Gas adsorption and gas mixture separations using mixed-ligand MOF material

Hupp, Joseph T; Mulfort, Karen L; Snurr, Randall Q; Bae, Youn-Sang

Title: Gas adsorption and gas mixture separations using mixed-ligand MOF material

Abstract

A method of separating a mixture of carbon dioxiode and hydrocarbon gas using a mixed-ligand, metal-organic framework (MOF) material having metal ions coordinated to carboxylate ligands and pyridyl ligands.

Inventors:

Hupp, Joseph T ^[1]; Mulfort, Karen L ^[2]; Snurr, Randall Q ^[3]; Bae, Youn-Sang ^[3]

Northfield, IL
Chicago, IL
Evanston, IL

Issue Date:: 2011-01-04

Research Org.:: Northwestern University (Evanston, IL)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1017468

Patent Number(s):: 7862647

Application Number:: 12/317,774

Assignee:: Northwestern University (Evanston, IL)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10S - TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

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B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D53/047 - Pressure swing adsorption
B01D2257/504 - Carbon dioxide
B01D53/02 - by adsorption, e.g. preparative gas chromatography {
B01D2256/24 - Hydrocarbons

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10S - TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10S95/90 - Solid sorbent

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E50/30 - Fuel from waste

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D2253/204 - Metal organic frameworks

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DOE Contract Number:: FG02-01ER15244

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Hupp, Joseph T, Mulfort, Karen L, Snurr, Randall Q, and Bae, Youn-Sang. Gas adsorption and gas mixture separations using mixed-ligand MOF material.  United States: N. p., 2011. 
        Web.

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                    Hupp, Joseph T, Mulfort, Karen L, Snurr, Randall Q, & Bae, Youn-Sang. Gas adsorption and gas mixture separations using mixed-ligand MOF material.  United States.

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                    Hupp, Joseph T, Mulfort, Karen L, Snurr, Randall Q, and Bae, Youn-Sang. Tue .  
        "Gas adsorption and gas mixture separations using mixed-ligand MOF material".  United States.  https://www.osti.gov/servlets/purl/1017468.

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@article{osti_1017468,

  title        = {Gas adsorption and gas mixture separations using mixed-ligand MOF material},

  author       = {Hupp, Joseph T and Mulfort, Karen L and Snurr, Randall Q and Bae, Youn-Sang},

  abstractNote = {A method of separating a mixture of carbon dioxiode and hydrocarbon gas using a mixed-ligand, metal-organic framework (MOF) material having metal ions coordinated to carboxylate ligands and pyridyl ligands.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2011},

  month        = {1}

}

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Works referenced in this record:

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Cavenati, Simone; Grande, Carlos A.; Rodrigues, Alírio E.
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Electrostatic-Field-Induced Enhancement of Gas Mixture Separation in Metal-Organic Frameworks: A Computational Study
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Yang, Qingyuan; Zhong, Chongli
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SAPO-34 membranes for CO2/CH4 separation
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Kinetic Separation of Landfill Gas by a Two-Bed Pressure Swing Adsorption Process Packed with Carbon Molecular Sieve: Nonisothermal Operation
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Kim, Min-Bae; Bae, Youn-Sang; Choi, Dae-Ki
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Similar Records

Title: Gas adsorption and gas mixture separations using mixed-ligand MOF material

Abstract

Citation Formats

Adsorption Equilibrium of Methane, Carbon Dioxide, and Nitrogen on Zeolite 13X at High Pressures journal, July 2004

Removal of Carbon Dioxide from Natural Gas by Vacuum Pressure Swing Adsorption journal, November 2006

Strategies for Hydrogen Storage in Metal-Organic Frameworks journal, July 2005

Electrostatic-Field-Induced Enhancement of Gas Mixture Separation in Metal-Organic Frameworks: A Computational Study journal, June 2006

SAPO-34 membranes for CO2/CH4 separation journal, September 2004

Thermodynamics of mixed-gas adsorption journal, January 1965

Molecular Simulation of Carbon Dioxide/Methane/Hydrogen Mixture Adsorption in Metal−Organic Frameworks journal, September 2006

Kinetic Separation of Landfill Gas by a Two-Bed Pressure Swing Adsorption Process Packed with Carbon Molecular Sieve: Nonisothermal Operation journal, July 2006

Kinetic separation of methane—carbon dioxide mixture by adsorption on molecular sieve carbon journal, January 1989

Storage and Separation of CO 2 and CH 4 in Silicalite, C 168 Schwarzite, and IRMOF-1: A Comparative Study from Monte Carlo Simulation journal, January 2007

Prospects for nanoporous metal-organic materials in advanced separations processes journal, January 2004

Adsorption separation of N2, O2, CO2 and CH4 gases by β-zeolite journal, January 2007

Carbon dioxide-methane mixture adsorption on activated carbon journal, January 2006

Metal–organic frameworks—prospective industrial applications journal, January 2006

Synthesis of MIL-102, a Chromium Carboxylate Metal−Organic Framework, with Gas Sorption Analysis journal, November 2006

Novel Ag+-zeolite/polymer mixed matrix membranes with a high CO2/CH4 selectivity journal, January 2007

Adsorption separation of CH4/CO2 on mesocarbon microbeads: Experiment and modeling journal, January 2006

Adsorption Equilibrium of Methane, Carbon Dioxide, and Nitrogen on Zeolite 13X at High Pressures
journal, July 2004

Removal of Carbon Dioxide from Natural Gas by Vacuum Pressure Swing Adsorption
journal, November 2006

Strategies for Hydrogen Storage in Metal-Organic Frameworks
journal, July 2005

Electrostatic-Field-Induced Enhancement of Gas Mixture Separation in Metal-Organic Frameworks: A Computational Study
journal, June 2006

SAPO-34 membranes for CO2/CH4 separation
journal, September 2004

Thermodynamics of mixed-gas adsorption
journal, January 1965

Molecular Simulation of Carbon Dioxide/Methane/Hydrogen Mixture Adsorption in Metal−Organic Frameworks
journal, September 2006

Kinetic Separation of Landfill Gas by a Two-Bed Pressure Swing Adsorption Process Packed with Carbon Molecular Sieve: Nonisothermal Operation
journal, July 2006

Kinetic separation of methane—carbon dioxide mixture by adsorption on molecular sieve carbon
journal, January 1989

Storage and Separation of CO ₂ and CH ₄ in Silicalite, C ₁₆₈ Schwarzite, and IRMOF-1: A Comparative Study from Monte Carlo Simulation
journal, January 2007

Prospects for nanoporous metal-organic materials in advanced separations processes
journal, January 2004

Adsorption separation of N2, O2, CO2 and CH4 gases by β-zeolite
journal, January 2007

Carbon dioxide-methane mixture adsorption on activated carbon
journal, January 2006

Metal–organic frameworks—prospective industrial applications
journal, January 2006

Synthesis of MIL-102, a Chromium Carboxylate Metal−Organic Framework, with Gas Sorption Analysis
journal, November 2006

Novel Ag+-zeolite/polymer mixed matrix membranes with a high CO2/CH4 selectivity
journal, January 2007

Adsorption separation of CH4/CO2 on mesocarbon microbeads: Experiment and modeling
journal, January 2006