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Title: Materials Data on Ce(PPt)2 by Materials Project

Abstract

Ce(PtP)2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Ce3+ is bonded in a 8-coordinate geometry to eight P3- atoms. There are four shorter (3.20 Å) and four longer (3.23 Å) Ce–P bond lengths. There are two inequivalent Pt+1.50+ sites. In the first Pt+1.50+ site, Pt+1.50+ is bonded in a 5-coordinate geometry to five P3- atoms. There are one shorter (2.36 Å) and four longer (2.42 Å) Pt–P bond lengths. In the second Pt+1.50+ site, Pt+1.50+ is bonded in a distorted rectangular see-saw-like geometry to four equivalent P3- atoms. All Pt–P bond lengths are 2.54 Å. There are two inequivalent P3- sites. In the first P3- site, P3- is bonded in a 1-coordinate geometry to four equivalent Ce3+, five Pt+1.50+, and one P3- atom. The P–P bond length is 2.71 Å. In the second P3- site, P3- is bonded in a 8-coordinate geometry to four equivalent Ce3+ and four equivalent Pt+1.50+ atoms.

Publication Date:
Other Number(s):
mp-1205866
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Ce(PPt)2; Ce-P-Pt
OSTI Identifier:
1753733
DOI:
https://doi.org/10.17188/1753733

Citation Formats

The Materials Project. Materials Data on Ce(PPt)2 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1753733.
The Materials Project. Materials Data on Ce(PPt)2 by Materials Project. United States. doi:https://doi.org/10.17188/1753733
The Materials Project. 2020. "Materials Data on Ce(PPt)2 by Materials Project". United States. doi:https://doi.org/10.17188/1753733. https://www.osti.gov/servlets/purl/1753733. Pub date:Sun May 03 00:00:00 EDT 2020
@article{osti_1753733,
title = {Materials Data on Ce(PPt)2 by Materials Project},
author = {The Materials Project},
abstractNote = {Ce(PtP)2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Ce3+ is bonded in a 8-coordinate geometry to eight P3- atoms. There are four shorter (3.20 Å) and four longer (3.23 Å) Ce–P bond lengths. There are two inequivalent Pt+1.50+ sites. In the first Pt+1.50+ site, Pt+1.50+ is bonded in a 5-coordinate geometry to five P3- atoms. There are one shorter (2.36 Å) and four longer (2.42 Å) Pt–P bond lengths. In the second Pt+1.50+ site, Pt+1.50+ is bonded in a distorted rectangular see-saw-like geometry to four equivalent P3- atoms. All Pt–P bond lengths are 2.54 Å. There are two inequivalent P3- sites. In the first P3- site, P3- is bonded in a 1-coordinate geometry to four equivalent Ce3+, five Pt+1.50+, and one P3- atom. The P–P bond length is 2.71 Å. In the second P3- site, P3- is bonded in a 8-coordinate geometry to four equivalent Ce3+ and four equivalent Pt+1.50+ atoms.},
doi = {10.17188/1753733},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}