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Title: Materials Data on Sb8Cl2O11 by Materials Project

Abstract

Sb8O11Cl2 crystallizes in the triclinic P-1 space group. The structure is two-dimensional and consists of one Sb8O11Cl2 sheet oriented in the (0, 0, 1) direction. there are four inequivalent Sb3+ sites. In the first Sb3+ site, Sb3+ is bonded in a distorted square co-planar geometry to four O2- atoms. There are a spread of Sb–O bond distances ranging from 2.00–2.25 Å. In the second Sb3+ site, Sb3+ is bonded in a 2-coordinate geometry to two O2- and one Cl1- atom. There is one shorter (1.98 Å) and one longer (2.00 Å) Sb–O bond length. The Sb–Cl bond length is 2.55 Å. In the third Sb3+ site, Sb3+ is bonded in a distorted T-shaped geometry to three O2- atoms. There are two shorter (2.00 Å) and one longer (2.01 Å) Sb–O bond lengths. In the fourth Sb3+ site, Sb3+ is bonded in a rectangular see-saw-like geometry to four O2- atoms. There are a spread of Sb–O bond distances ranging from 2.01–2.25 Å. There are six inequivalent O2- sites. In the first O2- site, O2- is bonded in a 3-coordinate geometry to three Sb3+ atoms. In the second O2- site, O2- is bonded in a distorted trigonal non-coplanar geometry to three Sb3+more » atoms. In the third O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two Sb3+ atoms. In the fourth O2- site, O2- is bonded in a bent 120 degrees geometry to two Sb3+ atoms. In the fifth O2- site, O2- is bonded in a linear geometry to two equivalent Sb3+ atoms. In the sixth O2- site, O2- is bonded in a bent 120 degrees geometry to two Sb3+ atoms. Cl1- is bonded in a single-bond geometry to one Sb3+ atom.« less

Authors:
Publication Date:
Other Number(s):
mp-1219592
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Sb8Cl2O11; Cl-O-Sb
OSTI Identifier:
1751888
DOI:
https://doi.org/10.17188/1751888

Citation Formats

The Materials Project. Materials Data on Sb8Cl2O11 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1751888.
The Materials Project. Materials Data on Sb8Cl2O11 by Materials Project. United States. doi:https://doi.org/10.17188/1751888
The Materials Project. 2020. "Materials Data on Sb8Cl2O11 by Materials Project". United States. doi:https://doi.org/10.17188/1751888. https://www.osti.gov/servlets/purl/1751888. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1751888,
title = {Materials Data on Sb8Cl2O11 by Materials Project},
author = {The Materials Project},
abstractNote = {Sb8O11Cl2 crystallizes in the triclinic P-1 space group. The structure is two-dimensional and consists of one Sb8O11Cl2 sheet oriented in the (0, 0, 1) direction. there are four inequivalent Sb3+ sites. In the first Sb3+ site, Sb3+ is bonded in a distorted square co-planar geometry to four O2- atoms. There are a spread of Sb–O bond distances ranging from 2.00–2.25 Å. In the second Sb3+ site, Sb3+ is bonded in a 2-coordinate geometry to two O2- and one Cl1- atom. There is one shorter (1.98 Å) and one longer (2.00 Å) Sb–O bond length. The Sb–Cl bond length is 2.55 Å. In the third Sb3+ site, Sb3+ is bonded in a distorted T-shaped geometry to three O2- atoms. There are two shorter (2.00 Å) and one longer (2.01 Å) Sb–O bond lengths. In the fourth Sb3+ site, Sb3+ is bonded in a rectangular see-saw-like geometry to four O2- atoms. There are a spread of Sb–O bond distances ranging from 2.01–2.25 Å. There are six inequivalent O2- sites. In the first O2- site, O2- is bonded in a 3-coordinate geometry to three Sb3+ atoms. In the second O2- site, O2- is bonded in a distorted trigonal non-coplanar geometry to three Sb3+ atoms. In the third O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two Sb3+ atoms. In the fourth O2- site, O2- is bonded in a bent 120 degrees geometry to two Sb3+ atoms. In the fifth O2- site, O2- is bonded in a linear geometry to two equivalent Sb3+ atoms. In the sixth O2- site, O2- is bonded in a bent 120 degrees geometry to two Sb3+ atoms. Cl1- is bonded in a single-bond geometry to one Sb3+ atom.},
doi = {10.17188/1751888},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}