Phase stable rare earth garnets
Abstract
A transparent ceramic according to one embodiment includes a rare earth garnet comprising A.sub.hB.sub.iC.sub.jO.sub.12, where h is 3.+-.10%, i is 2.+-.10%, and j is 3.+-.10%. A includes a rare earth element or a mixture of rare earth elements, B includes at least one of aluminum, gallium and scandium, and C includes at least one of aluminum, gallium and scandium, where A is at a dodecahedral site of the garnet, B is at an octahedral site of the garnet, and C is at a tetrahedral site of the garnet. In one embodiment, the rare earth garment has scintillation properties. A radiation detector in one embodiment includes a transparent ceramic as described above and a photo detector optically coupled to the rare earth garnet.
- Inventors:
- Issue Date:
- Research Org.:
- Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1084218
- Patent Number(s):
- 8461535
- Application Number:
- 12/778,007
- Assignee:
- Lawrence Livermore National Security, LLC (Livermore, CA)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
- DOE Contract Number:
- AC52-07NA27344
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Kuntz, Joshua D., Cherepy, Nerine J., Roberts, Jeffery J., and Payne, Stephen A. Phase stable rare earth garnets. United States: N. p., 2013.
Web.
Kuntz, Joshua D., Cherepy, Nerine J., Roberts, Jeffery J., & Payne, Stephen A. Phase stable rare earth garnets. United States.
Kuntz, Joshua D., Cherepy, Nerine J., Roberts, Jeffery J., and Payne, Stephen A. Tue .
"Phase stable rare earth garnets". United States. https://www.osti.gov/servlets/purl/1084218.
@article{osti_1084218,
title = {Phase stable rare earth garnets},
author = {Kuntz, Joshua D. and Cherepy, Nerine J. and Roberts, Jeffery J. and Payne, Stephen A.},
abstractNote = {A transparent ceramic according to one embodiment includes a rare earth garnet comprising A.sub.hB.sub.iC.sub.jO.sub.12, where h is 3.+-.10%, i is 2.+-.10%, and j is 3.+-.10%. A includes a rare earth element or a mixture of rare earth elements, B includes at least one of aluminum, gallium and scandium, and C includes at least one of aluminum, gallium and scandium, where A is at a dodecahedral site of the garnet, B is at an octahedral site of the garnet, and C is at a tetrahedral site of the garnet. In one embodiment, the rare earth garment has scintillation properties. A radiation detector in one embodiment includes a transparent ceramic as described above and a photo detector optically coupled to the rare earth garnet.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jun 11 00:00:00 EDT 2013},
month = {Tue Jun 11 00:00:00 EDT 2013}
}
Works referenced in this record:
Compound Transparent Ceramics and Methods of Preparation Thereof
patent-application, April 2010
- Hollingsworth, Joel P.; Kuntz, Joshua D.; Soules, Thomas F.
- US Patent Application 12/603195; 20100105539
GSAG and YSAG: a study on isomorphism and crystal growth
journal, July 1990
- Lutts, G. B.; Denisov, A. L.; Zharikov, E. V.
- Optical and Quantum Electronics, Vol. 22, Issue S1
Solubility enhancement of Nd7+ in scandium-substituted rare earth-aluminum garnets
journal, September 1973
- Kokta, M.
- Journal of Solid State Chemistry, Vol. 8, Issue 1
Crystal chemical aspect of synthesis of laser crystals with garnet structure in Ln2O3−Sc2O3−M2O3 systems (Ln=Y, Gd; M=Ga, Al)
journal, September 1994
- Kuzmicheva, G. M.; Mukhin, B. V.
- Journal of Structural Chemistry, Vol. 35, Issue 5
High speed, radiation tolerant, CT scintillator system employing garnet structure scintillators
patent, October 1991
- Greskovich, Charles D.; Minnear, William Paul; Chernoch, Joseph P.
- US Patent Document 5,057,692
Characteristics of a Nonstoichiometric Gd 3+δ (Al,Ga) 5−δ O 12 :Ce Garnet Scintillator
journal, February 2008
- Kanai, Tsuneyuki; Satoh, Makoto; Miura, Ichiro
- Journal of the American Ceramic Society, Vol. 91, Issue 2
Transparent ceramics and methods of preparation thereof
patent, October 2011
- Hollingsworth, Joel P.; Kuntz, Joshua D.; Seeley, Zachary M.
- US Patent Document 8,039,413