Gas sensor incorporating a porous framework

Yaghi, Omar M.; Czaja, Alexander U.; Wang, Bo; Furukawa, Hiroyasu; Galatsis, Kosmas; Wang, Kang L.

Title: Gas sensor incorporating a porous framework

Abstract

The disclosure provides sensor for gas sensing including CO.sub.2 gas sensors comprising a porous framework sensing area for binding an analyte gas.

Inventors:: Yaghi, Omar M.; Czaja, Alexander U.; Wang, Bo; Furukawa, Hiroyasu; Galatsis, Kosmas; Wang, Kang L.

Issue Date:: 2013-07-09

Research Org.:: University of California (Oakland, CA)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1087899

Patent Number(s):: 8480955

Application Number:: 13/142,564

Assignee:: The Regents of the University of California (Oakland, CA); BASF SE (Ludwigshafen, DE)

Patent Classifications (CPCs):: Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES

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Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T436/25875 - Gaseous sample or with change of physical state

G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
G01N33/004 - {for CO, CO2}
G01N27/125 - {Composition of the body, e.g. the composition of its sensitive layer}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T436/204998 - Inorganic carbon compounds

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J20/226 - {Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T436/11 - Automated chemical analysis

G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
G01N33/50 - Chemical analysis of biological material, e.g. blood, urine

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DOE Contract Number:: FG02-08ER15935

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 47 OTHER INSTRUMENTATION

Citation Formats


                    Yaghi, Omar M., Czaja, Alexander U., Wang, Bo, Furukawa, Hiroyasu, Galatsis, Kosmas, and Wang, Kang L. Gas sensor incorporating a porous framework.  United States: N. p., 2013. 
        Web.

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                    Yaghi, Omar M., Czaja, Alexander U., Wang, Bo, Furukawa, Hiroyasu, Galatsis, Kosmas, & Wang, Kang L. Gas sensor incorporating a porous framework.  United States.

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                    Yaghi, Omar M., Czaja, Alexander U., Wang, Bo, Furukawa, Hiroyasu, Galatsis, Kosmas, and Wang, Kang L. Tue .  
        "Gas sensor incorporating a porous framework".  United States.  https://www.osti.gov/servlets/purl/1087899.

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@article{osti_1087899,

  title        = {Gas sensor incorporating a porous framework},

  author       = {Yaghi, Omar M. and Czaja, Alexander U. and Wang, Bo and Furukawa, Hiroyasu and Galatsis, Kosmas and Wang, Kang L.},

  abstractNote = {The disclosure provides sensor for gas sensing including CO.sub.2 gas sensors comprising a porous framework sensing area for binding an analyte gas.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2013},

  month        = {7}

}

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Highly Porous and Stable Metal−Organic Frameworks: Structure Design and Sorption Properties
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Eddaoudi, Mohamed; Li, Hailian; Yaghi, O. M.
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Ni, Zheng; Yassar, Abderrahim; Antoun, Tarek
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Title: Gas sensor incorporating a porous framework

Abstract

Citation Formats

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Synthesis and Structure of Chemically Stable Metal−Organic Polyhedra journal, September 2009

High H2 Adsorption in a Microporous Metal-Organic Framework with Open Metal Sites journal, July 2005

Strategies for Hydrogen Storage in Metal-Organic Frameworks journal, July 2005

Tailored Porous Materials journal, October 1999

Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks journal, April 2001

A Nearly Planar Water Sheet Sandwiched between Strontium−Imidazolium Carboxylate Coordination Polymers journal, July 2005

Exceptional H2 Saturation Uptake in Microporous Metal−Organic Frameworks journal, March 2006

A Combined Experimental−Computational Investigation of Carbon Dioxide Capture in a Series of Isoreticular Zeolitic Imidazolate Frameworks journal, August 2010

Reticular Chemistry of Metal–Organic Polyhedra journal, June 2008

Selective Guest Binding by Tailored Channels in a 3-D Porous Zinc(II)−Benzenetricarboxylate Network journal, March 1997

Hydrogen Storage in Microporous Metal-Organic Frameworks journal, May 2003

Assembly of Metal−Organic Frameworks from Large Organic and Inorganic Secondary Building Units: New Examples and Simplifying Principles for Complex Structures journal, August 2001

Ultrahigh Porosity in Metal-Organic Frameworks journal, July 2010

Open-Framework Solids with Diamond-Like Structures Prepared from Clusters and Metal-Organic Building Blocks journal, January 1994

Hydrothermal Synthesis of a Metal-Organic Framework Containing Large Rectangular Channels journal, October 1995

Synthetic Strategies, Structure Patterns, and Emerging Properties in the Chemistry of Modular Porous Solids† journal, August 1998

Construction of Porous Solids from Hydrogen-Bonded Metal Complexes of 1,3,5-Benzenetricarboxylic Acid journal, January 1996

Reticular Synthesis of Microporous and Mesoporous 2D Covalent Organic Frameworks journal, October 2007

Design of New Materials for Methane Storage journal, March 2004

T-Shaped Molecular Building Units in the Porous Structure of Ag(4,4‘-bpy)·NO3 journal, January 1996

Azulene based metal–organic frameworks for strong adsorption of H2 journal, January 2010

Establishing Microporosity in Open Metal−Organic Frameworks: Gas Sorption Isotherms for Zn(BDC) (BDC = 1,4-Benzenedicarboxylate) journal, August 1998

Metal–organic Frameworks: A tale of two entanglements journal, February 2007

Transformation of Germanium Dioxide to Microporous Germanate 4-Connected Nets journal, October 1998

Hydrogen Sorption in Functionalized Metal−Organic Frameworks journal, May 2004

Conversion of hydrogen-bonded manganese(II) and zinc(II) squarate (C4O42–) molecules, chains and sheets to three-dimensional cage networks journal, January 1995

A metal–organic framework replete with ordered donor–acceptor catenanes journal, January 2010

Control of Vertex Geometry, Structure Dimensionality, Functionality, and Pore Metrics in the Reticular Synthesis of Crystalline Metal−Organic Frameworks and Polyhedra journal, September 2008

Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0 journal, September 2008

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A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework journal, April 2009

Porous Germanates: Synthesis, Structure, and Inclusion Properties of Ge7O14.5F2·[(CH3)2NH2]3(H2O)0.86 journal, August 1998

Selective binding and removal of guests in a microporous metal–organic framework journal, December 1995

Advances in the chemistry of metal–organic frameworks journal, January 2002

Crystal Growth of Extended Solids by Nonaqueous Gel Diffusion journal, May 1997

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Three-periodic nets and tilings: regular and quasiregular nets journal, December 2002

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Secondary building units, nets and bonding in the chemistry of metal–organic frameworks journal, January 2009

Exceptional ammonia uptake by a covalent organic framework journal, February 2010

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Metal-organic frameworks—New materials for hydrogen storage journal, April 2007

Isoreticular Metalation of Metal−Organic Frameworks journal, July 2009

Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks journal, January 2010

Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores journal, February 2001

Coordinatively Unsaturated Metal Centers in the Extended Porous Framework of Zn3(BDC)3·6CH3OH (BDC = 1,4-Benzenedicarboxylate) journal, March 1998

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Three-periodic nets and tilings: edge-transitive binodal structures journal, August 2006

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Covalent Organic Frameworks as Exceptional Hydrogen Storage Materials journal, September 2008

From Condensed Lanthanide Coordination Solids to Microporous Frameworks Having Accessible Metal Sites journal, March 1999

Postsynthetic Modification of a Metal–Organic Framework for Stabilization of a Hemiaminal and Ammonia Uptake journal, August 2011

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Metal−Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature journal, December 2005

Construction of a new open-framework solid from 1,3,5-cyclohexanetricarboxylate and zinc(II) building blocks journal, January 1997

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Synthesis of Metal−Organic Complex Arrays journal, February 2011

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Supertetrahedral Sulfide Crystals with Giant Cavities and Channels
journal, February 1999

Synthesis and Structure of Chemically Stable Metal−Organic Polyhedra
journal, September 2009

High H₂ Adsorption in a Microporous Metal-Organic Framework with Open Metal Sites
journal, July 2005

Strategies for Hydrogen Storage in Metal-Organic Frameworks
journal, July 2005

Tailored Porous Materials
journal, October 1999

Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks
journal, April 2001

A Nearly Planar Water Sheet Sandwiched between Strontium−Imidazolium Carboxylate Coordination Polymers
journal, July 2005

Exceptional H₂ Saturation Uptake in Microporous Metal−Organic Frameworks
journal, March 2006

A Combined Experimental−Computational Investigation of Carbon Dioxide Capture in a Series of Isoreticular Zeolitic Imidazolate Frameworks
journal, August 2010

Reticular Chemistry of Metal–Organic Polyhedra
journal, June 2008

Selective Guest Binding by Tailored Channels in a 3-D Porous Zinc(II)−Benzenetricarboxylate Network
journal, March 1997

Hydrogen Storage in Microporous Metal-Organic Frameworks
journal, May 2003

Assembly of Metal−Organic Frameworks from Large Organic and Inorganic Secondary Building Units: New Examples and Simplifying Principles for Complex Structures
journal, August 2001

Ultrahigh Porosity in Metal-Organic Frameworks
journal, July 2010

Open-Framework Solids with Diamond-Like Structures Prepared from Clusters and Metal-Organic Building Blocks
journal, January 1994

Hydrothermal Synthesis of a Metal-Organic Framework Containing Large Rectangular Channels
journal, October 1995

Synthetic Strategies, Structure Patterns, and Emerging Properties in the Chemistry of Modular Porous Solids^†
journal, August 1998

Construction of Porous Solids from Hydrogen-Bonded Metal Complexes of 1,3,5-Benzenetricarboxylic Acid
journal, January 1996

Reticular Synthesis of Microporous and Mesoporous 2D Covalent Organic Frameworks
journal, October 2007

Design of New Materials for Methane Storage
journal, March 2004

T-Shaped Molecular Building Units in the Porous Structure of Ag(4,4‘-bpy)·NO₃
journal, January 1996

Azulene based metal–organic frameworks for strong adsorption of H₂
journal, January 2010

Establishing Microporosity in Open Metal−Organic Frameworks: Gas Sorption Isotherms for Zn(BDC) (BDC = 1,4-Benzenedicarboxylate)
journal, August 1998

Metal–organic Frameworks: A tale of two entanglements
journal, February 2007

Transformation of Germanium Dioxide to Microporous Germanate 4-Connected Nets
journal, October 1998

Hydrogen Sorption in Functionalized Metal−Organic Frameworks
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Advances in the chemistry of metal–organic frameworks
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Three-periodic nets and tilings: regular and quasiregular nets
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The pervasive chemistry of metal–organic frameworks
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Isoreticular Metalation of Metal−Organic Frameworks
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journal, August 2005

Crystalline Covalent Organic Frameworks with Hydrazone Linkages
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Zeolite A imidazolate frameworks
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Impact of Preparation and Handling on the Hydrogen Storage Properties of Zn₄O(1,4-benzenedicarboxylate)₃ (MOF-5)
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Three-periodic nets and tilings: edge-transitive binodal structures
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Reticular Chemistry: Occurrence and Taxonomy of Nets and Grammar for the Design of Frameworks
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Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
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Covalent Organic Frameworks as Exceptional Hydrogen Storage Materials
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journal, January 1997

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journal, May 2005

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Thermal conductivity of a metal-organic framework (MOF-5): Part II. Measurement
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Crystals as Molecules Postsynthesis Covalent Functionalization of Zeolitic Imidazolate Frameworks
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