DOE Data Explorer title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Materials Data on Sr(ClO3)2 by Materials Project

Abstract

Sr(O3Cl)2 crystallizes in the monoclinic C2 space group. The structure is one-dimensional and consists of two Sr(O3Cl)2 ribbons oriented in the (0, 0, 1) direction. Sr is bonded in a 7-coordinate geometry to seven O atoms. There are a spread of Sr–O bond distances ranging from 2.46–2.57 Å. There are four inequivalent O sites. In the first O site, O is bonded in a bent 120 degrees geometry to one O and one Cl atom. The O–O bond length is 1.34 Å. The O–Cl bond length is 1.81 Å. In the second O site, O is bonded in a 3-coordinate geometry to one Sr and two equivalent O atoms. Both O–O bond lengths are 1.80 Å. In the third O site, O is bonded in a distorted T-shaped geometry to two equivalent Sr and one O atom. In the fourth O site, O is bonded in a 4-coordinate geometry to two equivalent Sr and two equivalent O atoms. Cl is bonded in a single-bond geometry to one O atom.

Authors:
Publication Date:
Other Number(s):
mp-1179368
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Sr(ClO3)2; Cl-O-Sr
OSTI Identifier:
1758339
DOI:
https://doi.org/10.17188/1758339

Citation Formats

The Materials Project. Materials Data on Sr(ClO3)2 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1758339.
The Materials Project. Materials Data on Sr(ClO3)2 by Materials Project. United States. doi:https://doi.org/10.17188/1758339
The Materials Project. 2020. "Materials Data on Sr(ClO3)2 by Materials Project". United States. doi:https://doi.org/10.17188/1758339. https://www.osti.gov/servlets/purl/1758339. Pub date:Thu Sep 03 00:00:00 EDT 2020
@article{osti_1758339,
title = {Materials Data on Sr(ClO3)2 by Materials Project},
author = {The Materials Project},
abstractNote = {Sr(O3Cl)2 crystallizes in the monoclinic C2 space group. The structure is one-dimensional and consists of two Sr(O3Cl)2 ribbons oriented in the (0, 0, 1) direction. Sr is bonded in a 7-coordinate geometry to seven O atoms. There are a spread of Sr–O bond distances ranging from 2.46–2.57 Å. There are four inequivalent O sites. In the first O site, O is bonded in a bent 120 degrees geometry to one O and one Cl atom. The O–O bond length is 1.34 Å. The O–Cl bond length is 1.81 Å. In the second O site, O is bonded in a 3-coordinate geometry to one Sr and two equivalent O atoms. Both O–O bond lengths are 1.80 Å. In the third O site, O is bonded in a distorted T-shaped geometry to two equivalent Sr and one O atom. In the fourth O site, O is bonded in a 4-coordinate geometry to two equivalent Sr and two equivalent O atoms. Cl is bonded in a single-bond geometry to one O atom.},
doi = {10.17188/1758339},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {9}
}