Nanoreactors comprising a nanoreactor shell enveloping a space, and method of making

Alivisatos, A Paul; Yin, Yadong; Rioux, Robert M; Somorjai, Gabor A

Title: Nanoreactors comprising a nanoreactor shell enveloping a space, and method of making

Abstract

Described herein are nanoreactors having various shapes that can be produced by a simple chemical process. The nanoreactors described herein may have a shell as thin as 0.5 nm and outside diameters that can be controlled by the process of making and have a nanoparticle enclosed therein. The nanoreactors have catalytic activity and may be used to catalyze a variety of chemical reactions.

Inventors:

Alivisatos, A Paul ^[1]; Yin, Yadong ^[2]; Rioux, Robert M ^[3]; Somorjai, Gabor A ^[4]

Oakland, CA
Moreno Valley, CA
Somerville, MA
Berkeley, CA

Issue Date:: 2011-01-25

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1013021

Patent Number(s):: 7875351

Application Number:: 10/599,250

Assignee:: The Regents of the University of California (Oakland, CA)

Patent Classifications (CPCs):: C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

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C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2004/34 - hollow

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B21/0637 - {with metals not specified in groups C01B21/0607 - C01B21/0635, other than aluminium, titanium, zirconium or hafnium}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2004/16 - Nanowires or nanorods, i.e. solid nanofibres with two nearly equal dimensions between 1-100 nanometer

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B13/322 - {of elements or compounds in the solid state}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10S - TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10S977/70 - Nanostructure

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2004/61 - Micrometer sized, i.e. from 1-100 micrometer

B - PERFORMING OPERATIONS B82 - NANOTECHNOLOGY B82Y - SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES
B82Y30/00 - Nanotechnology for materials or surface science, e.g. nanocomposites

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C01G53/00 - Compounds of nickel

C - CHEMISTRY C30 - CRYSTAL GROWTH C30B - SINGLE-CRYSTAL-GROWTH
C30B29/60 - characterised by shape
C30B29/48 - AIIBVI compounds {wherein A is Zn, Cd or Hg, and B is S, Se or Te}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B21/0602 - {with two or more other elements chosen from metals, silicon or boron}
C01B19/007 - {Tellurides or selenides of metals

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C01G51/00 - Compounds of cobalt

B - PERFORMING OPERATIONS B22 - CASTING B22F - WORKING METALLIC POWDER
B22F1/0025 - {Nanofibres or nanotubes}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B13/32 - by oxidation or hydrolysis of elements or compounds in the liquid or solid state {or in non-aqueous solution, e.g. sol-gel process}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T428/12181 - Composite powder [e.g., coated, etc.]

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10S - TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10S977/773 - Nanoparticle, i.e. structure having three dimensions of 100 nm or less

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C01G49/06 - Ferric oxide

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B17/20 - Methods for preparing sulfides or polysulfides, in general

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T428/2991 - Coated

B - PERFORMING OPERATIONS B22 - CASTING B22F - WORKING METALLIC POWDER
B22F2001/0029 - {Hollow particles, including tubes and shells}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2004/04 - obtained by TEM, STEM, STM or AFM

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C01G53/09 - Chlorides

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T428/13 - Hollow or container type article [e.g., tube, vase, etc.]

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2004/13 - Nanotubes
C01P2002/72 - by d-values or two theta-values, e.g. as X-ray diagram

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B21/06 - Binary compounds of nitrogen with metals, with silicon, or with boron, {or with carbon, i.e. nitrides

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2004/64 - Nanometer sized, i.e. from 1-100 nanometer

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C01G51/30 - {Sulfides}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2004/62 - Submicrometer sized, i.e. from 0.1-1 micrometer

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C01G55/00 - Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum

C - CHEMISTRY C30 - CRYSTAL GROWTH C30B - SINGLE-CRYSTAL-GROWTH
C30B29/16 - Oxides
C30B7/00 - Single-crystal growth from solutions using solvents which are liquid at normal temperature, e.g. aqueous solutions

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C01G11/02 - Sulfides

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B21/0632 - {with gallium, indium or thallium}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C01G51/04 - Oxides

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DOE Contract Number:: The Regents of the University of California (Oakland, CA)

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 77 NANOSCIENCE AND NANOTECHNOLOGY

Citation Formats


                    Alivisatos, A Paul, Yin, Yadong, Rioux, Robert M, and Somorjai, Gabor A. Nanoreactors comprising a nanoreactor shell enveloping a space, and method of making.  United States: N. p., 2011. 
        Web.

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                    Alivisatos, A Paul, Yin, Yadong, Rioux, Robert M, & Somorjai, Gabor A. Nanoreactors comprising a nanoreactor shell enveloping a space, and method of making.  United States.

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                    Alivisatos, A Paul, Yin, Yadong, Rioux, Robert M, and Somorjai, Gabor A. Tue .  
        "Nanoreactors comprising a nanoreactor shell enveloping a space, and method of making".  United States.  https://www.osti.gov/servlets/purl/1013021.

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@article{osti_1013021,

  title        = {Nanoreactors comprising a nanoreactor shell enveloping a space, and method of making},

  author       = {Alivisatos, A Paul and Yin, Yadong and Rioux, Robert M and Somorjai, Gabor A},

  abstractNote = {Described herein are nanoreactors having various shapes that can be produced by a simple chemical process. The nanoreactors described herein may have a shell as thin as 0.5 nm and outside diameters that can be controlled by the process of making and have a nanoparticle enclosed therein. The nanoreactors have catalytic activity and may be used to catalyze a variety of chemical reactions.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2011},

  month        = {1}

}

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Similar Records

Title: Nanoreactors comprising a nanoreactor shell enveloping a space, and method of making

Abstract

Citation Formats

Synthesis and characterization of molybdate-modified platinum nanoparticles journal, January 2004

Synthesis of hcp-Co Nanodisks journal, October 2002

Hydrogenation of ethylene over platinum (111) single-crystal surfaces journal, April 1984

Controlled porosity by an extreme kirkendall effect journal, July 1974

Response Factors for Gas Chromatographic Analyses journal, February 1967

The Determination of Pore Volume and Area Distributions in Porous Substances. I. Computations from Nitrogen Isotherms journal, January 1951

Characteristic Features of Size-Selective Photoetching of CdS Nanoparticles as a Means of Preparation of Monodisperse Particles journal, January 1998

Sulphidation of cobalt at high temperatures journal, May 1998

Slush Baths. journal, January 1966

Hydrogenation of ethylene on supported platinum journal, March 1972

Pt Hollow Nanospheres: Facile Synthesis and Enhanced Electrocatalysts journal, March 2004

Multifunctional Yolk−Shell Nanoparticles: A Potential MRI Contrast and Anticancer Agent journal, September 2008

Kinetic study of ethylene hydrogenation journal, January 1991

Nanoengineering of Inorganic and Hybrid Hollow Spheres by Colloidal Templating journal, November 1998

Particle Size, Particle Size Distribution, and Related Measurements of Supported Metal Catalysts journal, February 1987

Synthesis of Core−Shell PtCo Nanocrystals † journal, July 2003

Preparation of Novel Silica−Cadmium Sulfide Composite Nanoparticles Having Adjustable Void Space by Size-Selective Photoetching journal, January 2003

Formation of Hollow Nanocrystals Through the Nanoscale Kirkendall Effect journal, April 2004

Influences of Initial Particle Size on Preparation of Monodisperse CdS Nanoparticles with Size-Selective Photoetching journal, May 1999

Shape-Controlled Synthesis of Gold and Silver Nanoparticles journal, December 2002

Adsorption of Gases in Multimolecular Layers journal, February 1938

Pt Nanocrystals: Shape Control and Langmuir−Blodgett Monolayer Formation journal, January 2005

Characterization of Ultrasmall CdS Nanoparticles Prepared by the Size-Selective Photoetching Technique journal, July 2001

Ethylene Hydrogenation over Platinum Nanoparticle Array Model Catalysts Fabricated by Electron Beam Lithography: Determination of Active Metal Surface Area journal, November 2002

Synthesis of metal–cadmium sulfide nanocomposites using jingle-bell-shaped core-shell photocatalyst particles journal, July 2005

Synthesis and characterization of molybdate-modified platinum nanoparticles
journal, January 2004

Synthesis of hcp-Co Nanodisks
journal, October 2002

Hydrogenation of ethylene over platinum (111) single-crystal surfaces
journal, April 1984

Controlled porosity by an extreme kirkendall effect
journal, July 1974

Response Factors for Gas Chromatographic Analyses
journal, February 1967

The Determination of Pore Volume and Area Distributions in Porous Substances. I. Computations from Nitrogen Isotherms
journal, January 1951

Characteristic Features of Size-Selective Photoetching of CdS Nanoparticles as a Means of Preparation of Monodisperse Particles
journal, January 1998

Sulphidation of cobalt at high temperatures
journal, May 1998

Slush Baths.
journal, January 1966

Hydrogenation of ethylene on supported platinum
journal, March 1972

Pt Hollow Nanospheres: Facile Synthesis and Enhanced Electrocatalysts
journal, March 2004

Multifunctional Yolk−Shell Nanoparticles: A Potential MRI Contrast and Anticancer Agent
journal, September 2008

Kinetic study of ethylene hydrogenation
journal, January 1991

Nanoengineering of Inorganic and Hybrid Hollow Spheres by Colloidal Templating
journal, November 1998

Particle Size, Particle Size Distribution, and Related Measurements of Supported Metal Catalysts
journal, February 1987

Synthesis of Core−Shell PtCo Nanocrystals ^†
journal, July 2003

Preparation of Novel Silica−Cadmium Sulfide Composite Nanoparticles Having Adjustable Void Space by Size-Selective Photoetching
journal, January 2003

Formation of Hollow Nanocrystals Through the Nanoscale Kirkendall Effect
journal, April 2004

Influences of Initial Particle Size on Preparation of Monodisperse CdS Nanoparticles with Size-Selective Photoetching
journal, May 1999

Shape-Controlled Synthesis of Gold and Silver Nanoparticles
journal, December 2002

Adsorption of Gases in Multimolecular Layers
journal, February 1938

Pt Nanocrystals: Shape Control and Langmuir−Blodgett Monolayer Formation
journal, January 2005

Characterization of Ultrasmall CdS Nanoparticles Prepared by the Size-Selective Photoetching Technique
journal, July 2001

Ethylene Hydrogenation over Platinum Nanoparticle Array Model Catalysts Fabricated by Electron Beam Lithography: Determination of Active Metal Surface Area
journal, November 2002

Synthesis of metal–cadmium sulfide nanocomposites using jingle-bell-shaped core-shell photocatalyst particles
journal, July 2005