Methods of making alkyl esters
Abstract
A method comprising contacting an alcohol, a feed comprising one or more glycerides and equal to or greater than 2 wt % of one or more free fatty acids, and a solid acid catalyst, a nanostructured polymer catalyst, or a sulfated zirconia catalyst in one or more reactors, and recovering from the one or more reactors an effluent comprising equal to or greater than about 75 wt % alkyl ester and equal to or less than about 5 wt % glyceride.
- Inventors:
-
- Wheat Ridge, CO
- Issue Date:
- Research Org.:
- TDA Research, Inc., Wheat Ridge, CO (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1015772
- Patent Number(s):
- 7767837
- Application Number:
- 11/744,693
- Assignee:
- TDA Research, Inc. (Wheat Ridge, CO)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C11 - ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES C11C - FATTY ACIDS FROM FATS, OILS OR WAXES
- DOE Contract Number:
- FG02-04ER86197
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2007 May 04
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Elliott, Brian. Methods of making alkyl esters. United States: N. p., 2010.
Web.
Elliott, Brian. Methods of making alkyl esters. United States.
Elliott, Brian. Tue .
"Methods of making alkyl esters". United States. https://www.osti.gov/servlets/purl/1015772.
@article{osti_1015772,
title = {Methods of making alkyl esters},
author = {Elliott, Brian},
abstractNote = {A method comprising contacting an alcohol, a feed comprising one or more glycerides and equal to or greater than 2 wt % of one or more free fatty acids, and a solid acid catalyst, a nanostructured polymer catalyst, or a sulfated zirconia catalyst in one or more reactors, and recovering from the one or more reactors an effluent comprising equal to or greater than about 75 wt % alkyl ester and equal to or less than about 5 wt % glyceride.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2010},
month = {8}
}
Works referenced in this record:
The heterogeneous advantage: biodiesel by catalytic reactive distillation
journal, November 2006
- Kiss, Anton A.; Omota, Florin; Dimian, Alexandre C.
- Topics in Catalysis, Vol. 40, Issue 1-4
New multi-phase catalytic systems based on tin compounds active for vegetable oil transesterificaton reaction
journal, March 2005
- Abreu, Frederique R.; Alves, Melquizedeque B.; Macêdo, Caio C. S.
- Journal of Molecular Catalysis A: Chemical, Vol. 227, Issue 1-2
Transesterification of triacetin with methanol on solid acid and base catalysts
journal, November 2005
- López, Dora E.; Goodwin, James G.; Bruce, David A.
- Applied Catalysis A: General, Vol. 295, Issue 2
Heterogeneous Catalysis Using a Nanostructured Solid Acid Resin Based on Lyotropic Liquid Crystals
journal, February 2004
- Xu, Yanjie; Gu, Weiqiang; Gin, Douglas L.
- Journal of the American Chemical Society, Vol. 126, Issue 6
Synthesis of Biodiesel via Acid Catalysis
journal, July 2005
- Lotero, Edgar; Liu, Yijun; Lopez, Dora E.
- Industrial & Engineering Chemistry Research, Vol. 44, Issue 14
Green chemistry: Biodiesel made with sugar catalyst
journal, November 2005
- Toda, Masakazu; Takagaki, Atsushi; Okamura, Mai
- Nature, Vol. 438, Issue 7065, p. 178-178
Transesterification of crude palm kernel oil and crude coconut oil by different solid catalysts
journal, February 2006
- Jitputti, J.; Kitiyanan, B.; Rangsunvigit, P.
- Chemical Engineering Journal, Vol. 116, Issue 1
Structure–reactivity correlations in sulphated-zirconia catalysts for the isomerisation of α-pinene
journal, April 2003
- Ecormier, M.
- Journal of Catalysis, Vol. 215, Issue 1
Preparation of biodiesel from crude oil of Pongamia pinnata
journal, September 2005
- Karmee, Sanjib Kumar; Chadha, Anju
- Bioresource Technology, Vol. 96, Issue 13
Conversion of oils and fats using advanced mesoporous heterogeneous catalysts
journal, February 2006
- Mbaraka, Isa K.; Shanks, Brent H.
- Journal of the American Oil Chemists' Society, Vol. 83, Issue 2
Biodiesel Production Via Avid Catalysis
journal, January 1999
- Canakci, M.; Van Gerpen, J.
- Transactions of the ASAE, Vol. 42, Issue 5, p. 1203-1210
Solid Acid Catalysts for Biodiesel Production –-Towards Sustainable Energy
journal, January 2006
- Kiss, Anton A.; Dimian, Alexandre C.; Rothenberg, Gadi
- Advanced Synthesis & Catalysis, Vol. 348, Issue 1-2
Reaction of glycerol with fatty acids in the presence of ion-exchange resins
journal, December 1999
- Pouilloux, Y.; Abro, S.; Vanhove, C.
- Journal of Molecular Catalysis A: Chemical, Vol. 149, Issue 1-2
Esterification of higher fatty acids by a novel strong solid acid
journal, August 2006
- Takagaki, Atsushi; Toda, Masakazu; Okamura, Mai
- Catalysis Today, Vol. 116, Issue 2
Organosulfonic acid-functionalized mesoporous silicas for the esterification of fatty acid
journal, October 2003
- Mbaraka, I.
- Journal of Catalysis, Vol. 219, Issue 2
Catalyzed dioctyl phthalate formation using a nanostructured solid acid resin
journal, January 2005
- Xu, Yanjie; Gin, Douglas L.; Elliott, Brian J.
- AIChE Journal, Vol. 52, Issue 1
Kinetics of Oleic Acid Esterification with Methanol in the Presence of Triglycerides
journal, October 2005
- Tesser, R.; Di Serio, M.; Guida, M.
- Industrial & Engineering Chemistry Research, Vol. 44, Issue 21
Hydrophobic, solid acid catalysts for production of biofuels and lubricants
journal, November 2006
- Sreeprasanth, P. S.; Srivastava, R.; Srinivas, D.
- Applied Catalysis A: General, Vol. 314, Issue 2
Biodiesel fuel production with solid superacid catalysis in fixed bed reactor under atmospheric pressure
journal, December 2004
- Furuta, Satoshi; Matsuhashi, Hiromi; Arata, Kazushi
- Catalysis Communications, Vol. 5, Issue 12, p. 721-723