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Title: Materials Data on CeNi2N17O24 by Materials Project

Abstract

(Ni)4(Ce(NO2)12)2(N2)5 crystallizes in the cubic Pn-3 space group. The structure is zero-dimensional and consists of ten ammonia molecules, four nickel molecules, and two Ce(NO2)12 clusters. In each Ce(NO2)12 cluster, Ce3+ is bonded in a cuboctahedral geometry to twelve equivalent O2- atoms. All Ce–O bond lengths are 2.68 Å. N+2.18+ is bonded in a bent 120 degrees geometry to two O2- atoms. There is one shorter (1.22 Å) and one longer (1.26 Å) N–O bond length. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to one Ce3+ and one N+2.18+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to one N+2.18+ atom.

Authors:
Publication Date:
Other Number(s):
mp-1196766
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; CeNi2N17O24; Ce-N-Ni-O
OSTI Identifier:
1744154
DOI:
https://doi.org/10.17188/1744154

Citation Formats

The Materials Project. Materials Data on CeNi2N17O24 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1744154.
The Materials Project. Materials Data on CeNi2N17O24 by Materials Project. United States. doi:https://doi.org/10.17188/1744154
The Materials Project. 2020. "Materials Data on CeNi2N17O24 by Materials Project". United States. doi:https://doi.org/10.17188/1744154. https://www.osti.gov/servlets/purl/1744154. Pub date:Thu Apr 30 00:00:00 EDT 2020
@article{osti_1744154,
title = {Materials Data on CeNi2N17O24 by Materials Project},
author = {The Materials Project},
abstractNote = {(Ni)4(Ce(NO2)12)2(N2)5 crystallizes in the cubic Pn-3 space group. The structure is zero-dimensional and consists of ten ammonia molecules, four nickel molecules, and two Ce(NO2)12 clusters. In each Ce(NO2)12 cluster, Ce3+ is bonded in a cuboctahedral geometry to twelve equivalent O2- atoms. All Ce–O bond lengths are 2.68 Å. N+2.18+ is bonded in a bent 120 degrees geometry to two O2- atoms. There is one shorter (1.22 Å) and one longer (1.26 Å) N–O bond length. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to one Ce3+ and one N+2.18+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to one N+2.18+ atom.},
doi = {10.17188/1744154},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}