Thermoset polymers via ring opening metathesis polymerization of functionalized oils
Abstract
The invention provides a method for producing a thermosetting resin from renewable oils, the method comprising supplying renewable oil molecules containing strained ring alkene moieties; reacting the alkene moieties with cyclic alkenes to create a polymer; and repeating the above two steps until the resin having desired characteristics are obtained. Also provided is a thermoset resin comprising functionalized renewable oil polymerized with a co-monomer.
- Inventors:
- Issue Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1080287
- Patent Number(s):
- 8318876
- Application Number:
- 13/357,739
- Assignee:
- U.S. Department of Energy (Washington, DC)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C - CHEMISTRY C09 - DYES C09D - COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS
- DOE Contract Number:
- AC02-07CH11358
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Larock, Richard C, Henna, Phillip H, and Kessier, Michael R. Thermoset polymers via ring opening metathesis polymerization of functionalized oils. United States: N. p., 2012.
Web.
Larock, Richard C, Henna, Phillip H, & Kessier, Michael R. Thermoset polymers via ring opening metathesis polymerization of functionalized oils. United States.
Larock, Richard C, Henna, Phillip H, and Kessier, Michael R. Tue .
"Thermoset polymers via ring opening metathesis polymerization of functionalized oils". United States. https://www.osti.gov/servlets/purl/1080287.
@article{osti_1080287,
title = {Thermoset polymers via ring opening metathesis polymerization of functionalized oils},
author = {Larock, Richard C and Henna, Phillip H and Kessier, Michael R},
abstractNote = {The invention provides a method for producing a thermosetting resin from renewable oils, the method comprising supplying renewable oil molecules containing strained ring alkene moieties; reacting the alkene moieties with cyclic alkenes to create a polymer; and repeating the above two steps until the resin having desired characteristics are obtained. Also provided is a thermoset resin comprising functionalized renewable oil polymerized with a co-monomer.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2012},
month = {11}
}
Works referenced in this record:
Synthesis and Photoinitiated Cationic Polymerization Of Epoxidized Castor Oil and Its Derivatives
journal, January 1998
- Chakrapani, S.; Crivello*, J. V.
- Journal of Macromolecular Science, Part A, Vol. 35, Issue 1
Catalyst Morphology and Dissolution Kinetics of Self-Healing Polymers
journal, March 2006
- Jones, Alan S.; Rule, Joseph D.; Moore, Jeffrey S.
- Chemistry of Materials, Vol. 18, Issue 5
Analyzing biodiesel: standards and other methods
journal, October 2006
- Knothe, Gerhard
- Journal of the American Oil Chemists' Society, Vol. 83, Issue 10
Ring-opening metathesis polymerization of a modified linseed oil with varying levels of crosslinking
journal, October 2008
- Mauldin, T. C.; Haman, K.; Sheng, X.
- Journal of Polymer Science Part A: Polymer Chemistry, Vol. 46, Issue 20
Mechanical properties of linseed oil monoglyceride maleate/styrene copolymers
journal, January 2005
- Mosiewicki, M.; Aranguren, M. I.; Borrajo, J.
- Journal of Applied Polymer Science, Vol. 97, Issue 3
Synthesis and Characterization of Polymeric Linseed Oil Grafted Methyl Methacrylate or Styrene
journal, July 2004
- Cakmakli, Birten; Hazer, Baki; Tekin, Ishak Ozel
- Macromolecular Bioscience, Vol. 4, Issue 7
Rubbery Thermosets by Ring-Opening Metathesis Polymerization of a Functionalized Castor Oil and Cyclooctene
journal, November 2007
- Henna, Phillip H.; Larock, Richard C.
- Macromolecular Materials and Engineering, Vol. 292, Issue 12
Structure and Properties of Polyurethanes Prepared from Triglyceride Polyols by Ozonolysis
journal, March 2005
- Petrović, Zoran S.; Zhang, Wei; Javni, Ivan
- Biomacromolecules, Vol. 6, Issue 2