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Title: Non-metallocene organometallic complexes and related methods and systems

Abstract

A non-metallocene organometallic complex comprising a tridentate ligand and a metal bonded to a tridentate ligand, wherein two substituted aryl groups in the tridentate ligand are connected to a cyclic group at the ortho position via semi-rigid ring-ring linkages, and selected so to provide the resulting non-metallocene organometallic complex with a C.sub.S geometry, a C.sub.1 geometry, a C.sub.2 geometry or a C.sub.2v geometry. Method for performing olefin polymerization with a non-metallocene organometallic complex as a catalyst, related catalytic systems, tridentate ligand and method for providing a non-metallocene organometallic complex.

Inventors:
 [1];  [2];  [2];  [2]
  1. Berkeley, CA
  2. Pasadena, CA
Issue Date:
Research Org.:
California Institute of Technology (CalTech), Pasadena, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1011404
Patent Number(s):
7847099
Application Number:
11/859,089
Assignee:
OAK
Patent Classifications (CPCs):
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08F - MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
DOE Contract Number:  
FG03-85ER13431
Resource Type:
Patent
Country of Publication:
United States
Language:
English

Citation Formats

Agapie, Theodor, Golisz, Suzanne Rose, Tofan, Daniel, and Bercaw, John E. Non-metallocene organometallic complexes and related methods and systems. United States: N. p., 2010. Web.
Agapie, Theodor, Golisz, Suzanne Rose, Tofan, Daniel, & Bercaw, John E. Non-metallocene organometallic complexes and related methods and systems. United States.
Agapie, Theodor, Golisz, Suzanne Rose, Tofan, Daniel, and Bercaw, John E. Tue . "Non-metallocene organometallic complexes and related methods and systems". United States. https://www.osti.gov/servlets/purl/1011404.
@article{osti_1011404,
title = {Non-metallocene organometallic complexes and related methods and systems},
author = {Agapie, Theodor and Golisz, Suzanne Rose and Tofan, Daniel and Bercaw, John E},
abstractNote = {A non-metallocene organometallic complex comprising a tridentate ligand and a metal bonded to a tridentate ligand, wherein two substituted aryl groups in the tridentate ligand are connected to a cyclic group at the ortho position via semi-rigid ring-ring linkages, and selected so to provide the resulting non-metallocene organometallic complex with a C.sub.S geometry, a C.sub.1 geometry, a C.sub.2 geometry or a C.sub.2v geometry. Method for performing olefin polymerization with a non-metallocene organometallic complex as a catalyst, related catalytic systems, tridentate ligand and method for providing a non-metallocene organometallic complex.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2010},
month = {12}
}

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Works referenced in this record:

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