skip to main content
DOE Patents title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Methods of forming single source precursors, methods of forming polymeric single source precursors, and single source precursors and intermediate products formed by such methods

Abstract

Methods of forming single source precursors (SSPs) include forming intermediate products having the empirical formula 1/2{L.sub.2N(.mu.-X).sub.2M'X.sub.2}.sub.2, and reacting MER with the intermediate products to form SSPs of the formula L.sub.2N(.mu.-ER).sub.2M'(ER).sub.2, wherein L is a Lewis base, M is a Group IA atom, N is a Group IB atom, M' is a Group IIIB atom, each E is a Group VIB atom, each X is a Group VIIA atom or a nitrate group, and each R group is an alkyl, aryl, vinyl, (per)fluoro alkyl, (per)fluoro aryl, silane, or carbamato group. Methods of forming polymeric or copolymeric SSPs include reacting at least one of HE.sup.1R.sup.1E.sup.1H and MER with one or more substances having the empirical formula L.sub.2N(.mu.-ER).sub.2M'(ER).sub.2 or L.sub.2N(.mu.-X).sub.2M'(X).sub.2 to form a polymeric or copolymeric SSP. New SSPs and intermediate products are formed by such methods.

Inventors:
; ; ; ; ;
Issue Date:
Research Org.:
Idaho National Lab. (INL), Idaho Falls, ID (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1082478
Patent Number(s):
8324414
Application Number:
12/646,474
Assignee:
Battelle Energy Alliance, LLC (Idaho Falls, ID)
Patent Classifications (CPCs):
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
DOE Contract Number:  
AC07-05ID14517
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Fox, Robert V., Rodriguez, Rene G., Pak, Joshua J., Sun, Chivin, Margulieux, Kelsey R., and Holland, Andrew W. Methods of forming single source precursors, methods of forming polymeric single source precursors, and single source precursors and intermediate products formed by such methods. United States: N. p., 2012. Web.
Fox, Robert V., Rodriguez, Rene G., Pak, Joshua J., Sun, Chivin, Margulieux, Kelsey R., & Holland, Andrew W. Methods of forming single source precursors, methods of forming polymeric single source precursors, and single source precursors and intermediate products formed by such methods. United States.
Fox, Robert V., Rodriguez, Rene G., Pak, Joshua J., Sun, Chivin, Margulieux, Kelsey R., and Holland, Andrew W. Tue . "Methods of forming single source precursors, methods of forming polymeric single source precursors, and single source precursors and intermediate products formed by such methods". United States. https://www.osti.gov/servlets/purl/1082478.
@article{osti_1082478,
title = {Methods of forming single source precursors, methods of forming polymeric single source precursors, and single source precursors and intermediate products formed by such methods},
author = {Fox, Robert V. and Rodriguez, Rene G. and Pak, Joshua J. and Sun, Chivin and Margulieux, Kelsey R. and Holland, Andrew W.},
abstractNote = {Methods of forming single source precursors (SSPs) include forming intermediate products having the empirical formula 1/2{L.sub.2N(.mu.-X).sub.2M'X.sub.2}.sub.2, and reacting MER with the intermediate products to form SSPs of the formula L.sub.2N(.mu.-ER).sub.2M'(ER).sub.2, wherein L is a Lewis base, M is a Group IA atom, N is a Group IB atom, M' is a Group IIIB atom, each E is a Group VIB atom, each X is a Group VIIA atom or a nitrate group, and each R group is an alkyl, aryl, vinyl, (per)fluoro alkyl, (per)fluoro aryl, silane, or carbamato group. Methods of forming polymeric or copolymeric SSPs include reacting at least one of HE.sup.1R.sup.1E.sup.1H and MER with one or more substances having the empirical formula L.sub.2N(.mu.-ER).sub.2M'(ER).sub.2 or L.sub.2N(.mu.-X).sub.2M'(X).sub.2 to form a polymeric or copolymeric SSP. New SSPs and intermediate products are formed by such methods.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2012},
month = {12}
}

Patent:

Save / Share:

Works referenced in this record:

Microwave-Assisted Polyol Synthesis of CuInTe 2 and CuInSe 2 Nanoparticles
journal, November 2003


Microwave enhanced synthesis of N-propargyl derivatives of imidazole
journal, June 2006


Green chemistry: Efficient epoxides ring-opening with 1-butanol under microwave irradiation
journal, June 2006


Synthesis and Characterization of Indium Oxide Nanoparticles
journal, June 2001


A New Facile Route for the Preparation of Single-Source Precursors for Bulk, Thin-Film, and Nanocrystallite I−III−VI Semiconductors
journal, December 2003


Synthesis of Monodispersed Wurtzite Structure CuInSe 2 Nanocrystals and Their Application in High-Performance Organic−Inorganic Hybrid Photodetectors
journal, September 2010


Increasing the Efficiency of Ideal Solar Cells by Photon Induced Transitions at Intermediate Levels
journal, June 1997


Chemistry of Metal Thio- and Selenocarboxylates:  Precursors for Metal Sulfide/Selenide Materials, Thin Films, and Nanocrystals
journal, November 2006


Synthesis of CuInSe<sub>2</sub> and CuInGaSe<sub>2</sub> Nanoparticles by Solvothermal Route
journal, March 2004


Microwave-assisted alkaline digestion combined with microwave-assisted distillation for the determination of iodide and total iodine in edible seaweed by catalytic spectrophotometry
journal, June 2005


Phase Transformation of Biphasic Cu 2 S−CuInS 2 to Monophasic CuInS 2 Nanorods
journal, April 2009


A High-Yield Synthesis of Chalcopyrite CuIn S 2 Nanoparticles with Exceptional Size Control
journal, January 2009


A facile route to the synthesis of CuInS2 nanoparticles
journal, August 2006


Surface structure of CuGaSe2 (001)
journal, June 2005


Synthesis of mixed copper-indium chalcogenolates. Single-source precursors for the photovoltaic materials CuInQ2 (Q = S, Se)
journal, February 1993


An efficient synthesis of 4,4′,5,5′-tetraiododibenzo-24-crown-8 and its highly conjugated derivatives
journal, January 2006


Sol-Gel TiO2 thin films sensitized with the mulberry pigment cyanidin
journal, December 2007


Synthesis and Characterization of Colloidal CuInS 2 Nanoparticles from a Molecular Single-Source Precursor
journal, August 2004


Nanocrystalline Chalcopyrite Materials (CuInS 2 and CuInSe 2 ) via Low-Temperature Pyrolysis of Molecular Single-Source Precursors
journal, August 2003


Microwave Assisted Preparation of CdSe, PbSe, and Cu 2 - x Se Nanoparticles
journal, August 2000


Synthesis of Cu−In−S Ternary Nanocrystals with Tunable Structure and Composition
journal, April 2008


Ternary single-source precursors for polycrystalline thin-film solar cells
journal, January 2002

  • Banger, Kulbinder K.; Hollingsworth, Jennifer A.; Harris, Jerry D.
  • Applied Organometallic Chemistry, Vol. 16, Issue 11, p. 617-627
  • https://doi.org/10.1002/aoc.362

Microwave-Assisted Chemical Reactions
journal, December 2003


Rapid synthesis and size control of CuInS2 semi-conductor nanoparticles using microwave irradiation
journal, October 2007


Physico-chemical characterisation of Cu(In,Al)Se2 thin film for solar cells obtained by a selenisation process
journal, June 2005


Preparation of Ultrafine Chalcopyrite Nanoparticles via the Photochemical Decomposition of Molecular Single-Source Precursors
journal, June 2006


Optimization of Microwave Digestion for Mercury Determination in Marine Biological Samples by Cold Vapour Atomic Absorption Spectrometry
journal, April 2006


Pulsed-Spray Radiofrequency Plasma Enhanced Chemical Vapor Deposition of CuInS2 Thin Films
journal, April 2006


Hybrid Nanorod-Polymer Solar Cells
journal, March 2002


One-Pot Synthesis of Copper−Indium Sulfide Nanocrystal Heterostructures with Acorn, Bottle, and Larva Shapes
journal, March 2006


Microwave assisted synthesis – a critical technology overview
journal, January 2004


Optimisation of microwave assisted digestion of sediments and determination of Sn and Hg
journal, April 2006


Preparation of meso-porous TiO2 gels and their characterization
journal, June 2001


Applications of microwave dielectric heating in environment-related heterogeneous gas-phase catalytic systems
journal, August 2006


Microwave-Enhanced Reaction Rates for Nanoparticle Synthesis
journal, November 2005


Synthesis of Metastable Wurtzite CuInSe 2 Nanocrystals
journal, March 2010


Synthesis and Characterization of Nanostructured Wurtzite CuInS 2 : A New Cation Disordered Polymorph of CuInS 2
journal, February 2009


Novel Bimetallic Thiocarboxylate Compounds as Single-Source Precursors to Binary and Ternary Metal Sulfide Materials
journal, June 2003


Nanometer-sized semiconductor clusters: materials synthesis, quantum size effects, and photophysical properties
journal, January 1991


Synthesis and Characterization of the First Liquid Single-Source Precursors for the Deposition of Ternary Chalcopyrite (CuInS 2 ) Thin Film Materials
journal, November 2001


Changes in carrier dynamics induced by proton irradiation in quantum dots
journal, March 2002


Synthesis of CuInS 2 Nanocubes by a Wet Chemical Process
journal, September 2005


Influence of Calcination Temperature on the Microstructure of Porous TiO<sub>2</sub> Film
journal, January 2008


Comparison of three optimized digestion methods for rapid determination of chemical oxygen demand: Closed microwaves, open microwaves and ultrasound irradiation
journal, March 2006