Carbon dioxide absorbent and method of using the same

Perry, Robert James; Lewis, Larry Neil; O'Brien, Michael Joseph; Soloveichik, Grigorii Lev; Kniajanski, Sergei; Lam, Tunchiao Hubert; Lee, Julia Lam; Rubinsztajn, Malgorzata Iwona

Title: Carbon dioxide absorbent and method of using the same

Abstract

In accordance with one aspect, the present invention provides an amino-siloxane composition comprising at least one of structures I, II, III, IV or V said compositions being useful for the capture of carbon dioxide from gas streams such as power plant flue gases. In addition, the present invention provides methods of preparing the amino-siloxane compositions are provided. Also provided are methods for reducing the amount of carbon dioxide in a process stream employing the amino-siloxane compositions of the invention as species which react with carbon dioxide to form an adduct with carbon dioxide. The reaction of the amino-siloxane compositions provided by the present invention with carbon dioxide is reversible and thus, the method provides for multicycle use of said compositions.

Inventors:

Perry, Robert James ^[1]; Lewis, Larry Neil ^[2]; O'Brien, Michael Joseph ^[3]; Soloveichik, Grigorii Lev ^[4]; Kniajanski, Sergei ^[3]; Lam, Tunchiao Hubert ^[3]; Lee, Julia Lam ^[1]; Rubinsztajn, Malgorzata Iwona ^[5]

Niskayuna, NY
Scotia, NY
Clifton Park, NY
Latham, NY
Ballston Spa, NY

Issue Date:: 2011-10-04

Research Org.:: National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1029277

Patent Number(s):: 8030509

Application Number:: 12/512,105

Assignee:: General Electric Company (Niskayuna, NY)

Patent Classifications (CPCs):: F - MECHANICAL ENGINEERING F23 - COMBUSTION APPARATUS F23J - REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION

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F - MECHANICAL ENGINEERING F23 - COMBUSTION APPARATUS F23J - REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES
F23J2215/50 - Carbon dioxide

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D53/1475 - {Removing carbon dioxide}
B01D53/1493 - {Selection of liquid materials for use as absorbents}

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DOE Contract Number:: NT0005310

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 20 FOSSIL-FUELED POWER PLANTS

Citation Formats


                    Perry, Robert James, Lewis, Larry Neil, O'Brien, Michael Joseph, Soloveichik, Grigorii Lev, Kniajanski, Sergei, Lam, Tunchiao Hubert, Lee, Julia Lam, and Rubinsztajn, Malgorzata Iwona. Carbon dioxide absorbent and method of using the same.  United States: N. p., 2011. 
        Web.

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                    Perry, Robert James, Lewis, Larry Neil, O'Brien, Michael Joseph, Soloveichik, Grigorii Lev, Kniajanski, Sergei, Lam, Tunchiao Hubert, Lee, Julia Lam, & Rubinsztajn, Malgorzata Iwona. Carbon dioxide absorbent and method of using the same.  United States.

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                    Perry, Robert James, Lewis, Larry Neil, O'Brien, Michael Joseph, Soloveichik, Grigorii Lev, Kniajanski, Sergei, Lam, Tunchiao Hubert, Lee, Julia Lam, and Rubinsztajn, Malgorzata Iwona. Tue .  
        "Carbon dioxide absorbent and method of using the same".  United States.  https://www.osti.gov/servlets/purl/1029277.

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@article{osti_1029277,

  title        = {Carbon dioxide absorbent and method of using the same},

  author       = {Perry, Robert James and Lewis, Larry Neil and O'Brien, Michael Joseph and Soloveichik, Grigorii Lev and Kniajanski, Sergei and Lam, Tunchiao Hubert and Lee, Julia Lam and Rubinsztajn, Malgorzata Iwona},

  abstractNote = {In accordance with one aspect, the present invention provides an amino-siloxane composition comprising at least one of structures I, II, III, IV or V said compositions being useful for the capture of carbon dioxide from gas streams such as power plant flue gases. In addition, the present invention provides methods of preparing the amino-siloxane compositions are provided. Also provided are methods for reducing the amount of carbon dioxide in a process stream employing the amino-siloxane compositions of the invention as species which react with carbon dioxide to form an adduct with carbon dioxide. The reaction of the amino-siloxane compositions provided by the present invention with carbon dioxide is reversible and thus, the method provides for multicycle use of said compositions.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2011},

  month        = {10}

}

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Works referenced in this record:

Ordered mesoporous and macroporous inorganic films and membranes
journal, June 2004

Guliants, V. V.; Carreon, M. A.; Lin, Y. S.
Journal of Membrane Science, Vol. 235, Issue 1-2, p. 53-72
https://doi.org/10.1016/j.memsci.2004.01.019

Progress in carbon dioxide separation and capture: A review
journal, January 2008

Yang, Hongqun; Xu, Zhenghe; Fan, Maohong
Journal of Environmental Sciences, Vol. 20, Issue 1, p. 14-27
https://doi.org/10.1016/S1001-0742(08)60002-9

CO₂ adsorption using amine-functionalized mesoporous silica prepared via anionic surfactant-mediated synthesis
journal, November 2008

Kim, Se-Na; Son, Won-Jin; Choi, Jung-Sik
Microporous and Mesoporous Materials, Vol. 115, Issue 3, p. 497-503
https://doi.org/10.1016/j.micromeso.2008.02.025

Amine loaded zeolites for carbon dioxide capture: Amine loading and adsorption studies
journal, May 2009

Chatti, Ravikrishna; Bansiwal, Amit K.; Thote, Jayashri A.
Microporous and Mesoporous Materials, Vol. 121, Issue 1-3, p. 84-89
https://doi.org/10.1016/j.micromeso.2009.01.007

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Title: Carbon dioxide absorbent and method of using the same

Abstract

Citation Formats

Ordered mesoporous and macroporous inorganic films and membranes journal, June 2004

Progress in carbon dioxide separation and capture: A review journal, January 2008

CO2 adsorption using amine-functionalized mesoporous silica prepared via anionic surfactant-mediated synthesis journal, November 2008

Amine loaded zeolites for carbon dioxide capture: Amine loading and adsorption studies journal, May 2009

Ordered mesoporous and macroporous inorganic films and membranes
journal, June 2004

Progress in carbon dioxide separation and capture: A review
journal, January 2008

CO₂ adsorption using amine-functionalized mesoporous silica prepared via anionic surfactant-mediated synthesis
journal, November 2008

Amine loaded zeolites for carbon dioxide capture: Amine loading and adsorption studies
journal, May 2009