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Title: Efficient reversible electrodes for solid oxide electrolyzer cells

Abstract

An electrolyzer cell is disclosed which includes a cathode to reduce an oxygen-containing molecule, such as H2O, CO2, or a combination thereof, to produce an oxygen ion and a fuel molecule, such as H2, CO, or a combination thereof. An electrolyte is coupled to the cathode to transport the oxygen ion to an anode. The anode is coupled to the electrolyte to receive the oxygen ion and produce oxygen gas therewith. In one embodiment, the anode may be fabricated to include an electron-conducting phase having a perovskite crystalline structure or structure similar thereto. This perovskite may have a chemical formula of substantially (Pr(1-x)Lax)(z-y)A'yBO(3-.differential.), wherein 0.ltoreq.x.ltoreq.0.5, 0.ltoreq.y.ltoreq.0.5, and 0.8.ltoreq.z.ltoreq.1.1. In another embodiment, the cathode includes an electron-conducting phase that contains nickel oxide intermixed with magnesium oxide.

Inventors:
 [1];  [2]
  1. South Jordan, UT
  2. Kaysville, UT
Issue Date:
Research Org.:
Ceramatec, Inc. (Salt Lake City, UT)
Sponsoring Org.:
USDOE
OSTI Identifier:
1019434
Patent Number(s):
7976686
Application Number:
US Patent Application 11/781,718
Assignee:
Ceramatec, Inc. (Salt Lake City, UT)
Patent Classifications (CPCs):
C - CHEMISTRY C25 - ELECTROLYTIC OR ELECTROPHORETIC PROCESSES C25B - ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
DOE Contract Number:  
AC07-05ID14517
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Elangovan, Singaravelu, and Hartvigsen, Joseph J. Efficient reversible electrodes for solid oxide electrolyzer cells. United States: N. p., 2011. Web.
Elangovan, Singaravelu, & Hartvigsen, Joseph J. Efficient reversible electrodes for solid oxide electrolyzer cells. United States.
Elangovan, Singaravelu, and Hartvigsen, Joseph J. Tue . "Efficient reversible electrodes for solid oxide electrolyzer cells". United States. https://www.osti.gov/servlets/purl/1019434.
@article{osti_1019434,
title = {Efficient reversible electrodes for solid oxide electrolyzer cells},
author = {Elangovan, Singaravelu and Hartvigsen, Joseph J},
abstractNote = {An electrolyzer cell is disclosed which includes a cathode to reduce an oxygen-containing molecule, such as H2O, CO2, or a combination thereof, to produce an oxygen ion and a fuel molecule, such as H2, CO, or a combination thereof. An electrolyte is coupled to the cathode to transport the oxygen ion to an anode. The anode is coupled to the electrolyte to receive the oxygen ion and produce oxygen gas therewith. In one embodiment, the anode may be fabricated to include an electron-conducting phase having a perovskite crystalline structure or structure similar thereto. This perovskite may have a chemical formula of substantially (Pr(1-x)Lax)(z-y)A'yBO(3-.differential.), wherein 0.ltoreq.x.ltoreq.0.5, 0.ltoreq.y.ltoreq.0.5, and 0.8.ltoreq.z.ltoreq.1.1. In another embodiment, the cathode includes an electron-conducting phase that contains nickel oxide intermixed with magnesium oxide.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jul 12 00:00:00 EDT 2011},
month = {Tue Jul 12 00:00:00 EDT 2011}
}

Works referenced in this record:

High temperature electrolysis cell performance characterization
journal, January 1986


Oxygen Reduction Activities of Praseodymium Manganites in Alkaline Solution
journal, January 1997


Electrode Performance in Reversible Solid Oxide Fuel Cells
journal, January 2007