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Title: Materials Data on HW2C9NO10 by Materials Project

Abstract

W2HW2H(NO)2(CO)18 crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of thirty-six formaldehyde molecules, two W2H clusters, and two W2H(NO)2 clusters. In each W2H cluster, W5+ is bonded in a single-bond geometry to one H1+ atom. The W–H bond length is 1.92 Å. H1+ is bonded in a bent 120 degrees geometry to two equivalent W5+ atoms. In each W2H(NO)2 cluster, W5+ is bonded in a linear geometry to one N3- and one H1+ atom. The W–N bond length is 1.90 Å. The W–H bond length is 1.95 Å. N3- is bonded in a linear geometry to one W5+ and one O2- atom. The N–O bond length is 1.17 Å. H1+ is bonded in a bent 120 degrees geometry to two equivalent W5+ atoms. O2- is bonded in a single-bond geometry to one N3- atom.

Authors:
Publication Date:
Other Number(s):
mp-1224668
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; HW2C9NO10; C-H-N-O-W
OSTI Identifier:
1753592
DOI:
https://doi.org/10.17188/1753592

Citation Formats

The Materials Project. Materials Data on HW2C9NO10 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1753592.
The Materials Project. Materials Data on HW2C9NO10 by Materials Project. United States. doi:https://doi.org/10.17188/1753592
The Materials Project. 2020. "Materials Data on HW2C9NO10 by Materials Project". United States. doi:https://doi.org/10.17188/1753592. https://www.osti.gov/servlets/purl/1753592. Pub date:Fri May 01 00:00:00 EDT 2020
@article{osti_1753592,
title = {Materials Data on HW2C9NO10 by Materials Project},
author = {The Materials Project},
abstractNote = {W2HW2H(NO)2(CO)18 crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of thirty-six formaldehyde molecules, two W2H clusters, and two W2H(NO)2 clusters. In each W2H cluster, W5+ is bonded in a single-bond geometry to one H1+ atom. The W–H bond length is 1.92 Å. H1+ is bonded in a bent 120 degrees geometry to two equivalent W5+ atoms. In each W2H(NO)2 cluster, W5+ is bonded in a linear geometry to one N3- and one H1+ atom. The W–N bond length is 1.90 Å. The W–H bond length is 1.95 Å. N3- is bonded in a linear geometry to one W5+ and one O2- atom. The N–O bond length is 1.17 Å. H1+ is bonded in a bent 120 degrees geometry to two equivalent W5+ atoms. O2- is bonded in a single-bond geometry to one N3- atom.},
doi = {10.17188/1753592},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}