Palladium-based electrocatalysts and fuel cells employing such electrocatalysts
Abstract
A direct organic fuel cell includes a fluid fuel comprising formic acid, an anode having an electrocatalyst comprising palladium nanoparticles, a fluid oxidant, a cathode electrically connected to the anode, and an electrolyte interposed between the anode and the cathode.
- Inventors:
-
- Champaign, IL
- Urbana, IL
- Issue Date:
- Research Org.:
- Univ. of Illinois at Urbana-Champaign, IL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1013609
- Patent Number(s):
- 7785728
- Application Number:
- 10/817,361
- Assignee:
- The Board of Trustees of the University of Illinois (Urbana, IL)
- Patent Classifications (CPCs):
-
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- DOE Contract Number:
- FG02-99ER14993
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Masel, Richard I., Larsen, Robert T., and Zhu, Yimin Zhu. Palladium-based electrocatalysts and fuel cells employing such electrocatalysts. United States: N. p., 2010.
Web.
Masel, Richard I., Larsen, Robert T., & Zhu, Yimin Zhu. Palladium-based electrocatalysts and fuel cells employing such electrocatalysts. United States.
Masel, Richard I., Larsen, Robert T., and Zhu, Yimin Zhu. Tue .
"Palladium-based electrocatalysts and fuel cells employing such electrocatalysts". United States. https://www.osti.gov/servlets/purl/1013609.
@article{osti_1013609,
title = {Palladium-based electrocatalysts and fuel cells employing such electrocatalysts},
author = {Masel, Richard I. and Larsen, Robert T. and Zhu, Yimin Zhu},
abstractNote = {A direct organic fuel cell includes a fluid fuel comprising formic acid, an anode having an electrocatalyst comprising palladium nanoparticles, a fluid oxidant, a cathode electrically connected to the anode, and an electrolyte interposed between the anode and the cathode.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2010},
month = {8}
}
Works referenced in this record:
CO Tolerance of Pd-Rich Platinum Palladium Carbon-Supported Electrocatalysts
journal, January 2002
- Papageorgopoulos, D. C.; Keijzer, M.; Veldhuis, J. B. J.
- Journal of The Electrochemical Society, Vol. 149, Issue 11
Structural effects in electrocatalysis
journal, July 1983
- Adžić, R. R.; Tripković, A. V.; Marković, N. M.
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 150, Issue 1-2
Enhancement of the electrochemical oxidation of formic acid. Effects of anion adsorption and variation of rotation rate
journal, August 2001
- Chen, Shengli; Lee, Diane; Schell, Mark
- Electrochimica Acta, Vol. 46, Issue 23
The effect of strong acid on the reactions of hydrogen and oxygen on the noble metals. A study using cyclic voltammetry and a new teflon electrode holder
journal, October 1972
- Capon, Andrew; Parsons, Roger
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 39, Issue 2
Oxidation of formic acid on Pt(111) electrodes modified by irreversibly adsorbed tellurium
journal, September 1995
- Herrero, E.; Llorca, M. J.; Feliu, J. M.
- Journal of Electroanalytical Chemistry, Vol. 394, Issue 1-2
Electrocatalysis of formic acid and CO oxidation on antimony-modified Pt(111) electrodes
journal, December 1998
- Climent, Vı́ctor; Herrero, Enrique; Feliu, Juan M.
- Electrochimica Acta, Vol. 44, Issue 8-9
Reactive scattering of small molecules from platinum crystal surfaces: D2CO, CH3OH, HCOOH, and the nonanomalous kinetics of hydrogen atom recombination
journal, May 1983
- Gdowski, G. E.; Fair, J. A.; Madix, R. J.
- Surface Science, Vol. 127, Issue 3
New insights into the influence of upd Sn on the oxidation of formic acid on platinum in acidic solution
journal, December 1999
- Xia, X. H.
- Electrochimica Acta, Vol. 45, Issue 7
Kinetic modeling for wet air oxidation of formic acid on a carbon supported platinum catalyst
journal, December 1997
- Harmsen, J. M. A.; Jelemensky, L.; Van Andel-Scheffer, P. J. M.
- Applied Catalysis A: General, Vol. 165, Issue 1-2
The oxidation of formic acid at noble metal electrodes Part 4. Platinum + palladium alloys
journal, October 1975
- Capon, A.
- Journal of Electroanalytical Chemistry, Vol. 65, Issue 1
Formic acid oxidation on Pdad + Pt(100) and Pdad + Pt(111) electrodes
journal, October 1994
- Llorca, M. J.; Feliu, J. M.; Aldaz, A.
- Journal of Electroanalytical Chemistry, Vol. 376, Issue 1-2
Electrocatalytic Oxidation of Small Carbohydrate Fuels at Pt−Sn Modified Electrodes
journal, December 1998
- González, María J.; Hable, Christopher T.; Wrighton, Mark S.
- The Journal of Physical Chemistry B, Vol. 102, Issue 49
Formic Acid Oxidation on Ultrathin Pd Films on Au( hkl ) and Pt( hkl ) Electrodes
journal, January 1996
- Baldauf, M.; Kolb, D. M.
- The Journal of Physical Chemistry, Vol. 100, Issue 27
Nanoparticles of Pt hydrosol immobilised on Au support: an approach to the study of structural effects in electrocatalysis
journal, April 2001
- Pron'kin, S. N.; Tsirlina, G. A.; Petrii, O. A.
- Electrochimica Acta, Vol. 46, Issue 15
ChemInform Abstract: Electrocatalysis by Ad-Atoms. Part 23. Design of Platinum Ad-Electrodes for Formic Acid Fuel Cells with Ad-Atoms of the IVth and the Vth Groups.
journal, October 1988
- Watanabe, M.; Horiuchi, M.; Motoo, S.
- ChemInform, Vol. 19, Issue 43
Effects of Nafion as a binding agent for unsupported nanoparticle catalysts
journal, March 2003
- McGovern, M. S.; Garnett, E. C.; Rice, C.
- Journal of Power Sources, Vol. 115, Issue 1
Electrocatalytic oxidation of formic acid by Pt/Co nanoparticles
journal, January 2001
- Chi, Ning; Chan, Kwong-Yu; Phillips, David Lee
- Catalysis Letters, Vol. 71, Issue 1/2, p. 21-26
Crossover of formic acid through Nafion® membranes
journal, May 2003
- Rhee, Young-Woo; Ha, Su Y.; Masel, Richard I.
- Journal of Power Sources, Vol. 117, Issue 1-2
Electro-oxidation mechanisms of methanol and formic acid on Pt-Ru alloy surfaces
journal, January 1995
- Marković, Nenad M.; Gasteiger, Hubert A.; Ross, Philip N.
- Electrochimica Acta, Vol. 40, Issue 1
Performance of CO-electrodeposited Pt-Ru/WO3 electrodes for the electrooxidation of formic acid at room temperature
journal, June 1995
- Shen, Pei Kang; Chen, Kun Yao; Tseung, Alfred C. C.
- Journal of Electroanalytical Chemistry, Vol. 389, Issue 1-2
Investigation of the mechanism of the electrochemical oxidation of formic acid at a gold electrode in sulfuric acid solution
journal, December 2001
- Xiang, Juan; Wu, Bing-Liang; Chen, Sheng-Li
- Journal of Electroanalytical Chemistry, Vol. 517, Issue 1-2
Oxidation of formic acid on Pt(100) electrodes modified by irreversibly adsorbed tellurium
journal, February 1995
- Herrero, E.; Llorca, M. J.; Feliu, J. M.
- Journal of Electroanalytical Chemistry, Vol. 383, Issue 1-2
Heterogeneous electrocatalysis on well defined platinum surfaces modified by controlled amounts of irreversibly adsorbed adatoms
journal, January 1989
- Fernandez-Vega, A.; Feliu, J. M.; Aldaz, A.
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 258, Issue 1
Adsorption and reaction of HCOOH on K-promoted Pd(100) surfaces
journal, December 1991
- Solymosi, Frigyes; Kovács, Imre
- Surface Science, Vol. 259, Issue 1-2
A miniature air breathing direct formic acid fuel cell
journal, April 2004
- Ha, S.; Adams, B.; Masel, R. I.
- Journal of Power Sources, Vol. 128, Issue 2
A nanoparticle catalyst with superior activity for electrooxidation of formic acid
journal, July 2002
- Waszczuk, Piotr; Barnard, Thomas M.; Rice, Cynthia
- Electrochemistry Communications, Vol. 4, Issue 7
Methanol Electrooxidation on Platinum/Ruthenium Nanoparticle Catalysts
journal, October 2001
- Waszczuk, P.; Solla-Gullón, J.; Kim, H. -S.
- Journal of Catalysis, Vol. 203, Issue 1
Catalytic effects of Hg and Tl submonolayers on the electrooxidation of formic acid on Pt
journal, June 1986
- Hartung, Th.; Willsau, J.; Heitbaum, J.
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 205, Issue 1-2
High power density direct formic acid fuel cells
journal, May 2004
- Zhu, Yimin; Ha, Su Y.; Masel, Richard I.
- Journal of Power Sources, Vol. 130, Issue 1-2
Formic Acid Oxidation in a Polymer Electrolyte Fuel Cell
journal, January 1996
- Weber, M.
- Journal of The Electrochemical Society, Vol. 143, Issue 7
Nanostructured platinum as an electrocatalyst for the electrooxidation of formic acid
journal, February 2002
- Jiang, Junhua; Kucernak, Anthony
- Journal of Electroanalytical Chemistry, Vol. 520, Issue 1-2
Formic acid oxidation on Pt(111) electrodes modified by irreversibly adsorbed selenium
journal, August 1994
- Llorca, M. J.; Herrero, E.; Feliu, J. M.
- Journal of Electroanalytical Chemistry, Vol. 373, Issue 1-2
Electrocatalysis by AD-atoms
journal, September 1985
- Watanabe, M.; Furuuchi, Y.; Motoo, S.
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 191, Issue 2
Active oxygen on Group VIII metals: activation of formic acid and formaldehyde on Pd(100)
journal, January 1988
- Jorgensen, Scott W.; Madix, Robert J.
- Journal of the American Chemical Society, Vol. 110, Issue 2
The oxidation of formic acid at noble metal electrodes Part III. Intermediates and mechanism on platinum electrodes
journal, July 1973
- Capon, Andrew; Parsons, Roger
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 45, Issue 2
Methanol conditioning for improved performance of formic acid fuel cells
journal, November 2002
- Ha, Su; Rice, Cynthia A.; Masel, Richard I.
- Journal of Power Sources, Vol. 112, Issue 2
Adsorption and Reaction of Formic Acid on a Pseudomorphic Palladium Monolayer on Mo(110)
journal, January 1996
- Xu, Chen; Goodman, D. W.
- The Journal of Physical Chemistry, Vol. 100, Issue 1
Electrocatalytic activity of noble metals for the oxidation of formate in neutral medium
journal, July 1979
- Beden, B.; Lamy, C.; Leger, J. M.
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 101, Issue 1
Electrocatalysis by ad-atoms
journal, July 1988
- Shibata, Masami; Takahashi, Osamu; Motoo, Satoshi
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 249, Issue 1-2
The oxidation of formic acid on noble metal electrodes
journal, June 1973
- Capon, Andrew; Parsons, Roger
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 44, Issue 2
The influence of UPD-lead on the adsorption of formaldehyde, formic acid and methanol on Pt in acid solution
journal, November 1985
- Bełtowska-Brzezinska, M.; Heitbaum, J.; Vielstich, W.
- Electrochimica Acta, Vol. 30, Issue 11
Electrocatalytic oxidation of formic acid on ultrafine palladium particles supported on a glassy carbon
journal, September 1995
- Zhang, Xiao-Gang; Arikawa, Toshihide; Murakami, Yasushi
- Electrochimica Acta, Vol. 40, Issue 12
A nanoparticle catalyst with superior activity for electrooxidation of formic acid [Electrochem. Commun. 4 (2002) 599-603]
journal, September 2002
- Waszczuk, Piotr; Barnard, Thomas M.; Rice, Cynthia
- Electrochemistry Communications, Vol. 4, Issue 9
UHV and electrochemical studies of CO and methanol adsorbed at platinum/ruthenium surfaces, and reference to fuel cell catalysis
journal, August 2002
- Waszczuk, P.; Lu, G. -Q.; Wieckowski, A.
- Electrochimica Acta, Vol. 47, Issue 22-23
Surface modification and electrocatalytic properties of Pt(100), Pt(110), Pt(320) and Pt(331) electrodes with Sb towards HCOOH oxidation
journal, August 2001
- Yang, Yi-Yun; Sun, Shi-Gang; Gu, Yan-Juan
- Electrochimica Acta, Vol. 46, Issue 28
The behaviour of formic acid on a rhodium electrode
journal, August 1978
- Sobkowski, Jerzy; Zelenay, Piotr
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 91, Issue 3
Structural effects on the oxidation of HCOOH by bismuth modified Pt(111) electrodes with (110) monatomic steps
journal, June 1999
- Smith, Sean P. E.; Abruña, Héctor D.
- Journal of Electroanalytical Chemistry, Vol. 467, Issue 1-2
Electro-oxidation of small organic molecules on well-characterized PtRu alloys
journal, August 1994
- Gasteiger, Hubert A.; Marković, Nenad; Ross, Philip N.
- Electrochimica Acta, Vol. 39, Issue 11-12
Study of nickel upd at a polycrystalline Pt electrode and its influence on HCOOH oxidation in acidic and nearly neutral media
journal, April 1998
- El-Shafei, A. A.
- Journal of Electroanalytical Chemistry, Vol. 447, Issue 1-2
Heterogeneous electrocatalysis on well defined platinum surfaces modified by controlled amounts of irreversibly adsorbed adatoms
journal, January 1989
- Clavilier, J.; Fernandez-Vega, A.; Feliu, J. M.
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 258, Issue 1
SFG study of formic acid on a Pt(110)-(1 × 2) surface
journal, June 1996
- Watanabe, N.; Iwatsu, K.; Yamakata, A.
- Surface Science, Vol. 357-358
The electro-oxidation of formic acid on Pt–Pd single crystal bimetallic surfaces
journal, January 2003
- Arenz, M.; Stamenkovic, V.; Schmidt, T. J.
- Phys. Chem. Chem. Phys., Vol. 5, Issue 19
Direct formic acid fuel cells
journal, September 2002
- Rice, C.; Ha, S.; Masel, R. I.
- Journal of Power Sources, Vol. 111, Issue 1, p. 83-89
Formic Acid Decomposition on Polycrystalline Platinum and Palladized Platinum Electrodes
journal, November 1999
- Lu, Guo-Qiang; Crown, Alechia; Wieckowski, Andrzej
- The Journal of Physical Chemistry B, Vol. 103, Issue 44
Electro-oxidation of Formic Acid on Highly Dispersed Platinum and Perchlorate Doped Polypyrrole Electrodes
journal, January 2001
- Becerı̇k, İ.; Kadirgan, F.
- Journal of The Electrochemical Society, Vol. 148, Issue 5
Catalysts for direct formic acid fuel cells
journal, April 2003
- Rice, C.
- Journal of Power Sources, Vol. 115, Issue 2
Electrocatalytic oxidation of formic acid on Pt binary and ternary electrodes in H3PO4
journal, December 1993
- El-Shafei, A. A.; Shabanah, H. M.; Moussa, M. N. H.
- Journal of Electroanalytical Chemistry, Vol. 362, Issue 1-2
The electrocatalytic properties of the oxides of noble metals in the electrooxidation of methanol and formic acid
journal, July 2001
- Avramov-Ivić, M.; Štrbac, S.; Mitrović, V.
- Electrochimica Acta, Vol. 46, Issue 20-21