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Title: Materials Data on Eu3W(ClO2)3 by Materials Project

Abstract

Eu3W(O2Cl)3 crystallizes in the hexagonal P6_3/m space group. The structure is three-dimensional. Eu3+ is bonded in a 10-coordinate geometry to six equivalent O2- and four equivalent Cl1- atoms. There are a spread of Eu–O bond distances ranging from 2.41–2.66 Å. There are a spread of Eu–Cl bond distances ranging from 2.97–3.05 Å. W6+ is bonded in a distorted pentagonal pyramidal geometry to six equivalent O2- atoms. All W–O bond lengths are 1.95 Å. O2- is bonded to three equivalent Eu3+ and one W6+ atom to form a mixture of distorted edge and corner-sharing OEu3W tetrahedra. Cl1- is bonded in a 4-coordinate geometry to four equivalent Eu3+ atoms.

Authors:
Publication Date:
Other Number(s):
mp-1213105
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Eu3W(ClO2)3; Cl-Eu-O-W
OSTI Identifier:
1758639
DOI:
https://doi.org/10.17188/1758639

Citation Formats

The Materials Project. Materials Data on Eu3W(ClO2)3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1758639.
The Materials Project. Materials Data on Eu3W(ClO2)3 by Materials Project. United States. doi:https://doi.org/10.17188/1758639
The Materials Project. 2020. "Materials Data on Eu3W(ClO2)3 by Materials Project". United States. doi:https://doi.org/10.17188/1758639. https://www.osti.gov/servlets/purl/1758639. Pub date:Thu Sep 03 00:00:00 EDT 2020
@article{osti_1758639,
title = {Materials Data on Eu3W(ClO2)3 by Materials Project},
author = {The Materials Project},
abstractNote = {Eu3W(O2Cl)3 crystallizes in the hexagonal P6_3/m space group. The structure is three-dimensional. Eu3+ is bonded in a 10-coordinate geometry to six equivalent O2- and four equivalent Cl1- atoms. There are a spread of Eu–O bond distances ranging from 2.41–2.66 Å. There are a spread of Eu–Cl bond distances ranging from 2.97–3.05 Å. W6+ is bonded in a distorted pentagonal pyramidal geometry to six equivalent O2- atoms. All W–O bond lengths are 1.95 Å. O2- is bonded to three equivalent Eu3+ and one W6+ atom to form a mixture of distorted edge and corner-sharing OEu3W tetrahedra. Cl1- is bonded in a 4-coordinate geometry to four equivalent Eu3+ atoms.},
doi = {10.17188/1758639},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {9}
}