Extractant compositions for co-extracting cesium and strontium, a method of separating cesium and strontium from an aqueous feed, and calixarene compounds
Abstract
A mixed extractant solvent that includes at least one dialkyloxycalix[4]arenebenzocrown-6 compound, 4',4',(5')-di-(t-butyldicyclohexano)-18-crown-6, at least one modifier, and, optionally, a diluent. The dialkyloxycalix[4]arenebenzocrown-6 compound is 1,3-alternate-25,27-di(octyloxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(decyloxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(dodecyloxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(2-ethylhexyl-1-oxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(3,7-dimethyloctyl-1-oxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(4-butyloctyl-1-oxy)calix[4]arenebenzocrown-6, or combinations thereof. The modifier is a primary alcohol. A method of separating cesium and strontium from an aqueous feed is also disclosed, as are dialkyloxycalix[4]arenebenzocrown-6 compounds and an alcohol modifier.
- Inventors:
-
- Idaho Falls, ID
- Pocatello, ID
- Firth, ID
- Iona, ID
- Moore, ID
- Lubbock, TX
- Oak Ridge, TN
- Knoxville, TN
- Issue Date:
- Research Org.:
- Idaho National Laboratory (INL), Idaho Falls, ID (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1040866
- Patent Number(s):
- 8158088
- Application Number:
- 12/268,189
- Assignee:
- Battelle Energy Alliance, LLC (Idaho Falls, ID)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
- DOE Contract Number:
- AC07-99ID13727; AC07-05ID14517
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Peterman, Dean R, Meikrantz, David H, Law, Jack D, Riddle, Catherine L, Todd, Terry A, Greenhalgh, Mitchell R, Tillotson, Richard D, Bartsch, Richard A, Moyer, Bruce A, Delmau, Laetitia H, and Bonnesen, Peter V. Extractant compositions for co-extracting cesium and strontium, a method of separating cesium and strontium from an aqueous feed, and calixarene compounds. United States: N. p., 2012.
Web.
Peterman, Dean R, Meikrantz, David H, Law, Jack D, Riddle, Catherine L, Todd, Terry A, Greenhalgh, Mitchell R, Tillotson, Richard D, Bartsch, Richard A, Moyer, Bruce A, Delmau, Laetitia H, & Bonnesen, Peter V. Extractant compositions for co-extracting cesium and strontium, a method of separating cesium and strontium from an aqueous feed, and calixarene compounds. United States.
Peterman, Dean R, Meikrantz, David H, Law, Jack D, Riddle, Catherine L, Todd, Terry A, Greenhalgh, Mitchell R, Tillotson, Richard D, Bartsch, Richard A, Moyer, Bruce A, Delmau, Laetitia H, and Bonnesen, Peter V. Tue .
"Extractant compositions for co-extracting cesium and strontium, a method of separating cesium and strontium from an aqueous feed, and calixarene compounds". United States. https://www.osti.gov/servlets/purl/1040866.
@article{osti_1040866,
title = {Extractant compositions for co-extracting cesium and strontium, a method of separating cesium and strontium from an aqueous feed, and calixarene compounds},
author = {Peterman, Dean R and Meikrantz, David H and Law, Jack D and Riddle, Catherine L and Todd, Terry A and Greenhalgh, Mitchell R and Tillotson, Richard D and Bartsch, Richard A and Moyer, Bruce A and Delmau, Laetitia H and Bonnesen, Peter V},
abstractNote = {A mixed extractant solvent that includes at least one dialkyloxycalix[4]arenebenzocrown-6 compound, 4',4',(5')-di-(t-butyldicyclohexano)-18-crown-6, at least one modifier, and, optionally, a diluent. The dialkyloxycalix[4]arenebenzocrown-6 compound is 1,3-alternate-25,27-di(octyloxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(decyloxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(dodecyloxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(2-ethylhexyl-1-oxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(3,7-dimethyloctyl-1-oxy)calix[4]arenebenzocrown-6, 1,3-alternate-25,27-di(4-butyloctyl-1-oxy)calix[4]arenebenzocrown-6, or combinations thereof. The modifier is a primary alcohol. A method of separating cesium and strontium from an aqueous feed is also disclosed, as are dialkyloxycalix[4]arenebenzocrown-6 compounds and an alcohol modifier.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2012},
month = {4}
}
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