U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on HgP2(PdO4)2 by Materials Project
Abstract
HgP2(PdO4)2 crystallizes in the orthorhombic Fddd space group. The structure is three-dimensional. Pd2+ is bonded in a square co-planar geometry to four O2- atoms. There are two shorter (2.05 Å) and two longer (2.06 Å) Pd–O bond lengths. Hg2+ is bonded in a 8-coordinate geometry to eight O2- atoms. There are four shorter (2.38 Å) and four longer (2.70 Å) Hg–O bond lengths. P5+ is bonded in a tetrahedral geometry to four O2- atoms. There is two shorter (1.55 Å) and two longer (1.57 Å) P–O bond length. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a 1-coordinate geometry to one Pd2+, one Hg2+, and one P5+ atom. In the second O2- site, O2- is bonded in a distorted trigonal planar geometry to one Pd2+, one Hg2+, and one P5+ atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-1192405
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; HgP2(PdO4)2; Hg-O-P-Pd
- OSTI Identifier:
- 1747854
- DOI:
- https://doi.org/10.17188/1747854
Citation Formats
The Materials Project. Materials Data on HgP2(PdO4)2 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1747854.
The Materials Project. Materials Data on HgP2(PdO4)2 by Materials Project. United States. doi:https://doi.org/10.17188/1747854
The Materials Project. 2020.
"Materials Data on HgP2(PdO4)2 by Materials Project". United States. doi:https://doi.org/10.17188/1747854. https://www.osti.gov/servlets/purl/1747854. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1747854,
title = {Materials Data on HgP2(PdO4)2 by Materials Project},
author = {The Materials Project},
abstractNote = {HgP2(PdO4)2 crystallizes in the orthorhombic Fddd space group. The structure is three-dimensional. Pd2+ is bonded in a square co-planar geometry to four O2- atoms. There are two shorter (2.05 Å) and two longer (2.06 Å) Pd–O bond lengths. Hg2+ is bonded in a 8-coordinate geometry to eight O2- atoms. There are four shorter (2.38 Å) and four longer (2.70 Å) Hg–O bond lengths. P5+ is bonded in a tetrahedral geometry to four O2- atoms. There is two shorter (1.55 Å) and two longer (1.57 Å) P–O bond length. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a 1-coordinate geometry to one Pd2+, one Hg2+, and one P5+ atom. In the second O2- site, O2- is bonded in a distorted trigonal planar geometry to one Pd2+, one Hg2+, and one P5+ atom.},
doi = {10.17188/1747854},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat May 02 00:00:00 EDT 2020},
month = {Sat May 02 00:00:00 EDT 2020}
}