Materials Data on Ni(NO2)4 by Materials Project
Abstract
Ni(NO2)4 crystallizes in the monoclinic C2/c space group. The structure is two-dimensional and consists of two Ni(NO2)4 sheets oriented in the (1, 0, 0) direction. Ni4+ is bonded in an octahedral geometry to six O2- atoms. There are a spread of Ni–O bond distances ranging from 2.03–2.13 Å. There are two inequivalent N3+ sites. In the first N3+ site, N3+ is bonded in a bent 120 degrees geometry to two O2- atoms. There is one shorter (1.25 Å) and one longer (1.26 Å) N–O bond length. In the second N3+ site, N3+ is bonded in a bent 120 degrees geometry to two O2- atoms. There is one shorter (1.21 Å) and one longer (1.26 Å) N–O bond length. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a bent 120 degrees geometry to one Ni4+ and one N3+ atom. In the second O2- site, O2- is bonded in a bent 120 degrees geometry to one Ni4+ and one N3+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to one N3+ atom. In the fourth O2- site, O2- is bonded in a bent 120 degrees geometry to one Ni4+ andmore »
- Authors:
- Publication Date:
- Other Number(s):
- mp-1210164
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Ni(NO2)4; N-Ni-O
- OSTI Identifier:
- 1750092
- DOI:
- https://doi.org/10.17188/1750092
Citation Formats
The Materials Project. Materials Data on Ni(NO2)4 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1750092.
The Materials Project. Materials Data on Ni(NO2)4 by Materials Project. United States. doi:https://doi.org/10.17188/1750092
The Materials Project. 2020.
"Materials Data on Ni(NO2)4 by Materials Project". United States. doi:https://doi.org/10.17188/1750092. https://www.osti.gov/servlets/purl/1750092. Pub date:Wed Apr 29 00:00:00 EDT 2020
@article{osti_1750092,
title = {Materials Data on Ni(NO2)4 by Materials Project},
author = {The Materials Project},
abstractNote = {Ni(NO2)4 crystallizes in the monoclinic C2/c space group. The structure is two-dimensional and consists of two Ni(NO2)4 sheets oriented in the (1, 0, 0) direction. Ni4+ is bonded in an octahedral geometry to six O2- atoms. There are a spread of Ni–O bond distances ranging from 2.03–2.13 Å. There are two inequivalent N3+ sites. In the first N3+ site, N3+ is bonded in a bent 120 degrees geometry to two O2- atoms. There is one shorter (1.25 Å) and one longer (1.26 Å) N–O bond length. In the second N3+ site, N3+ is bonded in a bent 120 degrees geometry to two O2- atoms. There is one shorter (1.21 Å) and one longer (1.26 Å) N–O bond length. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a bent 120 degrees geometry to one Ni4+ and one N3+ atom. In the second O2- site, O2- is bonded in a bent 120 degrees geometry to one Ni4+ and one N3+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to one N3+ atom. In the fourth O2- site, O2- is bonded in a bent 120 degrees geometry to one Ni4+ and one N3+ atom.},
doi = {10.17188/1750092},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Wed Apr 29 00:00:00 EDT 2020},
month = {Wed Apr 29 00:00:00 EDT 2020}
}