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Title: Thermoset polymers via ring opening metathesis polymerization of functionalized oils

Abstract

The invention provides a method for producing a thermosetting resin from renewable oils, the method comprising supplying renewable oil molecules containing strained ring alkene moieties; reacting the alkene moieties with cyclic alkenes to create a polymer; and repeating the above two steps until the resin having desired characteristics are obtained. Also provided is a thermoset resin comprising functionalized renewable oil polymerized with a co-monomer.

Inventors:
; ;
Issue Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1080287
Patent Number(s):
8318876
Application Number:
13/357,739
Assignee:
U.S. Department of Energy (Washington, DC)
Patent Classifications (CPCs):
C - CHEMISTRY C09 - DYES C09D - COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
DOE Contract Number:  
AC02-07CH11358
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Larock, Richard C, Henna, Phillip H, and Kessier, Michael R. Thermoset polymers via ring opening metathesis polymerization of functionalized oils. United States: N. p., 2012. Web.
Larock, Richard C, Henna, Phillip H, & Kessier, Michael R. Thermoset polymers via ring opening metathesis polymerization of functionalized oils. United States.
Larock, Richard C, Henna, Phillip H, and Kessier, Michael R. Tue . "Thermoset polymers via ring opening metathesis polymerization of functionalized oils". United States. https://www.osti.gov/servlets/purl/1080287.
@article{osti_1080287,
title = {Thermoset polymers via ring opening metathesis polymerization of functionalized oils},
author = {Larock, Richard C and Henna, Phillip H and Kessier, Michael R},
abstractNote = {The invention provides a method for producing a thermosetting resin from renewable oils, the method comprising supplying renewable oil molecules containing strained ring alkene moieties; reacting the alkene moieties with cyclic alkenes to create a polymer; and repeating the above two steps until the resin having desired characteristics are obtained. Also provided is a thermoset resin comprising functionalized renewable oil polymerized with a co-monomer.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2012},
month = {11}
}

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Works referenced in this record:

Synthesis and Photoinitiated Cationic Polymerization Of Epoxidized Castor Oil and Its Derivatives
journal, January 1998


Catalyst Morphology and Dissolution Kinetics of Self-Healing Polymers
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Analyzing biodiesel: standards and other methods
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Ring-opening metathesis polymerization of a modified linseed oil with varying levels of crosslinking
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Mechanical properties of linseed oil monoglyceride maleate/styrene copolymers
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Synthesis and Characterization of Polymeric Linseed Oil Grafted Methyl Methacrylate or Styrene
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Rubbery Thermosets by Ring-Opening Metathesis Polymerization of a Functionalized Castor Oil and Cyclooctene
journal, November 2007


Structure and Properties of Polyurethanes Prepared from Triglyceride Polyols by Ozonolysis
journal, March 2005