Metal complex-based electron-transfer mediators in dye-sensitized solar cells
Abstract
This present invention provides a metal-ligand complex and methods for using and preparing the same. In particular, the metal-ligand complex of the present invention is of the formula: L.sub.a-M-X.sub.b where L, M, X, a, and b are those define herein. The metal-ligand complexes of the present invention are useful in a variety of applications including as electron-transfer mediators in dye-sensitized solar cells and related photoelectrochromic devices.
- Inventors:
-
- Fort Collins, CO
- Broomfield, CO
- Ferrara, IT
- Legnago, IT
- Viconovo, IT
- Issue Date:
- Research Org.:
- Colorado State Univ., Fort Collins, CO (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1007908
- Patent Number(s):
- 7019138
- Application Number:
- 10/494,086
- Assignee:
- Colorado State University Research Foundation (Fort Collins, CO); The University of Ferrara (Ferrara, IT)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
C - CHEMISTRY C09 - DYES C09B - ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES {, e.g. PIGMENTS},
- DOE Contract Number:
- FG03-97ER14808
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Elliott, C Michael, Sapp, Shawn A, Bignozzi, Carlo Alberto, Contado, Cristiano, and Caramori, Stefano. Metal complex-based electron-transfer mediators in dye-sensitized solar cells. United States: N. p., 2006.
Web.
Elliott, C Michael, Sapp, Shawn A, Bignozzi, Carlo Alberto, Contado, Cristiano, & Caramori, Stefano. Metal complex-based electron-transfer mediators in dye-sensitized solar cells. United States.
Elliott, C Michael, Sapp, Shawn A, Bignozzi, Carlo Alberto, Contado, Cristiano, and Caramori, Stefano. Tue .
"Metal complex-based electron-transfer mediators in dye-sensitized solar cells". United States. https://www.osti.gov/servlets/purl/1007908.
@article{osti_1007908,
title = {Metal complex-based electron-transfer mediators in dye-sensitized solar cells},
author = {Elliott, C Michael and Sapp, Shawn A and Bignozzi, Carlo Alberto and Contado, Cristiano and Caramori, Stefano},
abstractNote = {This present invention provides a metal-ligand complex and methods for using and preparing the same. In particular, the metal-ligand complex of the present invention is of the formula: L.sub.a-M-X.sub.b where L, M, X, a, and b are those define herein. The metal-ligand complexes of the present invention are useful in a variety of applications including as electron-transfer mediators in dye-sensitized solar cells and related photoelectrochromic devices.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2006},
month = {3}
}
Works referenced in this record:
Substituted Polypyridine Complexes of Cobalt(II/III) as Efficient Electron-Transfer Mediators in Dye-Sensitized Solar Cells
journal, September 2002
- Sapp, Shawn A.; Elliott, C. Michael; Contado, Cristiano
- Journal of the American Chemical Society, Vol. 124, Issue 37
Dual role of para-phenyl substituents in aromatic imine ligand complexes of cobalt and iron
journal, January 1980
- Rao, Joseph M.; Macero, Daniel J.; Hughes, Michael C.
- Inorganica Chimica Acta, Vol. 41
Effects of silver particles on the photovoltaic properties of dye-sensitized TiO2 thin films
journal, April 2000
- Wen, C.; Ishikawa, K.; Kishima, M.
- Solar Energy Materials and Solar Cells, Vol. 61, Issue 4
Solution Redox Couples for Electrochemical Energy Storage
journal, January 1982
- Chen, Yih-Wen D.
- Journal of The Electrochemical Society, Vol. 129, Issue 1