Materials Data on OsPt(N2Cl3)2 by Materials Project

doi:10.17188/1749043

Title: Materials Data on OsPt(N2Cl3)2 by Materials Project

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Abstract

OsPt(N2Cl3)2 crystallizes in the orthorhombic Cmce space group. The structure is one-dimensional and consists of four OsPt(N2Cl3)2 ribbons oriented in the (0, 0, 1) direction. Os4+ is bonded in an octahedral geometry to six Cl1- atoms. There are four shorter (2.32 Å) and two longer (2.34 Å) Os–Cl bond lengths. Pt6+ is bonded in a square co-planar geometry to four equivalent N1- atoms. All Pt–N bond lengths are 1.94 Å. N1- is bonded in a distorted L-shaped geometry to one Pt6+ and one Cl1- atom. The N–Cl bond length is 1.76 Å. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a trigonal non-coplanar geometry to one Os4+ and two equivalent N1- atoms. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Os4+ atom.

Authors:: The Materials Project

Publication Date:: Sun May 03 00:00:00 EDT 2020

Other Number(s):: mp-1192649

DOE Contract Number:: AC02-05CH11231; EDCBEE

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Collaborations:: MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE

Keywords:: crystal structure; OsPt(N2Cl3)2; Cl-N-Os-Pt

OSTI Identifier:: 1749043

DOI:: https://doi.org/10.17188/1749043

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                    The Materials Project. Materials Data on OsPt(N2Cl3)2 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1749043.

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                    The Materials Project. Materials Data on OsPt(N2Cl3)2 by Materials Project.  United States.  doi:https://doi.org/10.17188/1749043

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                    The Materials Project. 2020.  
"Materials Data on OsPt(N2Cl3)2 by Materials Project".  United States.  doi:https://doi.org/10.17188/1749043.  https://www.osti.gov/servlets/purl/1749043. Pub date:Sun May 03 00:00:00 EDT 2020

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@article{osti_1749043,

  title        = {Materials Data on OsPt(N2Cl3)2 by Materials Project},

  author       = {The Materials Project},

  abstractNote = {OsPt(N2Cl3)2 crystallizes in the orthorhombic Cmce space group. The structure is one-dimensional and consists of four OsPt(N2Cl3)2 ribbons oriented in the (0, 0, 1) direction. Os4+ is bonded in an octahedral geometry to six Cl1- atoms. There are four shorter (2.32 Å) and two longer (2.34 Å) Os–Cl bond lengths. Pt6+ is bonded in a square co-planar geometry to four equivalent N1- atoms. All Pt–N bond lengths are 1.94 Å. N1- is bonded in a distorted L-shaped geometry to one Pt6+ and one Cl1- atom. The N–Cl bond length is 1.76 Å. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a trigonal non-coplanar geometry to one Os4+ and two equivalent N1- atoms. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Os4+ atom.},

  doi          = {10.17188/1749043},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {Sun May 03 00:00:00 EDT 2020},

  month        = {Sun May 03 00:00:00 EDT 2020}

}

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DOI: https://doi.org/10.17188/1749043

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