Nanocrystal doped matrixes
Abstract
Matrixes doped with semiconductor nanocrystals are provided. In certain embodiments, the semiconductor nanocrystals have a size and composition such that they absorb or emit light at particular wavelengths. The nanocrystals can comprise ligands that allow for mixing with various matrix materials, including polymers, such that a minimal portion of light is scattered by the matrixes. The matrixes of the present invention can also be utilized in refractive index matching applications. In other embodiments, semiconductor nanocrystals are embedded within matrixes to form a nanocrystal density gradient, thereby creating an effective refractive index gradient. The matrixes of the present invention can also be used as filters and antireflective coatings on optical devices and as down-converting layers. Processes for producing matrixes comprising semiconductor nanocrystals are also provided. Nanostructures having high quantum efficiency, small size, and/or a narrow size distribution are also described, as are methods of producing indium phosphide nanostructures and core-shell nanostructures with Group II-VI shells.
- Inventors:
-
- Palo Alto, CA
- Sunnyvale, CA
- San Carlos, CA
- San Mateo, CA
- Vallejo, CA
- San Jose, CA
- Redwood City, CA
- Belmont, CA
- Issue Date:
- Research Org.:
- Nanosys, Inc. (Palo Alto, CA)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1014076
- Patent Number(s):
- 7645397
- Application Number:
- US Patent Application 11/492,717
- Assignee:
- Nanosys, Inc. (Palo Alto, CA)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B82 - NANOTECHNOLOGY B82Y - SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
- DOE Contract Number:
- FG02-04ER84020
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Parce, J Wallace, Bernatis, Paul, Dubrow, Robert, Freeman, William P, Gamoras, Joel, Kan, Shihai, Meisel, Andreas, Qian, Baixin, Whiteford, Jeffery A, and Ziebarth, Jonathan. Nanocrystal doped matrixes. United States: N. p., 2010.
Web.
Parce, J Wallace, Bernatis, Paul, Dubrow, Robert, Freeman, William P, Gamoras, Joel, Kan, Shihai, Meisel, Andreas, Qian, Baixin, Whiteford, Jeffery A, & Ziebarth, Jonathan. Nanocrystal doped matrixes. United States.
Parce, J Wallace, Bernatis, Paul, Dubrow, Robert, Freeman, William P, Gamoras, Joel, Kan, Shihai, Meisel, Andreas, Qian, Baixin, Whiteford, Jeffery A, and Ziebarth, Jonathan. Tue .
"Nanocrystal doped matrixes". United States. https://www.osti.gov/servlets/purl/1014076.
@article{osti_1014076,
title = {Nanocrystal doped matrixes},
author = {Parce, J Wallace and Bernatis, Paul and Dubrow, Robert and Freeman, William P and Gamoras, Joel and Kan, Shihai and Meisel, Andreas and Qian, Baixin and Whiteford, Jeffery A and Ziebarth, Jonathan},
abstractNote = {Matrixes doped with semiconductor nanocrystals are provided. In certain embodiments, the semiconductor nanocrystals have a size and composition such that they absorb or emit light at particular wavelengths. The nanocrystals can comprise ligands that allow for mixing with various matrix materials, including polymers, such that a minimal portion of light is scattered by the matrixes. The matrixes of the present invention can also be utilized in refractive index matching applications. In other embodiments, semiconductor nanocrystals are embedded within matrixes to form a nanocrystal density gradient, thereby creating an effective refractive index gradient. The matrixes of the present invention can also be used as filters and antireflective coatings on optical devices and as down-converting layers. Processes for producing matrixes comprising semiconductor nanocrystals are also provided. Nanostructures having high quantum efficiency, small size, and/or a narrow size distribution are also described, as are methods of producing indium phosphide nanostructures and core-shell nanostructures with Group II-VI shells.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2010},
month = {1}
}
Works referenced in this record:
Reduced photo-instability of luminescence spectrum of core-shell CdSe/CdS nanocrystals
journal, March 2000
- Xu, Ling; Huang, Xinfan; Zhu, Jianming
- Journal of Materials Science, Vol. 35, Issue 6, p. 1375-1378
Immobilization of semiconductor nanoparticles formed in reverse micelles into polyurea via in situ polymerization of diisocyanates
journal, January 1998
- Shiojiri, Susumu; Hirai, Takayuki; Komasawa, Isao
- Chemical Communications, Issue 14
Colloidal Synthesis and Properties of InAs/InP and InAs/CdSe Core/Shell Nanocrystals
journal, January 1999
- Cao, Yun-Wei; Aksenton, Julia; Soloviev, Victor
- MRS Proceedings, Vol. 571
Synthesis and characterization of ZnO nanostructures templated using diblock copolymers
journal, May 2003
- Mulligan, Robert F.; Iliadis, Agis A.; Kofinas, Peter
- Journal of Applied Polymer Science, Vol. 89, Issue 4
Synthesis of Self-Assembled Metal-Oxide Nanostructures in a Diblock Copolymer Matrix and Integration onto Semiconductor Surfaces
journal, January 2000
- Mulligan, Robert F.; Iliadis, Agis A.; Lee, U.
- MRS Proceedings, Vol. 642
Preparation of nano-CdS–polyurethane composites via in situ polymerization in reverse micellar systems
journal, January 2000
- Hirai, Takayuki; Komasawa, Isao
- Journal of Materials Chemistry, Vol. 10, Issue 10
Synthesis and characterization of nearly monodisperse CdE (E = sulfur, selenium, tellurium) semiconductor nanocrystallites
journal, September 1993
- Murray, C. B.; Norris, D. J.; Bawendi, M. G.
- Journal of the American Chemical Society, Vol. 115, Issue 19, p. 8706-8715
Core−Shell Quantum Dots of Lattice-Matched ZnCdSe 2 Shells on InP Cores: Experiment and Theory
journal, December 2000
- Mićić, Olga I.; Smith, Barton B.; Nozik, Arthur J.
- The Journal of Physical Chemistry B, Vol. 104, Issue 51
Epitaxial Growth of Highly Luminescent CdSe/CdS Core/Shell Nanocrystals with Photostability and Electronic Accessibility
journal, July 1997
- Peng, Xiaogang; Schlamp, Michael C.; Kadavanich, Andreas V.
- Journal of the American Chemical Society, Vol. 119, Issue 30, p. 7019-7029
Rapid Synthesis of High-Quality InP Nanocrystals
journal, February 2006
- Xu, Shu; Kumar, Sandeep; Nann, Thomas
- Journal of the American Chemical Society, Vol. 128, Issue 4
Semiconductor Clusters, Nanocrystals, and Quantum Dots
journal, February 1996
- Alivisatos, A. P.
- Science, Vol. 271, Issue 5251, p. 933-937
Bright UV-Blue Luminescent Colloidal ZnSe Nanocrystals
journal, May 1998
- Hines, Margaret A.; Guyot-Sionnest, Philippe
- The Journal of Physical Chemistry B, Vol. 102, Issue 19
High refractive index thin films of ZnS/polythiourethane nanocomposites
journal, February 2003
- Lü, Changli; Cui, Zhanchen; Li, Zuo
- Journal of Materials Chemistry, Vol. 13, Issue 3
(CdSe)ZnS Core−Shell Quantum Dots: Synthesis and Characterization of a Size Series of Highly Luminescent Nanocrystallites
journal, November 1997
- Dabbousi, B. O.; Rodriguez-Viejo, J.; Mikulec, F. V.
- The Journal of Physical Chemistry B, Vol. 101, Issue 46, p. 9463-9475
Synthesis of Cu and CuO nanoclusters within microphase-separated diblock copolymers
journal, January 1998
- T. Clay, Russell; E. Cohen, Robert
- New Journal of Chemistry, Vol. 22, Issue 7
Structural and spectroscopic investigations of CdS/HgS/CdS quantum-dot quantum wells
journal, May 1996
- Mews, A.; Kadavanich, A. V.; Banin, U.
- Physical Review B, Vol. 53, Issue 20
New preparation method for organic–inorganic layered compounds by organo derivatization reaction of Zn(OH)2 with carboxylic acids
journal, January 2000
- Ogata, Sumikazu; Tagaya, Hideyuki; Karasu, Masa
- Journal of Materials Chemistry, Vol. 10, Issue 2
Synthesis of metal nanoclusters within microphase-separated diblock copolymers: ICP-AES analysis of metal ion uptake
journal, March 1997
- Clay, R. T.; Cohen, R. E.
- Supramolecular Science, Vol. 4, Issue 1-2
Colloidal chemical synthesis and characterization of InAs nanocrystal quantum dots
journal, September 1996
- Guzelian, A. A.; Banin, U.; Kadavanich, A. V.
- Applied Physics Letters, Vol. 69, Issue 10
Preparation of Semiconductor Nanoparticle−Polyurea Composites Using Reverse Micellar Systems via an in Situ Diisocyanate Polymerization
journal, November 1999
- Hirai, Takayuki; Watanabe, Tatsufumi; Komasawa, Isao
- The Journal of Physical Chemistry B, Vol. 103, Issue 46
Size Variation of PbS Particles in High-Refractive-Index Nanocomposites
journal, September 1994
- Kyprianidou-Leodidou, Tasoula; Caseri, Walter; Suter, Ulrich W.
- The Journal of Physical Chemistry, Vol. 98, Issue 36
High-Pressure Structural Transformations in Semiconductor Nanocrystals
journal, October 1995
- Tolbert, Sarah H.; Alivisatos, A. P.
- Annual Review of Physical Chemistry, Vol. 46, Issue 1
Colloidal ZnSe, ZnSe/ZnS, and ZnSe/ZnSeS Quantum Dots Synthesized from ZnO
journal, November 2004
- Chen, Hsueh-Shih; Lo, Bertrand; Hwang, Jen-Yu
- The Journal of Physical Chemistry B, Vol. 108, Issue 44
Formation of High Quality InP and InAs Nanocrystals in a Noncoordinating Solvent
journal, September 2002
- Battaglia, David; Peng, Xiaogang
- Nano Letters, Vol. 2, Issue 9
Synthesis and Characterization of Mn Doped CdS Quantum Dots from a Single Source Precursor
journal, January 1999
- Malik, M. Azad; O'Brien, Paul; Revaprasadu, N.
- MRS Proceedings, Vol. 581
Composite nano-CdS-polyurethane transparent films
journal, January 1999
- Hirai, Takayuki; Miyamoto, Masanori; Komasawa, Isao
- Journal of Materials Chemistry, Vol. 9, Issue 6
Processible Optically Transparent Block Copolymer Films Containing Superparamagnetic Iron Oxide Nanoclusters
journal, January 1997
- Sohn, B. H.; Cohen, R. E.
- Chemistry of Materials, Vol. 9, Issue 1
Synthesis and characterization of mixed CdSZnS nanoparticles in reverse micelles
journal, June 1996
- Qi, Limin; Ma, Jiming; Cheng, Humin
- Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 111, Issue 3
Effects of Thiols on Photocatalytic Properties of Nano-CdS-Polythiourethane Composite Particles.
journal, January 1998
- Hirai, Takayuki; Miyamoto, Masanori; Watanabe, Tatsufumi
- JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, Vol. 31, Issue 6
Synthesis and Characterization of InP, GaP, and GaInP2 Quantum Dots
journal, May 1995
- Micic, O. I.; Sprague, J. R.; Curtis, C. J.
- The Journal of Physical Chemistry, Vol. 99, Issue 19
Structural and magnetic characterization of norbornene–deuterated norbornene dicarboxylic acid diblock copolymers doped with iron oxide nanoparticles
journal, June 2005
- Akcora, Pinar; Zhang, Xin; Varughese, Bindhu
- Polymer, Vol. 46, Issue 14
Etching of Colloidal InP Nanocrystals with Fluorides: Photochemical Nature of the Process Resulting in High Photoluminescence Efficiency
journal, December 2002
- Talapin, Dmitri V.; Gaponik, Nikolai; Borchert, Holger
- The Journal of Physical Chemistry B, Vol. 106, Issue 49
Lateral Coupling of Self-Assembled Quantum Dots Studied by Near-Field Spectroscopy
journal, January 1999
- Robinson, H. D.; Goldberg, B. B.; Merz, J. L.
- MRS Proceedings, Vol. 571
Thiol-Mediated Immobilization of Photocatalytic Metal Sulfide Ultrafine Particles Formed in Reverse Micellar Systems in Polythiourethane.
journal, January 1998
- Shiojiri, Susumu; Miyamoto, Masanori; Hirai, Takayuki
- JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, Vol. 31, Issue 3
Growth and Properties of Semiconductor Core/Shell Nanocrystals with InAs Cores
journal, October 2000
- Banin, Uri
- Journal of the American Chemical Society, Vol. 122, Issue 40, p. 9692-9702
Synthesis and Characterization of CdSe/CdS Core-Shell and CdSe/CdS Composites
journal, January 1999
- Malika, M. Azad; O'Brien, Paul; Revaprasaduac, N.
- MRS Proceedings, Vol. 581
Preparation, characterization, and photophysics of the quantum dot quantum well system cadmium sulfide/mercury sulfide/cadmium sulfide
journal, January 1994
- Mews, A.; Eychmueller, A.; Giersig, M.
- The Journal of Physical Chemistry, Vol. 98, Issue 3
Controlled Synthesis of Mixed Core and Layered (Zn,Cd)S and (Hg,Cd)S Nanocrystals within Phosphatidylcholine Vesicles
journal, April 2000
- Korgel, Brian A.; Monbouquette, Harold G.
- Langmuir, Vol. 16, Issue 8
Monodispersed InP Quantum Dots Prepared by Colloidal Chemistry in a Noncoordinating Solvent
journal, July 2005
- Lucey, Derrick W.; MacRae, David J.; Furis, Madalina
- Chemistry of Materials, Vol. 17, Issue 14
Synthesis of Size-Selected, Surface-Passivated InP Nanocrystals
journal, January 1996
- Guzelian, A. A.; Katari, J. E. B.; Kadavanich, A. V.
- The Journal of Physical Chemistry, Vol. 100, Issue 17
Folate-Receptor-Mediated Delivery of InP Quantum Dots for Bioimaging Using Confocal and Two-Photon Microscopy
journal, August 2005
- Bharali, Dhruba J.; Lucey, Derrick W.; Jayakumar, Harishankar
- Journal of the American Chemical Society, Vol. 127, Issue 32
Synthesis of Doped ZnS Nanoclusters within Block Copolymer Nanoreactors
journal, January 1999
- Kane, R. S.; Cohen, R. E.; Silbey, R.
- Chemistry of Materials, Vol. 11, Issue 1
High Quality ZnSe and ZnS Nanocrystals Formed by Activating Zinc Carboxylate Precursors
journal, November 2004
- Li, Lin Song; Pradhan, Narayan; Wang, Yunjun
- Nano Letters, Vol. 4, Issue 11