Method for releasing hydrogen from ammonia borane

Varma, Arvind; Diwan, Moiz; Shafirovich, Evgeny; Hwang, Hyun-Tae; Al-Kukhun, Ahmad

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Title: Method for releasing hydrogen from ammonia borane

Abstract

A method of releasing hydrogen from ammonia borane is disclosed. The method comprises heating an aqueous ammonia borane solution to between about 80-135.degree. C. at between about 14.7 and 200 pounds per square inch absolute (psia) to release hydrogen by hydrothermolysis.

Inventors:: Varma, Arvind; Diwan, Moiz; Shafirovich, Evgeny; Hwang, Hyun-Tae; Al-Kukhun, Ahmad

Issue Date:: 2013-02-19

Research Org.:: Purdue Research Foundation (West Lafayette, IN)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1082919

Patent Number(s):: 8377416

Application Number:: 12/544,832

Assignee:: Purdue Research Foundation (West Lafayette, IN)

Patent Classifications (CPCs):: C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

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C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B3/04 - by decomposition of inorganic compounds, e.g. ammonia {
C01B3/065 - {from a hydride}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/36 - Hydrogen production from non-carbon containing sources

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DOE Contract Number:: FG36-06GO86050

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 08 HYDROGEN

Citation Formats


                    Varma, Arvind, Diwan, Moiz, Shafirovich, Evgeny, Hwang, Hyun-Tae, and Al-Kukhun, Ahmad. Method for releasing hydrogen from ammonia borane.  United States: N. p., 2013. 
        Web.

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                    Varma, Arvind, Diwan, Moiz, Shafirovich, Evgeny, Hwang, Hyun-Tae, & Al-Kukhun, Ahmad. Method for releasing hydrogen from ammonia borane.  United States.

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                    Varma, Arvind, Diwan, Moiz, Shafirovich, Evgeny, Hwang, Hyun-Tae, and Al-Kukhun, Ahmad. Tue .  
        "Method for releasing hydrogen from ammonia borane".  United States.  https://www.osti.gov/servlets/purl/1082919.

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@article{osti_1082919,

  title        = {Method for releasing hydrogen from ammonia borane},

  author       = {Varma, Arvind and Diwan, Moiz and Shafirovich, Evgeny and Hwang, Hyun-Tae and Al-Kukhun, Ahmad},

  abstractNote = {A method of releasing hydrogen from ammonia borane is disclosed. The method comprises heating an aqueous ammonia borane solution to between about 80-135.degree. C. at between about 14.7 and 200 pounds per square inch absolute (psia) to release hydrogen by hydrothermolysis.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2013},

  month        = {2}

}

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Works referenced in this record:

Portable hydrogen source
patent, August 2007

Jones, Peter Brian; Browning, Darren Jonathan; Mepstead, Gary Owen
US Patent Document 7,261,748
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7261748

Catalytic dehydrogenation of amine borane complexes
patent, October 2007

Mohajeri, Nahid; Tabatabaie-Raissi, Ali
US Patent Document 7,285,142
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7285142

Materials for storage and release of hydrogen and methods for preparing and using same
patent, January 2008

Autrey, Thomas S.; Gutowska, Anna; Shin, Yongsoon
US Patent Document 7,316,788
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7316788

Noncatalytic hydrothermolysis of ammonia borane
journal, February 2008

Diwan, Moiz; Diakov, Victor; Shafirovich, Evgeny
International Journal of Hydrogen Energy, Vol. 33, Issue 4
https://doi.org/10.1016/j.ijhydene.2007.12.049

Ni _1- _x Pt _x ( x = 0−0.12) Hollow Spheres as Catalysts for Hydrogen Generation from Ammonia Borane
journal, February 2007

Cheng, Fangyi; Ma, Hua; Li, Yueming
Inorganic Chemistry, Vol. 46, Issue 3
https://doi.org/10.1021/ic061712e

Amine-boranes as hydrogen generating propellants
patent, June 1979

Chew, William M.; Murfree, James A.; Martignoni, Pasquale
US Patent Document 4,157,927
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4157927

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Liquid compositions of ammonia borane and a suitably chosen amine borane material were prepared and subjected to conditions suitable for their thermal decomposition in a closed system that resulted in hydrogen and a liquid reaction product.
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Similar Records

Title: Method for releasing hydrogen from ammonia borane

Abstract

Citation Formats

Portable hydrogen source patent, August 2007

Catalytic dehydrogenation of amine borane complexes patent, October 2007

Materials for storage and release of hydrogen and methods for preparing and using same patent, January 2008

Noncatalytic hydrothermolysis of ammonia borane journal, February 2008

Ni 1- x Pt x ( x = 0−0.12) Hollow Spheres as Catalysts for Hydrogen Generation from Ammonia Borane journal, February 2007

Amine-boranes as hydrogen generating propellants patent, June 1979

Portable hydrogen source
patent, August 2007

Catalytic dehydrogenation of amine borane complexes
patent, October 2007

Materials for storage and release of hydrogen and methods for preparing and using same
patent, January 2008

Noncatalytic hydrothermolysis of ammonia borane
journal, February 2008

Ni _1- _x Pt _x ( x = 0−0.12) Hollow Spheres as Catalysts for Hydrogen Generation from Ammonia Borane
journal, February 2007

Amine-boranes as hydrogen generating propellants
patent, June 1979