal, August 2006
- Delgado-Friedrichs, Olaf; O'Keeffe, Michael; Yaghi, Omar M.
- Acta Crystallographica Section A Foundations of Crystallography, Vol. 62, Issue 5, p. 350-355
Reticular Chemistry: Occurrence and Taxonomy of Nets and Grammar for the Design of Frameworks
journal, March 2005
- Ockwig, Nathan W.; Delgado-Friedrichs, Olaf; O'Keeffe, Michael
- Accounts of Chemical Research, Vol. 38, Issue 3, p. 176-182
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
journal, June 2006
- Park, K. S.; Ni, Z.; Cote, A. P.
- Proceedings of the National Academy of Sciences, Vol. 103, Issue 27, p. 10186-10191
Reticular synthesis and the design of new materials
journal, June 2003
- Yaghi, Omar M.; O'Keeffe, Michael; Ockwig, Nathan W.
- Nature, Vol. 423, Issue 6941, p. 705-714
Improved Designs of Metal-Organic Frameworks for Hydrogen Storage
journal, July 2007
- Han, Sang Soo; Deng, Wei-Qiao; Goddard, William A.
- Angewandte Chemie International Edition, Vol. 46, Issue 33, p. 6289-6292
Computation of Aromatic C3N4 Networks and Synthesis of the Molecular Precursor N(C3N3)3Cl6
journal, September 2003
- Vodak, David T.; Kim, Kibum; Iordanidis, Lykourgos
- Chemistry - A European Journal, Vol. 9, Issue 17, p. 4197-4201
High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO2 Capture
journal, February 2008
- Banerjee, Rahul; Phan, Anh; Wang, Bo
- Science, Vol. 319, Issue 5865, p. 939-943
Crystals as Molecules Postsynthesis Covalent Functionalization of Zeolitic Imidazolate Frameworks
journal, September 2008
- Morris, William; Doonan, Christian J.; Furukawa, Hiroyasu
- Journal of the American Chemical Society, Vol. 130, Issue 38, p. 12626-12627
Polymer-Induced Heteronucleation for the Discovery of New Extended Solids
journal, April 2006
- Grzesiak, Adam L.; Uribe, Fernando J.; Ockwig, Nathan W.
- Angewandte Chemie International Edition, Vol. 45, Issue 16, p. 2553-2556
Effects of Functionalization, Catenation, and Variation of the Metal Oxide and Organic Linking Units on the Low-Pressure Hydrogen Adsorption Properties of Metal−Organic Frameworks
journal, February 2006
- Rowsell, Jesse L. C.; Yaghi, Omar M.
- Journal of the American Chemical Society, Vol. 128, Issue 4, p. 1304-1315
A route to high surface area, porosity and inclusion of large molecules in crystals
journal, February 2004
- Chae, Hee K.; Siberio-Pérez, Diana Y.; Kim, Jaheon
- Nature, Vol. 427, Issue 6974, p. 523-527
The Reticular Chemistry Structure Resource (RCSR) Database of, and Symbols for, Crystal Nets
journal, December 2008
- O’Keeffe, Michael; Peskov, Maxim A.; Ramsden, Stuart J.
- Accounts of Chemical Research, Vol. 41, Issue 12, p. 1782-1789
Post-Synthetic Modification of Tagged Metal-Organic Frameworks
journal, October 2008
- Burrows, Andrew D.; Frost, Christopher G.; Mahon, Mary F.
- Angewandte Chemie International Edition, Vol. 47, Issue 44, p. 8482-8486
Construction of Microporous Materials from Molecular Building Blocks
book, January 2002
- Yaghi, Omar M.; Pinnavaia, Thomas J.; Thorpe, M. F.
- Access in Nanoporous Materials, p. 111-121
A Flexible Germanate Structure Containing 24-Ring Channels and with Very Low Framework Density
journal, December 2001
- Plévert, Jacques; Gentz, Travis M.; Laine, Aaron
- Journal of the American Chemical Society, Vol. 123, Issue 50, p. 12706-12707
Gas Adsorption Sites in a Large-Pore Metal-Organic Framework
journal, August 2005
- Rowsell, Jesse L. C.; Spencer, Elinor C.; Eckert, Juergen
- Science, Vol. 309, Issue 5739, p. 1350-1354
The CdSO4, rutile, cooperite and quartz dual nets: interpenetration and catenation
journal, January 2003
- Delgado Friedrichs, Olaf; O'Keeffe, Michael; Yaghi, Omar M.
- Solid State Sciences, Vol. 5, Issue 1, p. 73-78
Three-periodic nets and tilings: semiregular nets
journal, October 2003
- Delgado Friedrichs, Olaf; O'Keeffe, Michael; Yaghi, Omar M.
- Acta Crystallographica Section A Foundations of Crystallography, Vol. 59, Issue 6, p. 515-525
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002
- Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel
- Science, Vol. 295, Issue 5554, p. 469-472
Robust dynamics
journal, May 2010
- Deng, Hexiang; Olson, Mark A.; Stoddart, J. Fraser
- Nature Chemistry, Vol. 2, Issue 6, p. 439-443
Hydrogen-Bonded Complexes of Aromatic Crown Ethers with (9-Anthracenyl)methylammonium Derivatives. Supramolecular Photochemistry and Photophysics. pH-Controllable Supramolecular Switching
journal, November 1997
- Ashton, Peter R.; Ballardini, Roberto; Balzani, Vincenzo
- Journal of the American Chemical Society, Vol. 119, Issue 44, p. 10641-10651
Geometric requirements and examples of important structures in the assembly of square building blocks
journal, April 2002
- Eddaoudi, M.; Kim, J.; Vodak, D.
- Proceedings of the National Academy of Sciences, Vol. 99, Issue 8, p. 4900-4904
Frameworks for Extended Solids: Geometrical Design Principles
journal, June 2000
- O'Keeffe, M.; Eddaoudi, M.; Li, Hailian
- Journal of Solid State Chemistry, Vol. 152, Issue 1, p. 3-20
Layered Structures Constructed from New Linkages of Ge7(O,OH,F)19 Clusters
journal, February 2003
- Plévert, Jacques; Gentz, Travis M.; Groy, Thomas L.
- Chemistry of Materials, Vol. 15, Issue 3, p. 714-718
Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks
journal, February 2010
- Deng, H.; Doonan, C. J.; Furukawa, H.
- Science, Vol. 327, Issue 5967, p. 846-850
Synthesis and Characterization of Zirconogermanates
journal, September 2003
- Plévert, Jacques; Sanchez-Smith, Rebeca; Gentz, Travis M.
- Inorganic Chemistry, Vol. 42, Issue 19, p. 5954-5959
Rotaxanes as ligands: from molecules to materials
journal, January 2007
- Loeb, Stephen J.
- Chemical Society Reviews, Vol. 36, Issue 2, p. 226-235
Industrial applications of metal–organic frameworks
journal, January 2009
- Czaja, Alexander U.; Trukhan, Natalia; Müller, Ulrich
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1284-1293
Colossal cages in zeolitic imidazolate frameworks as selective carbon dioxide reservoirs
journal, May 2008
- Wang, Bo; Côté, Adrien P.; Furukawa, Hiroyasu
- Nature, Vol. 453, Issue 7192, p. 207-211
Design of Solids from Molecular Building Blocks: Golden Opportunities for Solid State Chemistry
journal, June 2000
- Yaghi, O. M.; O'Keeffe, M.; Kanatzidis, M.
- Journal of Solid State Chemistry, Vol. 152, Issue 1, p. 1-2
Taxonomy of periodic nets and the design of materials
journal, January 2007
- Delgado-Friedrichs, Olaf; O’Keeffe, Michael; Yaghi, Omar M.
- Phys. Chem. Chem. Phys., Vol. 9, Issue 9, p. 1035-1043
Porous Metal−Organic Truncated Octahedron Constructed from Paddle-Wheel Squares and Terthiophene Links
journal, September 2005
- Ni, Zheng; Yassar, Abderrahim; Antoun, Tarek
- Journal of the American Chemical Society, Vol. 127, Issue 37, p. 12752-12753