Non-stoichiometric mixed-phase titania photocatalyst
Abstract
A mixed anatase-rutile phase, non-stoichiometric titania photocatalyst material is a highly reactive and is a UV and visible light responsive photocastalyst in the as-deposited condition (i.e. without the need for a subsequent thermal treatment). The mixed phase, non-stoichiometric titania thin film material is non-stoichiometric in terms of its oxygen content such that the thin film material shows a marked red-shift in photoresponse.
- Inventors:
-
- Lakewood, CO
- Evanston, IL
- Issue Date:
- Research Org.:
- Northwestern University (Evanston, IL)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1055501
- Patent Number(s):
- 8202820
- Application Number:
- 12/583,763
- Assignee:
- Northwestern University (Evanston, IL)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10L - FUELS NOT OTHERWISE PROVIDED FOR
- DOE Contract Number:
- FG02-03ER15457; AC02-06CH1135
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Chen, Le, Gray, Kimberly A, and Graham, Michael E. Non-stoichiometric mixed-phase titania photocatalyst. United States: N. p., 2012.
Web.
Chen, Le, Gray, Kimberly A, & Graham, Michael E. Non-stoichiometric mixed-phase titania photocatalyst. United States.
Chen, Le, Gray, Kimberly A, and Graham, Michael E. Tue .
"Non-stoichiometric mixed-phase titania photocatalyst". United States. https://www.osti.gov/servlets/purl/1055501.
@article{osti_1055501,
title = {Non-stoichiometric mixed-phase titania photocatalyst},
author = {Chen, Le and Gray, Kimberly A and Graham, Michael E},
abstractNote = {A mixed anatase-rutile phase, non-stoichiometric titania photocatalyst material is a highly reactive and is a UV and visible light responsive photocastalyst in the as-deposited condition (i.e. without the need for a subsequent thermal treatment). The mixed phase, non-stoichiometric titania thin film material is non-stoichiometric in terms of its oxygen content such that the thin film material shows a marked red-shift in photoresponse.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jun 19 00:00:00 EDT 2012},
month = {Tue Jun 19 00:00:00 EDT 2012}
}
Works referenced in this record:
A comparison of mixed phase titania photocatalysts prepared by physical and chemical methods: The importance of the solid–solid interface
journal, September 2007
- Li, Gonghu; Chen, Le; Graham, Michael E.
- Journal of Molecular Catalysis A: Chemical, Vol. 275, Issue 1-2
Photocatalytic Process for CO 2 Emission Reduction from Industrial Flue Gas Streams
journal, April 2006
- Usubharatana, Phairat; McMartin, Dena; Veawab, Amornvadee
- Industrial & Engineering Chemistry Research, Vol. 45, Issue 8
Probing reaction mechanisms in mixed phase TiO2 by EPR
journal, February 2006
- Hurum, D. C.; Agrios, A. G.; Crist, S. E.
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 150, Issue 2-3, p. 155-163
The effect of substrate temperature on the properties of d.c. reactive magnetron sputtered titanium oxide films
journal, February 1993
- Meng, Li-jian; Andritschky, M.; dos Santos, M. P.
- Thin Solid Films, Vol. 223, Issue 2
Visible Light Absorption by Various Titanium Dioxide Specimens †
journal, December 2006
- Kuznetsov, Vyacheslav N.; Serpone, Nick
- The Journal of Physical Chemistry B, Vol. 110, Issue 50
Preparation of Polycrystalline TiO 2 Photocatalysts Impregnated with Various Transition Metal Ions: Characterization and Photocatalytic Activity for the Degradation of 4-Nitrophenol
journal, January 2002
- Di Paola, A.; Marcì, G.; Palmisano, L.
- The Journal of Physical Chemistry B, Vol. 106, Issue 3
Photocatalytic activity of rutile–anatase coupled TiO2 particles prepared by a dissolution–reprecipitation method
journal, November 2003
- Kawahara, Tetsuro; Ozawa, Toshiaki; Iwasaki, Mitsunobu
- Journal of Colloid and Interface Science, Vol. 267, Issue 2
Synthesizing mixed-phase TiO2 nanocomposites using a hydrothermal method for photo-oxidation and photoreduction applications
journal, January 2008
- Li, G.; Ciston, S.; Saponjic, Z.
- Journal of Catalysis, Vol. 253, Issue 1
Photocatalytic TiO2 thin film deposited onto glass by DC magnetron sputtering
journal, July 2001
- Takeda, Satoshi; Suzuki, Susumu; Odaka, Hidefumi
- Thin Solid Films, Vol. 392, Issue 2
Visible-Light Photocatalysis in Nitrogen-Doped Titanium Oxides
journal, July 2001
- Asahi, R.
- Science, Vol. 293, Issue 5528
Fundamental understanding and modeling of reactive sputtering processes
journal, April 2005
- Berg, S.; Nyberg, T.
- Thin Solid Films, Vol. 476, Issue 2
Process stabilization and increase of the deposition rate in reactive sputtering of metal oxides and oxynitrides
journal, April 2006
- Severin, D.; Kappertz, O.; Kubart, T.
- Applied Physics Letters, Vol. 88, Issue 16
Reactive d.c. magnetron sputtering of the oxides of Ti, Zr, and Hf
journal, February 1997
- Sproul, William D.; Graham, Michael E.; Wong, Ming-Show
- Surface and Coatings Technology, Vol. 89, Issue 1-2
Electrochemical Photolysis of Water at a Semiconductor Electrode
journal, July 1972
- Fujishima, Akira; Honda, Kenichi
- Nature, Vol. 238, Issue 5358, p. 37-38
Fabricating highly active mixed phase TiO2 photocatalysts by reactive DC magnetron sputter deposition
journal, November 2006
- Chen, Le; Graham, Michael E.; Li, Gonghu
- Thin Solid Films, Vol. 515, Issue 3, p. 1176-1181
Explaining the Enhanced Photocatalytic Activity of Degussa P25 Mixed-Phase TiO 2 Using EPR
journal, May 2003
- Hurum, Deanna C.; Agrios, Alexander G.; Gray, Kimberly A.
- The Journal of Physical Chemistry B, Vol. 107, Issue 19
Reactive direct current magnetron sputtering of aluminum oxide coatings
journal, May 1995
- Sproul, W. D.; Graham, M. E.; Wong, M. S.
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 13, Issue 3
Nitrogen stabilized reactive sputtering of optimized TiO2−x photocatalysts with visible light reactivity
journal, July 2009
- Chen, Le; Graham, Michael E.; Gray, Kimberly A.
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 27, Issue 4
Hysteresis effects in the sputtering process using two reactive gases
journal, May 1995
- Baránková, H.; Berg, S.; Carlsson, P.
- Thin Solid Films, Vol. 260, Issue 2
Photocatalysis for new energy production
journal, April 2007
- Matsuoka, Masaya; Kitano, Masaaki; Takeuchi, Masato
- Catalysis Today, Vol. 122, Issue 1-2
Recombination Pathways in the Degussa P25 Formulation of TiO 2 : Surface versus Lattice Mechanisms
journal, January 2005
- Hurum, Deanna C.; Gray, Kimberly A.; Rajh, Tijana
- The Journal of Physical Chemistry B, Vol. 109, Issue 2
Extending the Photoresponse of TiO 2 to the Visible Light Region: Photoelectrochemical Behavior of TiO 2 Thin Films Prepared by the Radio Frequency Magnetron Sputtering Deposition Method
journal, March 2006
- Kikuchi, Hisashi; Kitano, Masaaki; Takeuchi, Masato
- The Journal of Physical Chemistry B, Vol. 110, Issue 11
Effect of rutile phase on the photocatalytic properties of nanocrystalline titania during the degradation of p-coumaric acid
journal, March 1998
- Bacsa, R. R.; Kiwi, J.
- Applied Catalysis B: Environmental, Vol. 16, Issue 1
TiO2: As a versatile catalyst for the ortho-selective methylation of phenol
journal, September 2005
- Gandhe, Aditi R.; Fernandes, Julio B.; Varma, Salil
- Journal of Molecular Catalysis A: Chemical, Vol. 238, Issue 1-2
Formation of ZnO nanostructures by a simple way of thermal evaporation
journal, July 2002
- Yao, B. D.; Chan, Y. F.; Wang, N.
- Applied Physics Letters, Vol. 81, Issue 4
Is the Band Gap of Pristine TiO 2 Narrowed by Anion- and Cation-Doping of Titanium Dioxide in Second-Generation Photocatalysts?
journal, December 2006
- Serpone, Nick
- The Journal of Physical Chemistry B, Vol. 110, Issue 48
Adsorption and Reaction of CO and CO 2 on Oxidized and Reduced SrTiO 3 (100) Surfaces
journal, May 2005
- Azad, Samina; Engelhard, Mark H.; Wang, Li-Qiong
- The Journal of Physical Chemistry B, Vol. 109, Issue 20
Preparation of Mixed-Phase Titanium Dioxide Nanocomposites via Solvothermal Processing
journal, March 2007
- Li, Gonghu; Gray, Kimberly A.
- Chemistry of Materials, Vol. 19, Issue 5
Thermodynamic analysis of phase stability of nanocrystalline titania
journal, January 1998
- Zhang, Hengzhong; Banfield, Jillian F.
- Journal of Materials Chemistry, Vol. 8, Issue 9
Effects of Single Metal-Ion Doping on the Visible-Light Photoreactivity of TiO 2
journal, December 2009
- Choi, Jina; Park, Hyunwoong; Hoffmann, Michael R.
- The Journal of Physical Chemistry C, Vol. 114, Issue 2
Preparation, Characterization, and Reactivities of Highly Functional Titanium Oxide-Based Photocatalysts Able to Operate under UV–Visible Light Irradiation: Approaches in Realizing High Efficiency in the Use of Visible Light
journal, August 2004
- Anpo, Masakazu
- Bulletin of the Chemical Society of Japan, Vol. 77, Issue 8
Photoreduction of CO2 by TiO2 nanocomposites synthesized through reactive direct current magnetron sputter deposition
journal, August 2009
- Chen, Le; Graham, Michael E.; Li, Gonghu
- Thin Solid Films, Vol. 517, Issue 19
Nitrogen-Concentration Dependence on Photocatalytic Activity of TiO 2 - x N x Powders
journal, June 2003
- Irie, Hiroshi; Watanabe, Yuka; Hashimoto, Kazuhito
- The Journal of Physical Chemistry B, Vol. 107, Issue 23
TiO2-based Photocatalysis: Surface Defects, Oxygen and Charge Transfer
journal, July 2005
- Thompson, Tracy L.; Yates, John T.
- Topics in Catalysis, Vol. 35, Issue 3-4
Optical properties of TiO2, Y2O3 and CeO2 thin films deposited by electron beam evaporation
journal, February 1993
- Atanassov, George; Thielsch, Roland; Popov, Dimitar
- Thin Solid Films, Vol. 223, Issue 2
Advances in partial-pressure control applied to reactive sputtering
journal, December 1989
- Sproul, W. D.; Rudnik, P. J.; Gogol, C. A.
- Surface and Coatings Technology, Vol. 39-40
Effect of total and oxygen partial pressures on structure of photocatalytic TiO2 films sputtered on unheated substrate
journal, April 2002
- Zeman, P.; Takabayashi, S.
- Surface and Coatings Technology, Vol. 153, Issue 1
Photoinduced Formation of Defects and Nitrogen Stabilization of Color Centers in N-Doped Titanium Dioxide
journal, August 2007
- Emeline, A. V.; Sheremetyeva, N. V.; Khomchenko, N. V.
- The Journal of Physical Chemistry C, Vol. 111, Issue 30
Spin localization for NO adsorption on surface O atoms of metal oxides
journal, April 2006
- Markovits, A.; Mguig, B.; Calatayud, M.
- Catalysis Today, Vol. 113, Issue 3-4
Control of reactive sputtering processes
journal, November 2005
- Sproul, W. D.; Christie, D. J.; Carter, D. C.
- Thin Solid Films, Vol. 491, Issue 1-2, p. 1-17
Visible light photocatalytic properties of anion-doped TiO2 materials prepared from a molecular titanium precursor
journal, January 2008
- Li, Gonghu; Chen, Le; Dimitrijevic, Nada M.
- Chemical Physics Letters, Vol. 451, Issue 1-3
On the investigation of d.c. plasmatron discharges by optical emission spectrometry
journal, October 1982
- Schiller, S.; Heisig, U.; Steinfelder, K.
- Thin Solid Films, Vol. 96, Issue 3
The effect of Nb substitution on synthesis and photo-response of TiO2 thin films prepared by direct current magnetron sputtering
journal, March 2011
- DeSario, Paul A.; Graham, Michael E.; Gelfand, Ryan M.
- Thin Solid Films, Vol. 519, Issue 11
Reactive sputtering of dielectric layers on large scale substrates using an AC twin magnetron cathode
journal, August 1997
- Szczyrbowski, J.; Bräuer, G.; Dicken, W.
- Surface and Coatings Technology, Vol. 93, Issue 1
Reactively sputtered N-doped titanium oxide films as visible-light photocatalyst
journal, January 2006
- Wong, Ming-Show; Pang Chou, Hung; Yang, Tien-Syh
- Thin Solid Films, Vol. 494, Issue 1-2
Nanocolumnar titania thin films uniquely incorporated with carbon for visible light photocatalysis
journal, November 2007
- Wang, Shun-Huei; Chen, Ta-Kun; Rao, K. Koteswara
- Applied Catalysis B: Environmental, Vol. 76, Issue 3-4
Synthesis of Novel Thin-Film Materials by Pulsed Laser Deposition
journal, August 1996
- Lowndes, D. H.; Geohegan, D. B.; Puretzky, A. A.
- Science, Vol. 273, Issue 5277, p. 898-903
Effects of hydrothermal temperature and time on the photocatalytic activity and microstructures of bimodal mesoporous TiO2 powders
journal, January 2007
- Yu, J.; Wang, G.; Cheng, B.
- Applied Catalysis B: Environmental, Vol. 69, Issue 3-4