U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Pb(CO)4 by Materials Project
Abstract
(C)2PbC2O4 crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional and consists of four ethyne molecules and one PbC2O4 framework. In the PbC2O4 framework, Pb2+ is bonded to eight equivalent O2- atoms to form distorted edge-sharing PbO8 hexagonal bipyramids. There are four shorter (2.62 Å) and four longer (2.74 Å) Pb–O bond lengths. C+1.50+ is bonded in a bent 120 degrees geometry to two equivalent O2- atoms. Both C–O bond lengths are 1.27 Å. O2- is bonded in a distorted single-bond geometry to two equivalent Pb2+ and one C+1.50+ atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-1179835
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Pb(CO)4; C-O-Pb
- OSTI Identifier:
- 1744092
- DOI:
- https://doi.org/10.17188/1744092
Citation Formats
The Materials Project. Materials Data on Pb(CO)4 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1744092.
The Materials Project. Materials Data on Pb(CO)4 by Materials Project. United States. doi:https://doi.org/10.17188/1744092
The Materials Project. 2020.
"Materials Data on Pb(CO)4 by Materials Project". United States. doi:https://doi.org/10.17188/1744092. https://www.osti.gov/servlets/purl/1744092. Pub date:Sun May 03 00:00:00 EDT 2020
@article{osti_1744092,
title = {Materials Data on Pb(CO)4 by Materials Project},
author = {The Materials Project},
abstractNote = {(C)2PbC2O4 crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional and consists of four ethyne molecules and one PbC2O4 framework. In the PbC2O4 framework, Pb2+ is bonded to eight equivalent O2- atoms to form distorted edge-sharing PbO8 hexagonal bipyramids. There are four shorter (2.62 Å) and four longer (2.74 Å) Pb–O bond lengths. C+1.50+ is bonded in a bent 120 degrees geometry to two equivalent O2- atoms. Both C–O bond lengths are 1.27 Å. O2- is bonded in a distorted single-bond geometry to two equivalent Pb2+ and one C+1.50+ atom.},
doi = {10.17188/1744092},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sun May 03 00:00:00 EDT 2020},
month = {Sun May 03 00:00:00 EDT 2020}
}
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