DOE Patents title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Tetratopic phenyl compounds, related metal-organic framework materials and post-assembly elaboration

Abstract

Disclosed are tetratopic carboxylic acid phenyl for use in metal-organic framework compounds. These compounds are useful in catalysis, gas storage, sensing, biological imaging, drug delivery and gas adsorption separation.

Inventors:
;
Issue Date:
Research Org.:
Northwestern University (Evanston, IL)
Sponsoring Org.:
USDOE
OSTI Identifier:
1078267
Patent Number(s):
8262775
Application Number:
12/578,357
Assignee:
Northwestern University (Evanston, IL)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
DOE Contract Number:  
FG02-01ER15244
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Farha, Omar K., and Hupp, Joseph T. Tetratopic phenyl compounds, related metal-organic framework materials and post-assembly elaboration. United States: N. p., 2012. Web.
Farha, Omar K., & Hupp, Joseph T. Tetratopic phenyl compounds, related metal-organic framework materials and post-assembly elaboration. United States.
Farha, Omar K., and Hupp, Joseph T. Tue . "Tetratopic phenyl compounds, related metal-organic framework materials and post-assembly elaboration". United States. https://www.osti.gov/servlets/purl/1078267.
@article{osti_1078267,
title = {Tetratopic phenyl compounds, related metal-organic framework materials and post-assembly elaboration},
author = {Farha, Omar K. and Hupp, Joseph T.},
abstractNote = {Disclosed are tetratopic carboxylic acid phenyl for use in metal-organic framework compounds. These compounds are useful in catalysis, gas storage, sensing, biological imaging, drug delivery and gas adsorption separation.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Sep 11 00:00:00 EDT 2012},
month = {Tue Sep 11 00:00:00 EDT 2012}
}

Works referenced in this record:

Tandem Modification of Metal–Organic Frameworks by a Postsynthetic Approach
journal, June 2008


A Chemically Functionalizable Nanoporous Material [Cu3(TMA)2(H2O)3]n
journal, February 1999


A homochiral metal–organic porous material for enantioselective separation and catalysis
journal, April 2000


Li-decorated metal organic framework 5: A route to achieving a suitable hydrogen storage medium
journal, December 2007


Ligand-elaboration as a strategy for engendering structural diversity in porous metal–organic framework compounds
journal, January 2008


High H2 Adsorption in a Microporous Metal-Organic Framework with Open Metal Sites
journal, July 2005


Chemical Reduction of Metal−Organic Framework Materials as a Method to Enhance Gas Uptake and Binding
journal, August 2007


Why Li Doping in MOFs Enhances H 2 Storage Capacity? A Multi-scale Theoretical Study
journal, April 2008


Adsorption and separation of hydrogen isotopes in carbon nanotubes: Multicomponent grand canonical Monte Carlo simulations
journal, January 2002


Metal−Organic Frameworks Based on Double-Bond-Coupled Di-Isophthalate Linkers with High Hydrogen and Methane Uptakes
journal, May 2008


Hydrogen storage in metal–organic frameworks
journal, January 2007


Hydrogen-Bonded Supramolecular Architectures of Organic Salts Based on Aromatic Tetracarboxylic Acids and Amines
journal, November 2006


Chiral Porous Hybrid Solids for Practical Heterogeneous Asymmetric Hydrogenation of Aromatic Ketones
journal, September 2003


Single-crystal structure validation with the program PLATON
journal, January 2003


Covalent surface modification of a metal–organic framework: selective surface engineering via CuI-catalyzed Huisgen cycloaddition
journal, January 2008


Postsynthetic Covalent Modification of a Neutral Metal−Organic Framework
journal, October 2007


Hydrogen Storage in a Microporous Metal−Organic Framework with Exposed Mn 2+ Coordination Sites
journal, December 2006


Molecular Simulation of Carbon Dioxide/Methane/Hydrogen Mixture Adsorption in Metal−Organic Frameworks
journal, September 2006


Metal–Organic Frameworks as Efficient Materials for Drug Delivery
journal, September 2006


Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002


Hydrogen Storage in the Giant-Pore Metal–Organic Frameworks MIL-100 and MIL-101
journal, December 2006


Prospects for nanoporous metal-organic materials in advanced separations processes
journal, January 2004


Microporous Pillared Paddle-Wheel Frameworks Based on Mixed-Ligand Coordination of Zinc Ions
journal, July 2005


Preparation, Clathration Ability, and Catalysis of a Two-Dimensional Square Network Material Composed of Cadmium(II) and 4,4'-Bipyridine
journal, February 1994


Synthesis and Hydrogen Sorption Properties of Carborane Based Metal−Organic Framework Materials
journal, October 2007


Carborane-based metal–organic frameworks as highly selective sorbents for CO2 over methane
journal, January 2008


The current status of hydrogen storage in metal–organic frameworks
journal, January 2008


Supermolecular Building Blocks (SBBs) for the Design and Synthesis of Highly Porous Metal-Organic Frameworks
journal, February 2008


Alkali Metal Cation Effects on Hydrogen Uptake and Binding in Metal-Organic Frameworks
journal, September 2008


Hybrid porous solids past, present, future
journal, January 2008


Enhanced Hydrogen Uptake and the Electronic Structure of Lithium-Doped Metal−Organic Frameworks
journal, May 2008


Systematic Functionalization of a Metal−Organic Framework via a Postsynthetic Modification Approach
journal, July 2008


Nanoscale Metal−Organic Frameworks as Potential Multimodal Contrast Enhancing Agents
journal, July 2006


A metal–organic framework material that functions as an enantioselective catalyst for olefin epoxidation
journal, January 2006


Separation of CO 2 from CH 4 Using Mixed-Ligand Metal−Organic Frameworks
journal, August 2008


Strong H 2 Binding and Selective Gas Adsorption within the Microporous Coordination Solid Mg 3 (O 2 C-C 10 H 6 -CO 2 ) 3
journal, July 2005


Virial-type thermal equation of gas—solid adsorption
journal, January 1989


Chiral porous coordination networks: rational design and applications in enantioselective processes
journal, November 2003


A Homochiral Porous Metal−Organic Framework for Highly Enantioselective Heterogeneous Asymmetric Catalysis
journal, June 2005


Multifunctionality and Crystal Dynamics of a Highly Stable, Porous Metal−Organic Framework [Zn 4 O(NTB) 2 ]
journal, May 2005


Atomistic Simulations of CO 2 and N 2 Adsorption in Silica Zeolites:  The Impact of Pore Size and Shape
journal, August 2002


Amine Grafting on Coordinatively Unsaturated Metal Centers of MOFs: Consequences for Catalysis and Metal Encapsulation
journal, May 2008


Molecular simulation of separation of CO2 from flue gases in CU-BTC metal-organic framework
journal, January 2007