System and method for producing substitute natural gas from coal

Hobbs, Raymond

Title: System and method for producing substitute natural gas from coal

Abstract

The present invention provides a system and method for producing substitute natural gas and electricity, while mitigating production of any greenhouse gasses. The system includes a hydrogasification reactor, to form a gas stream including natural gas and a char stream, and an oxygen burner to combust the char material to form carbon oxides. The system also includes an algae farm to convert the carbon oxides to hydrocarbon material and oxygen.

Inventors:

Hobbs, Raymond ^[1]

Avondale, AZ

Issue Date:: 2012-08-07

Research Org.:: National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1061450

Patent Number(s):: 8236072

Application Number:: 12/084,845

Assignee:: Arizona Public Service Company (Phoenix, AZ)

Patent Classifications (CPCs):: C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10J - PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES

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C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B2203/0485 - the impurity being a sulfur compound
C01B3/56 - by contacting with solids

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10J - PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES
C10J2300/1606 - Combustion processes

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B3/586 - {the reaction being a methanation reaction}

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
C10G27/04 - with oxygen or compounds generating oxygen

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B2203/048 - the impurity being an organic compound

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10J - PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES
C10J2300/1807 - Recycle loops, e.g. gas, solids, heating medium, water
C10J2300/093 - Coal
C10J2300/1693 - with storage facilities for intermediate, feed and/or product

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B2203/042 - Purification by adsorption on solids
C01B2203/0475 - the impurity being carbon dioxide

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/36 - Hydrogen production from non-carbon containing sources

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10L - FUELS NOT OTHERWISE PROVIDED FOR
C10L3/08 - Production of synthetic natural gas

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
Y02P30/00 - Technologies relating to oil refining and petrochemical industry

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10J - PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES
C10J2300/1637 - Char combustion
C10J2300/0969 - Carbon dioxide

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
C10G2300/405 - Limiting CO, NOx or SOx emissions

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10J - PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES
C10J2300/1675 - making use of a steam turbine
C10J2300/1671 - with the production of electricity
C10J2300/094 - Char

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
Y02P30/20 - Bio-feedstock

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
C10G2300/4043 - Limiting CO2 emissions

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B2203/0405 - Purification by membrane separation

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10J - PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES
C10J2300/1662 - to methane

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10L - FUELS NOT OTHERWISE PROVIDED FOR
C10L3/10 - Working-up natural gas or synthetic natural gas

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10K - PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
C10K1/004 - {Sulfur containing contaminants, e.g. hydrogen sulfide}

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10J - PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES
C10J2300/0959 - Oxygen

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10L - FUELS NOT OTHERWISE PROVIDED FOR
C10L5/44 - on vegetable substances

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E50/10 - Biofuels

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10J - PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES
C10J2300/1684 - with electrolysis of water

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
C10G3/50 - {in the presence of hydrogen, hydrogen donors or hydrogen generating compounds}

C - CHEMISTRY C25 - ELECTROLYTIC OR ELECTROPHORETIC PROCESSES C25B - ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS
C25B1/04 - by electrolysis of water

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B3/501 - {by diffusion}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E50/30 - Fuel from waste

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
C10G2300/1014 - of vegetal origin

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10L - FUELS NOT OTHERWISE PROVIDED FOR
C10L3/102 - {of acid contaminants}

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10J - PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES
C10J2300/1681 - with biological plants, e.g. involving bacteria, algae, fungi

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B2203/0495 - the impurity being water

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10J - PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES
C10J3/485 - {Entrained flow gasifiers}

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
C10G2300/205 - Metal content

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10J - PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES
C10J3/466 - {Entrained flow processes}
C10J3/84 - with means for removing dust or tar from the gas

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
C10G2300/202 - Heteroatoms content, i.e. S, N, O, P

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10J - PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES
C10J2300/0966 - Hydrogen
C10J2300/1687 - with steam generation

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B2203/0445 - Selective methanation
C01B2203/0465 - Composition of the impurity
C01B2203/047 - the impurity being carbon monoxide

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10K - PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
C10K1/02 - Dust removal

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DOE Contract Number:: FC26-06NT42759

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 01 COAL, LIGNITE, AND PEAT; 03 NATURAL GAS

Citation Formats


                    Hobbs, Raymond. System and method for producing substitute natural gas from coal.  United States: N. p., 2012. 
        Web.

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                    Hobbs, Raymond. System and method for producing substitute natural gas from coal.  United States.

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                    Hobbs, Raymond. Tue .  
        "System and method for producing substitute natural gas from coal".  United States.  https://www.osti.gov/servlets/purl/1061450.

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@article{osti_1061450,

  title        = {System and method for producing substitute natural gas from coal},

  author       = {Hobbs, Raymond},

  abstractNote = {The present invention provides a system and method for producing substitute natural gas and electricity, while mitigating production of any greenhouse gasses. The system includes a hydrogasification reactor, to form a gas stream including natural gas and a char stream, and an oxygen burner to combust the char material to form carbon oxides. The system also includes an algae farm to convert the carbon oxides to hydrocarbon material and oxygen.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2012},

  month        = {8}

}

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Works referenced in this record:

Utilization of macro-algae for enhanced CO₂ fixation and biofuels production: Development of a computing software for an LCA study
journal, October 2005

Aresta, Michele; Dibenedetto, Angela; Barberio, Grazia
Fuel Processing Technology, Vol. 86, Issue 14-15, p. 1679-1693
https://doi.org/10.1016/j.fuproc.2005.01.016

Microalgal cultivation in a solution recovered from the low-temperature catalytic gasification of the microalga
journal, January 2001

Tsukahara, Kenichiro; Kimura, Tae; Minowa, Tomoaki
Journal of Bioscience and Bioengineering, Vol. 91, Issue 3
https://doi.org/10.1016/S1389-1723(01)80140-7

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Title: System and method for producing substitute natural gas from coal

Abstract

Citation Formats

Utilization of macro-algae for enhanced CO2 fixation and biofuels production: Development of a computing software for an LCA study journal, October 2005

Microalgal cultivation in a solution recovered from the low-temperature catalytic gasification of the microalga journal, January 2001

Utilization of macro-algae for enhanced CO₂ fixation and biofuels production: Development of a computing software for an LCA study
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Microalgal cultivation in a solution recovered from the low-temperature catalytic gasification of the microalga
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