Organic photovoltaic device with interfacial layer and method of fabricating same
Abstract
An organic photovoltaic device and method of forming same. In one embodiment, the organic photovoltaic device has an anode, a cathode, an active layer disposed between the anode and the cathode; and an interfacial layer disposed between the anode and the active layer, the interfacial layer comprising 5,5'-bis[(p-trichlorosilylpropylphenyl)phenylamino]-2,2'-bithiophene (PABTSi.sub.2).
- Inventors:
- Issue Date:
- Research Org.:
- Northwestern University (Evanston, IL)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1083031
- Patent Number(s):
- 8399761
- Application Number:
- 12/771,376
- Assignee:
- Northwestern University (Evanston, IL)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B82 - NANOTECHNOLOGY B82Y - SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- DOE Contract Number:
- FG02-08ER46536/A000
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 14 SOLAR ENERGY
Citation Formats
Marks, Tobin J., and Hains, Alexander W. Organic photovoltaic device with interfacial layer and method of fabricating same. United States: N. p., 2013.
Web.
Marks, Tobin J., & Hains, Alexander W. Organic photovoltaic device with interfacial layer and method of fabricating same. United States.
Marks, Tobin J., and Hains, Alexander W. Tue .
"Organic photovoltaic device with interfacial layer and method of fabricating same". United States. https://www.osti.gov/servlets/purl/1083031.
@article{osti_1083031,
title = {Organic photovoltaic device with interfacial layer and method of fabricating same},
author = {Marks, Tobin J. and Hains, Alexander W.},
abstractNote = {An organic photovoltaic device and method of forming same. In one embodiment, the organic photovoltaic device has an anode, a cathode, an active layer disposed between the anode and the cathode; and an interfacial layer disposed between the anode and the active layer, the interfacial layer comprising 5,5'-bis[(p-trichlorosilylpropylphenyl)phenylamino]-2,2'-bithiophene (PABTSi.sub.2).},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2013},
month = {3}
}
Works referenced in this record:
Anodic Coupling of Diphenylbenzo[ k ]fluoranthene:Â Mechanistic and Kinetic Studies Utilizing Cyclic Voltammetry and Electrogenerated Chemiluminescence
journal, February 1997
- Debad, Jeff D.; Morris, Jonathan C.; Magnus, Philip
- The Journal of Organic Chemistry, Vol. 62, Issue 3
Durability of MDMO-PPV and MDMO-PPV: PCBM blends under illumination in the absence of oxygen
journal, July 2008
- Chambon, Sylvain; Rivaton, Agnès; Gardette, Jean-Luc
- Solar Energy Materials and Solar Cells, Vol. 92, Issue 7
Effect of LiF/metal electrodes on the performance of plastic solar cells
journal, February 2002
- Brabec, Christoph J.; Shaheen, Sean E.; Winder, Christoph
- Applied Physics Letters, Vol. 80, Issue 7, p. 1288-1290
Theoretical investigation of electron transport modulation through benzenedithiol by substituent groups
journal, July 2008
- Smeu, Manuel; Wolkow, Robert A.; DiLabio, Gino A.
- The Journal of Chemical Physics, Vol. 129, Issue 3
Blocking reactions between indium-tin oxide and poly (3,4-ethylene dioxythiophene):poly(styrene sulphonate) with a self-assembly monolayer
journal, April 2002
- Wong, K. W.; Yip, H. L.; Luo, Y.
- Applied Physics Letters, Vol. 80, Issue 15
Characterization of Transparent Conducting Oxide Surfaces Using Self-Assembled Electroactive Monolayers
journal, May 2008
- Li, Jianfeng; Wang, Lian; Liu, Jun
- Langmuir, Vol. 24, Issue 11
Electron-blocking layer / hole-transport layer for organic photovoltaics and applications of same
patent, September 2010
- Marks, Tobin J.; Hains, Alexander W.; Irwin, Michael D.
- US Patent Document 7,799,990
Anode Interfacial Engineering Approaches to Enhancing Anode/Hole Transport Layer Interfacial Stability and Charge Injection Efficiency in Organic Light-Emitting Diodes
journal, September 2002
- Cui, Ji; Huang, Qinglan; Veinot, Jonathan C. G.
- Langmuir, Vol. 18, Issue 25
Palladium-catalyzed synthesis of arylamines from aryl halides. Mechanistic studies lead to coupling in the absence of tin reagents
journal, May 1995
- Louie, Janis; Hartwig, John F.
- Tetrahedron Letters, Vol. 36, Issue 21
Systematic Investigation of Nanoscale Adsorbate Effects at Organic Light-Emitting Diode Interfaces. Interfacial Structure−Charge Injection−Luminance Relationships
journal, May 2006
- Huang, Qinglan; Li, Jianfeng; Evmenenko, Guennadi A.
- Chemistry of Materials, Vol. 18, Issue 9
Dispirofluorene–Indenofluorene Derivatives as New Building Blocks for Blue Organic Electroluminescent Devices and Electroactive Polymers
journal, December 2007
- Poriel, Cyril; Liang, Jing-Jing; Rault-Berthelot, Joëlle
- Chemistry - A European Journal, Vol. 13, Issue 36
Modification of PEDOT:PSS as hole injection layer in polymer LEDs
journal, May 2004
- de Kok, M. M.; Buechel, M.; Vulto, S. I. E.
- physica status solidi (a), Vol. 201, Issue 6
Toward High-Performance Polymer Solar Cells:Â The Importance of Morphology Control
journal, March 2007
- Yang, Xiaoniu; Loos, Joachim
- Macromolecules, Vol. 40, Issue 5, p. 1353-1362
Control of the Surface Composition of a Conducting-Polymer Complex Film to Tune the Work Function
journal, August 2008
- Lee, Tae-Woo; Chung, Youngsu
- Advanced Functional Materials, Vol. 18, Issue 15
Organic Dye Compositions and use Thereof in Photovoltaic Cells
patent-application, February 2007
- Zhang, Ruzhou; Gui, John Yupeng; Xia, Zijun
- US Patent Application 11/197207; 20070028961
Semiconductive Polymer Blends: Correlating Structure with Transport Properties at the Nanoscale
journal, March 2004
- Ionescu-Zanetti, C.; Mechler, A.; Carter, S. A.
- Advanced Materials, Vol. 16, Issue 5, p. 385-389
Transition metal oxides as the buffer layer for polymer photovoltaic cells
journal, February 2006
- Shrotriya, Vishal; Li, Gang; Yao, Yan
- Applied Physics Letters, Vol. 88, Issue 7
Extraction of bulk and contact components of the series resistance in organic bulk donor-acceptor-heterojunctions
journal, February 2002
- Aernouts, T.; Geens, W.; Poortmans, J.
- Thin Solid Films, Vol. 403-404
Triarylamine siloxane anode functionalization/hole injection layers in high efficiency/high luminance small-molecule green- and blue-emitting organic light-emitting diodes
journal, May 2007
- Huang, Qinglan; Li, Jianfeng; Marks, Tobin J.
- Journal of Applied Physics, Vol. 101, Issue 9
Radical Ions of α,α‘-Bis(diphenylamino)-capped Oligothiophenes: A Combined Spectroelectrochemical and Theoretical Study
journal, April 2006
- Rohde, Dirk; Dunsch, Lothar; Tabet, Ahacine
- The Journal of Physical Chemistry B, Vol. 110, Issue 16
On the function of a bathocuproine buffer layer in organic photovoltaic cells
journal, October 2006
- Vogel, M.; Doka, S.; Breyer, Ch.
- Applied Physics Letters, Vol. 89, Issue 16
An Investigation of Poly(thienylene vinylene) in Organic Photovoltaic Devices
journal, October 2004
- Smith, Adam P.; Smith, Rachel R.; Taylor, Barney E.
- Chemistry of Materials, Vol. 16, Issue 23
Stability of the interface between indium-tin-oxide and poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) in polymer light-emitting diodes
journal, October 2000
- de Jong, M. P.; van IJzendoorn, L. J.; de Voigt, M. J. A.
- Applied Physics Letters, Vol. 77, Issue 14, p. 2255-2257
Accurate Measurement and Characterization of Organic Solar Cells
journal, October 2006
- Shrotriya, V.; Li, G.; Yao, Y.
- Advanced Functional Materials, Vol. 16, Issue 15
Built-in field electroabsorption spectroscopy of polymer light-emitting diodes incorporating a doped poly(3,4-ethylene dioxythiophene) hole injection layer
journal, September 1999
- Brown, T. M.; Kim, J. S.; Friend, R. H.
- Applied Physics Letters, Vol. 75, Issue 12
Designed Bithiophene-Based Interfacial Layer for High-Efficiency Bulk-Heterojunction Organic Photovoltaic Cells. Importance of Interfacial Energy Level Matching
journal, December 2009
- Hains, Alexander W.; Ramanan, Charusheela; Irwin, Michael D.
- ACS Applied Materials & Interfaces, Vol. 2, Issue 1
Consequences of Anode Interfacial Layer Deletion. HCl-Treated ITO in P3HT:PCBM-Based Bulk-Heterojunction Organic Photovoltaic Devices
journal, February 2010
- Irwin, Michael D.; Liu, Jun; Leever, Benjamin J.
- Langmuir, Vol. 26, Issue 4
Cathode dependence of the open-circuit voltage of polymer:fullerene bulk heterojunction solar cells
journal, November 2003
- Mihailetchi, V. D.; Blom, P. W. M.; Hummelen, J. C.
- Journal of Applied Physics, Vol. 94, Issue 10
Electrochemistry and Electrogenerated Chemiluminescence of Quinoxaline Derivatives
journal, November 2008
- Izadyar, Anahita; Omer, Khalid M.; Liu, Yunqi
- The Journal of Physical Chemistry C, Vol. 112, Issue 50
A Second-Generation Catalyst for Aryl Halide Amination:Â Mixed Secondary Amines from Aryl Halides and Primary Amines Catalyzed by (DPPF)PdCl 2
journal, January 1996
- Driver, Michael S.; Hartwig, John F.
- Journal of the American Chemical Society, Vol. 118, Issue 30
An Improved Catalyst System for Aromatic Carbon−Nitrogen Bond Formation: The Possible Involvement of Bis(Phosphine) Palladium Complexes as Key Intermediates
journal, January 1996
- Wolfe, John P.; Wagaw, Seble; Buchwald, Stephen L.
- Journal of the American Chemical Society, Vol. 118, Issue 30
Palladium-catalyzed amination of aryl halides and sulfonates
journal, March 1999
- Yang, Bryant H.; Buchwald, Stephen L.
- Journal of Organometallic Chemistry, Vol. 576, Issue 1-2
Luminescent Device
patent-application, August 2008
- Iwakuma, Toshihiro; Matsushima, Toshinori; Adachi, Chihaya
- US Patent Application 11/846233; 20080100213
Organic field-effect transistors based on a crosslinkable polymer blend as the semiconducting layer
journal, October 2005
- Yan, He; Yoon, Myung-Han; Facchetti, Antonio
- Applied Physics Letters, Vol. 87, Issue 18
Space-Charge Limited Photocurrent
journal, April 2005
- Mihailetchi, V. D.; Wildeman, J.; Blom, P. W. M.
- Physical Review Letters, Vol. 94, Issue 12
Comparative study of the influence of LiF, NaF, and KF on the performance of polymer bulk heterojunction solar cells
journal, April 2007
- Ahlswede, Erik; Hanisch, Jonas; Powalla, Michael
- Applied Physics Letters, Vol. 90, Issue 16
Bimolecular Crystals of Fullerenes in Conjugated Polymers and the Implications of Molecular Mixing for Solar Cells
journal, April 2009
- Mayer, A. C.; Toney, Michael F.; Scully, Shawn R.
- Advanced Functional Materials, Vol. 19, Issue 8
New n-Type Organic Semiconductors:Â Synthesis, Single Crystal Structures, Cyclic Voltammetry, Photophysics, Electron Transport, and Electroluminescence of a Series of Diphenylanthrazolines
journal, November 2003
- Tonzola, Christopher J.; Alam, Maksudul M.; Kaminsky, Werner
- Journal of the American Chemical Society, Vol. 125, Issue 44, p. 13548-13558
Organic Photovoltaic Cells: History, Principle and Techniques
journal, January 2008
- BernÈDe, J. C.
- Journal of the Chilean Chemical Society, Vol. 53, Issue 3
Safe and Convenient Procedure for Solvent Purification
journal, January 1996
- Pangborn, Amy B.; Giardello, Michael A.; Grubbs, Robert H.
- Organometallics, Vol. 15, Issue 5, p. 1518-1520
A Simple Catalytic Method for the Conversion of Aryl Bromides to Arylamines
journal, July 1995
- Guram, Anil S.; Rennels, Roger A.; Buchwald, Stephen L.
- Angewandte Chemie International Edition in English, Vol. 34, Issue 12
Absorption spectra modification in poly(3-hexylthiophene):methanofullerene blend thin films
journal, August 2005
- Shrotriya, Vishal; Ouyang, Jianyong; Tseng, Ricky J.
- Chemical Physics Letters, Vol. 411, Issue 1-3
Efficient inverted polymer solar cells
journal, June 2006
- Li, G.; Chu, C. -W.; Shrotriya, V.
- Applied Physics Letters, Vol. 88, Issue 25
Effect of Substitution on the Hole Mobility of Bis(diarylamino)biphenyl Derivatives Doped in Poly(Styrene)
journal, February 2003
- Maldonado, José-Luis; Bishop, Maximilienne; Fuentes-Hernandez, Canek
- Chemistry of Materials, Vol. 15, Issue 4
Novel Regiospecific MDMO−PPV Copolymer with Improved Charge Transport for Bulk Heterojunction Solar Cells
journal, April 2004
- Mozer, Attila J.; Denk, Patrick; Scharber, Markus C.
- The Journal of Physical Chemistry B, Vol. 108, Issue 17
Theoretical Calculation of Ionization Potentials for Disubstituted Benzenes:Â Additivity vs Non-Additivity of Substituent Effects
journal, April 2000
- DiLabio, Gino A.; Pratt, Derek A.; Wright, James S.
- The Journal of Organic Chemistry, Vol. 65, Issue 7
Synthesis and UV-visible properties of soluble α-thiophene oligomers. Monomer to octamer
journal, March 1992
- Tour, James M.; Wu, Ruilian
- Macromolecules, Vol. 25, Issue 7
Very-high-efficiency double-heterostructure copper phthalocyanine/C60 photovoltaic cells
journal, July 2001
- Peumans, P.; Forrest, S. R.
- Applied Physics Letters, Vol. 79, Issue 1
Electron Transport Materials for Organic Light-Emitting Diodes
journal, November 2004
- Kulkarni, Abhishek P.; Tonzola, Christopher J.; Babel, Amit
- Chemistry of Materials, Vol. 16, Issue 23
MOCVD-Derived Highly Transparent, Conductive Zinc- and Tin-Doped Indium Oxide Thin Films:Â Precursor Synthesis, Metastable Phase Film Growth and Characterization, and Application as Anodes in Polymer Light-Emitting Diodes
journal, April 2005
- Ni, Jun; Yan, He; Wang, Anchuang
- Journal of the American Chemical Society, Vol. 127, Issue 15
Scope and Mechanism of Palladium-Catalyzed Amination of Five-Membered Heterocyclic Halides
journal, April 2003
- Hooper, Mark W.; Utsunomiya, Masaru; Hartwig, John F.
- The Journal of Organic Chemistry, Vol. 68, Issue 7
Modification of Indium−Tin Oxide Electrodes with Thiophene Copolymer Thin Films: Optimizing Electron Transfer to Solution Probe Molecules
journal, January 2007
- Marrikar, F. Saneeha; Brumbach, Michael; Evans, Dennis H.
- Langmuir, Vol. 23, Issue 3
Three-Dimensional Nanoscale Organization of Bulk Heterojunction Polymer Solar Cells
journal, February 2009
- Bavel, Svetlana S. van; Sourty, Erwan; With, Gijsbertus de
- Nano Letters, Vol. 9, Issue 2
950. The synthesis of monohalogeno-2,2′-bithienyls
journal, January 1965
- Curtis, R. F.; Phillips, G. T.
- J. Chem. Soc., Vol. 0, Issue 0
Device annealing effect in organic solar cells with blends of regioregular poly(3-hexylthiophene) and soluble fullerene
journal, February 2005
- Kim, Youngkyoo; Choulis, Stelios A.; Nelson, Jenny
- Applied Physics Letters, Vol. 86, Issue 6
Photoelectron spectroscopy of thin films of PEDOT–PSS conjugated polymer blend: a mini-review and some new results
journal, December 2001
- Greczynski, G.; Kugler, Th.; Keil, M.
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 121, Issue 1-3, p. 1-17
Three-Dimensional Inhomogeneities in PEDOT:PSS Films
journal, December 2004
- Kemerink, M.; Timpanaro, S.; de Kok, M. M.
- The Journal of Physical Chemistry B, Vol. 108, Issue 49
TFB: TPDSI2 Interfacial Layer Usable i Organic Photovoltaic Cells
patent-application, March 2009
- Marks, Tobin J.; Hains, Alexander W.
- US Patent Application 12/046983; 20090056810