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Title: Materials Data on AlCdCl4 by Materials Project

Abstract

CdAlCl4 crystallizes in the triclinic P-1 space group. The structure is two-dimensional and consists of two CdAlCl4 sheets oriented in the (0, 0, 1) direction. Cd is bonded in a distorted rectangular see-saw-like geometry to three Cl atoms. There are two shorter (2.76 Å) and one longer (2.79 Å) Cd–Cl bond lengths. Al is bonded in a tetrahedral geometry to four Cl atoms. There are one shorter (2.11 Å) and three longer (2.18 Å) Al–Cl bond lengths. There are four inequivalent Cl sites. In the first Cl site, Cl is bonded in a water-like geometry to one Cd and one Al atom. In the second Cl site, Cl is bonded in a water-like geometry to one Cd and one Al atom. In the third Cl site, Cl is bonded in a single-bond geometry to one Al atom. In the fourth Cl site, Cl is bonded in a water-like geometry to one Cd and one Al atom.

Publication Date:
Other Number(s):
mp-1102961
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; AlCdCl4; Al-Cd-Cl
OSTI Identifier:
1746763
DOI:
https://doi.org/10.17188/1746763

Citation Formats

The Materials Project. Materials Data on AlCdCl4 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1746763.
The Materials Project. Materials Data on AlCdCl4 by Materials Project. United States. doi:https://doi.org/10.17188/1746763
The Materials Project. 2020. "Materials Data on AlCdCl4 by Materials Project". United States. doi:https://doi.org/10.17188/1746763. https://www.osti.gov/servlets/purl/1746763. Pub date:Sat May 09 00:00:00 EDT 2020
@article{osti_1746763,
title = {Materials Data on AlCdCl4 by Materials Project},
author = {The Materials Project},
abstractNote = {CdAlCl4 crystallizes in the triclinic P-1 space group. The structure is two-dimensional and consists of two CdAlCl4 sheets oriented in the (0, 0, 1) direction. Cd is bonded in a distorted rectangular see-saw-like geometry to three Cl atoms. There are two shorter (2.76 Å) and one longer (2.79 Å) Cd–Cl bond lengths. Al is bonded in a tetrahedral geometry to four Cl atoms. There are one shorter (2.11 Å) and three longer (2.18 Å) Al–Cl bond lengths. There are four inequivalent Cl sites. In the first Cl site, Cl is bonded in a water-like geometry to one Cd and one Al atom. In the second Cl site, Cl is bonded in a water-like geometry to one Cd and one Al atom. In the third Cl site, Cl is bonded in a single-bond geometry to one Al atom. In the fourth Cl site, Cl is bonded in a water-like geometry to one Cd and one Al atom.},
doi = {10.17188/1746763},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}