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Title: Materials Data on RhN3Cl6O by Materials Project

Abstract

RhOCl2(NCl)2NCl2 crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight chloramine molecules, four dichloramine molecules, and four RhOCl2 clusters. In each RhOCl2 cluster, Rh3+ is bonded in a trigonal planar geometry to one O2- and two equivalent Cl1- atoms. The Rh–O bond length is 1.69 Å. Both Rh–Cl bond lengths are 2.19 Å. O2- is bonded in a single-bond geometry to one Rh3+ atom. Cl1- is bonded in a single-bond geometry to one Rh3+ atom.

Publication Date:
Other Number(s):
mp-1199378
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; RhN3Cl6O; Cl-N-O-Rh
OSTI Identifier:
1749690
DOI:
https://doi.org/10.17188/1749690

Citation Formats

The Materials Project. Materials Data on RhN3Cl6O by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1749690.
The Materials Project. Materials Data on RhN3Cl6O by Materials Project. United States. doi:https://doi.org/10.17188/1749690
The Materials Project. 2020. "Materials Data on RhN3Cl6O by Materials Project". United States. doi:https://doi.org/10.17188/1749690. https://www.osti.gov/servlets/purl/1749690. Pub date:Wed Apr 29 00:00:00 EDT 2020
@article{osti_1749690,
title = {Materials Data on RhN3Cl6O by Materials Project},
author = {The Materials Project},
abstractNote = {RhOCl2(NCl)2NCl2 crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight chloramine molecules, four dichloramine molecules, and four RhOCl2 clusters. In each RhOCl2 cluster, Rh3+ is bonded in a trigonal planar geometry to one O2- and two equivalent Cl1- atoms. The Rh–O bond length is 1.69 Å. Both Rh–Cl bond lengths are 2.19 Å. O2- is bonded in a single-bond geometry to one Rh3+ atom. Cl1- is bonded in a single-bond geometry to one Rh3+ atom.},
doi = {10.17188/1749690},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}