Method of synthesis of anhydrous thorium(IV) complexes
Abstract
Method of producing anhydrous thorium(IV) tetrahalide complexes, utilizing Th(NO.sub.3).sub.4(H.sub.2O).sub.x, where x is at least 4, as a reagent; method of producing thorium-containing complexes utilizing ThCl.sub.4(DME).sub.2 as a precursor; method of producing purified ThCl.sub.4(ligand).sub.x compounds, where x is from 2 to 9; and novel compounds having the structures: ##STR00001##
- Inventors:
- Issue Date:
- Research Org.:
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1083273
- Patent Number(s):
- 8431689
- Application Number:
- 12/778,891
- Assignee:
- Los Alamos National Security, LLC (Los Alamas, NM)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01F - COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- DOE Contract Number:
- AC52-06NA25396
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Kiplinger, Jaqueline L, and Cantat, Thibault. Method of synthesis of anhydrous thorium(IV) complexes. United States: N. p., 2013.
Web.
Kiplinger, Jaqueline L, & Cantat, Thibault. Method of synthesis of anhydrous thorium(IV) complexes. United States.
Kiplinger, Jaqueline L, and Cantat, Thibault. Tue .
"Method of synthesis of anhydrous thorium(IV) complexes". United States. https://www.osti.gov/servlets/purl/1083273.
@article{osti_1083273,
title = {Method of synthesis of anhydrous thorium(IV) complexes},
author = {Kiplinger, Jaqueline L and Cantat, Thibault},
abstractNote = {Method of producing anhydrous thorium(IV) tetrahalide complexes, utilizing Th(NO.sub.3).sub.4(H.sub.2O).sub.x, where x is at least 4, as a reagent; method of producing thorium-containing complexes utilizing ThCl.sub.4(DME).sub.2 as a precursor; method of producing purified ThCl.sub.4(ligand).sub.x compounds, where x is from 2 to 9; and novel compounds having the structures: ##STR00001##},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2013},
month = {4}
}
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Works referenced in this record:
Synthesis and Crystal Structure of UO 2 Cl 2 (THF) 3 : A Simple Preparation of an Anhydrous Uranyl Reagent
journal, September 1999
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A convenient synthesis of solvated and unsolvated anhydrous metal chlorides via dehydration of metal chloride hydrates with trimethylchlorosilane
journal, April 1990
- So, Jeung Ho; Boudjouk, Philip
- Inorganic Chemistry, Vol. 29, Issue 8