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Title: Composite electrode/electrolyte structure

Abstract

Provided is an electrode fabricated from highly electronically conductive materials such as metals, metal alloys, or electronically conductive ceramics. The electronic conductivity of the electrode substrate is maximized. Onto this electrode in the green state, a green ionic (e.g., electrolyte) film is deposited and the assembly is co-fired at a temperature suitable to fully densify the film while the substrate retains porosity. Subsequently, a catalytic material is added to the electrode structure by infiltration of a metal salt and subsequent low temperature firing. The invention allows for an electrode with high electronic conductivity and sufficient catalytic activity to achieve high power density in ionic (electrochemical) devices such as fuel cells and electrolytic gas separation systems.

Inventors:
 [1];  [2];  [3]
  1. Berkeley, CA
  2. El Cerrito, CA
  3. Lafayette, CA
Issue Date:
Research Org.:
University of California (Oakland, CA)
Sponsoring Org.:
USDOE
OSTI Identifier:
1007485
Patent Number(s):
6682842
Application Number:
09/626,022
Assignee:
The Regents of the University of California (Oakland, CA)
Patent Classifications (CPCs):
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
DOE Contract Number:  
AC03-76SF00098
Resource Type:
Patent
Country of Publication:
United States
Language:
English

Citation Formats

Visco, Steven J, Jacobson, Craig P, and DeJonghe, Lutgard C. Composite electrode/electrolyte structure. United States: N. p., 2004. Web.
Visco, Steven J, Jacobson, Craig P, & DeJonghe, Lutgard C. Composite electrode/electrolyte structure. United States.
Visco, Steven J, Jacobson, Craig P, and DeJonghe, Lutgard C. Tue . "Composite electrode/electrolyte structure". United States. https://www.osti.gov/servlets/purl/1007485.
@article{osti_1007485,
title = {Composite electrode/electrolyte structure},
author = {Visco, Steven J and Jacobson, Craig P and DeJonghe, Lutgard C},
abstractNote = {Provided is an electrode fabricated from highly electronically conductive materials such as metals, metal alloys, or electronically conductive ceramics. The electronic conductivity of the electrode substrate is maximized. Onto this electrode in the green state, a green ionic (e.g., electrolyte) film is deposited and the assembly is co-fired at a temperature suitable to fully densify the film while the substrate retains porosity. Subsequently, a catalytic material is added to the electrode structure by infiltration of a metal salt and subsequent low temperature firing. The invention allows for an electrode with high electronic conductivity and sufficient catalytic activity to achieve high power density in ionic (electrochemical) devices such as fuel cells and electrolytic gas separation systems.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2004},
month = {1}
}

Works referenced in this record:

Improved preparation procedure and properties for a multilayer piezoelectric thick-film actuator
journal, November 1998


High Potential Performance of Tubular Type SOFC Using Metallic System Components
journal, January 1997


Microstructures of Y2O3-Stabilized ZrO2 Electron Beam-Physical Vapor Deposition Coatings on Ni-Base Superalloys
journal, April 1994


Development of Plasma Sprayed Components for a New SOFC Design
journal, January 1997


New Tubular Type SOFC Using Metallic System Components
journal, January 1996


Oxidation-resistant metallic materials
journal, November 1998