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Title: Materials Data on Co3P by Materials Project

Abstract

Co3P crystallizes in the tetragonal I-4 space group. The structure is three-dimensional. there are three inequivalent Co1+ sites. In the first Co1+ site, Co1+ is bonded in a distorted trigonal non-coplanar geometry to three equivalent P3- atoms. There are a spread of Co–P bond distances ranging from 2.21–2.34 Å. In the second Co1+ site, Co1+ is bonded in a water-like geometry to two equivalent P3- atoms. There are one shorter (2.23 Å) and one longer (2.36 Å) Co–P bond lengths. In the third Co1+ site, Co1+ is bonded to four equivalent P3- atoms to form a mixture of edge and corner-sharing CoP4 tetrahedra. There are a spread of Co–P bond distances ranging from 2.24–2.32 Å. P3- is bonded in a 9-coordinate geometry to nine Co1+ atoms.

Publication Date:
Other Number(s):
mp-1213762
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Co3P; Co-P
OSTI Identifier:
1752903
DOI:
https://doi.org/10.17188/1752903

Citation Formats

The Materials Project. Materials Data on Co3P by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1752903.
The Materials Project. Materials Data on Co3P by Materials Project. United States. doi:https://doi.org/10.17188/1752903
The Materials Project. 2020. "Materials Data on Co3P by Materials Project". United States. doi:https://doi.org/10.17188/1752903. https://www.osti.gov/servlets/purl/1752903. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1752903,
title = {Materials Data on Co3P by Materials Project},
author = {The Materials Project},
abstractNote = {Co3P crystallizes in the tetragonal I-4 space group. The structure is three-dimensional. there are three inequivalent Co1+ sites. In the first Co1+ site, Co1+ is bonded in a distorted trigonal non-coplanar geometry to three equivalent P3- atoms. There are a spread of Co–P bond distances ranging from 2.21–2.34 Å. In the second Co1+ site, Co1+ is bonded in a water-like geometry to two equivalent P3- atoms. There are one shorter (2.23 Å) and one longer (2.36 Å) Co–P bond lengths. In the third Co1+ site, Co1+ is bonded to four equivalent P3- atoms to form a mixture of edge and corner-sharing CoP4 tetrahedra. There are a spread of Co–P bond distances ranging from 2.24–2.32 Å. P3- is bonded in a 9-coordinate geometry to nine Co1+ atoms.},
doi = {10.17188/1752903},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}