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Title: Materials Data on MnN2F5 by Materials Project

Abstract

(MnF3)2N2(NF2)2 crystallizes in the orthorhombic Pnma space group. The structure is one-dimensional and consists of four ammonia molecules; four difluoroamine molecules; and two MnF3 ribbons oriented in the (0, 1, 0) direction. In each MnF3 ribbon, Mn3+ is bonded in a distorted square co-planar geometry to four F1- atoms. There is two shorter (1.80 Å) and two longer (1.93 Å) Mn–F bond length. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Mn3+ atom. In the second F1- site, F1- is bonded in a bent 150 degrees geometry to two equivalent Mn3+ atoms.

Authors:
Publication Date:
Other Number(s):
mp-1202287
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; MnN2F5; F-Mn-N
OSTI Identifier:
1747863
DOI:
https://doi.org/10.17188/1747863

Citation Formats

The Materials Project. Materials Data on MnN2F5 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1747863.
The Materials Project. Materials Data on MnN2F5 by Materials Project. United States. doi:https://doi.org/10.17188/1747863
The Materials Project. 2020. "Materials Data on MnN2F5 by Materials Project". United States. doi:https://doi.org/10.17188/1747863. https://www.osti.gov/servlets/purl/1747863. Pub date:Sun May 03 00:00:00 EDT 2020
@article{osti_1747863,
title = {Materials Data on MnN2F5 by Materials Project},
author = {The Materials Project},
abstractNote = {(MnF3)2N2(NF2)2 crystallizes in the orthorhombic Pnma space group. The structure is one-dimensional and consists of four ammonia molecules; four difluoroamine molecules; and two MnF3 ribbons oriented in the (0, 1, 0) direction. In each MnF3 ribbon, Mn3+ is bonded in a distorted square co-planar geometry to four F1- atoms. There is two shorter (1.80 Å) and two longer (1.93 Å) Mn–F bond length. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Mn3+ atom. In the second F1- site, F1- is bonded in a bent 150 degrees geometry to two equivalent Mn3+ atoms.},
doi = {10.17188/1747863},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}