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Title: Materials Data on CuH14C4(NO2)4 by Materials Project

Abstract

Cu(HCOO)2(CO(NH2)2)2(H2O)2 crystallizes in the monoclinic P2_1/c space group. The structure is two-dimensional and consists of four hydrazinocarbinol molecules; four water molecules; and one Cu(HCOO)2 sheet oriented in the (0, 0, 1) direction. In the Cu(HCOO)2 sheet, Cu2+ is bonded in a distorted square co-planar geometry to four O2- atoms. There is two shorter (1.98 Å) and two longer (2.00 Å) Cu–O bond length. C3+ is bonded in a trigonal planar geometry to one H1+ and two O2- atoms. The C–H bond length is 1.10 Å. There is one shorter (1.27 Å) and one longer (1.28 Å) C–O bond length. H1+ is bonded in a single-bond geometry to one C3+ atom. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Cu2+ and one C3+ atom. In the second O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Cu2+ and one C3+ atom.

Publication Date:
Other Number(s):
mp-1181627
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; CuH14C4(NO2)4; C-Cu-H-N-O
OSTI Identifier:
1744479
DOI:
https://doi.org/10.17188/1744479

Citation Formats

The Materials Project. Materials Data on CuH14C4(NO2)4 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1744479.
The Materials Project. Materials Data on CuH14C4(NO2)4 by Materials Project. United States. doi:https://doi.org/10.17188/1744479
The Materials Project. 2020. "Materials Data on CuH14C4(NO2)4 by Materials Project". United States. doi:https://doi.org/10.17188/1744479. https://www.osti.gov/servlets/purl/1744479. Pub date:Wed Apr 29 00:00:00 EDT 2020
@article{osti_1744479,
title = {Materials Data on CuH14C4(NO2)4 by Materials Project},
author = {The Materials Project},
abstractNote = {Cu(HCOO)2(CO(NH2)2)2(H2O)2 crystallizes in the monoclinic P2_1/c space group. The structure is two-dimensional and consists of four hydrazinocarbinol molecules; four water molecules; and one Cu(HCOO)2 sheet oriented in the (0, 0, 1) direction. In the Cu(HCOO)2 sheet, Cu2+ is bonded in a distorted square co-planar geometry to four O2- atoms. There is two shorter (1.98 Å) and two longer (2.00 Å) Cu–O bond length. C3+ is bonded in a trigonal planar geometry to one H1+ and two O2- atoms. The C–H bond length is 1.10 Å. There is one shorter (1.27 Å) and one longer (1.28 Å) C–O bond length. H1+ is bonded in a single-bond geometry to one C3+ atom. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Cu2+ and one C3+ atom. In the second O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Cu2+ and one C3+ atom.},
doi = {10.17188/1744479},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}