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Title: Phase stable rare earth garnets

Abstract

A transparent ceramic according to one embodiment includes a rare earth garnet comprising A.sub.hB.sub.iC.sub.jO.sub.12, where h is 3.+-.10%, i is 2.+-.10%, and j is 3.+-.10%. A includes a rare earth element or a mixture of rare earth elements, B includes at least one of aluminum, gallium and scandium, and C includes at least one of aluminum, gallium and scandium, where A is at a dodecahedral site of the garnet, B is at an octahedral site of the garnet, and C is at a tetrahedral site of the garnet. In one embodiment, the rare earth garment has scintillation properties. A radiation detector in one embodiment includes a transparent ceramic as described above and a photo detector optically coupled to the rare earth garnet.

Inventors:
; ; ;
Issue Date:
Research Org.:
Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1084218
Patent Number(s):
8461535
Application Number:
12/778,007
Assignee:
Lawrence Livermore National Security, LLC (Livermore, CA)
Patent Classifications (CPCs):
C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
DOE Contract Number:  
AC52-07NA27344
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Kuntz, Joshua D., Cherepy, Nerine J., Roberts, Jeffery J., and Payne, Stephen A. Phase stable rare earth garnets. United States: N. p., 2013. Web.
Kuntz, Joshua D., Cherepy, Nerine J., Roberts, Jeffery J., & Payne, Stephen A. Phase stable rare earth garnets. United States.
Kuntz, Joshua D., Cherepy, Nerine J., Roberts, Jeffery J., and Payne, Stephen A. Tue . "Phase stable rare earth garnets". United States. https://www.osti.gov/servlets/purl/1084218.
@article{osti_1084218,
title = {Phase stable rare earth garnets},
author = {Kuntz, Joshua D. and Cherepy, Nerine J. and Roberts, Jeffery J. and Payne, Stephen A.},
abstractNote = {A transparent ceramic according to one embodiment includes a rare earth garnet comprising A.sub.hB.sub.iC.sub.jO.sub.12, where h is 3.+-.10%, i is 2.+-.10%, and j is 3.+-.10%. A includes a rare earth element or a mixture of rare earth elements, B includes at least one of aluminum, gallium and scandium, and C includes at least one of aluminum, gallium and scandium, where A is at a dodecahedral site of the garnet, B is at an octahedral site of the garnet, and C is at a tetrahedral site of the garnet. In one embodiment, the rare earth garment has scintillation properties. A radiation detector in one embodiment includes a transparent ceramic as described above and a photo detector optically coupled to the rare earth garnet.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jun 11 00:00:00 EDT 2013},
month = {Tue Jun 11 00:00:00 EDT 2013}
}

Works referenced in this record:

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Solubility enhancement of Nd7+ in scandium-substituted rare earth-aluminum garnets
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Crystal chemical aspect of synthesis of laser crystals with garnet structure in Ln2O3−Sc2O3−M2O3 systems (Ln=Y, Gd; M=Ga, Al)
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High speed, radiation tolerant, CT scintillator system employing garnet structure scintillators
patent, October 1991


Characteristics of a Nonstoichiometric Gd 3+δ (Al,Ga) 5−δ O 12 :Ce Garnet Scintillator
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Transparent ceramics and methods of preparation thereof
patent, October 2011