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Title: Materials Data on Pb(CO)4 by Materials Project

Abstract

(C)2PbC2O4 crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional and consists of four ethyne molecules and one PbC2O4 framework. In the PbC2O4 framework, Pb2+ is bonded to eight equivalent O2- atoms to form distorted edge-sharing PbO8 hexagonal bipyramids. There are four shorter (2.62 Å) and four longer (2.74 Å) Pb–O bond lengths. C+1.50+ is bonded in a bent 120 degrees geometry to two equivalent O2- atoms. Both C–O bond lengths are 1.27 Å. O2- is bonded in a distorted single-bond geometry to two equivalent Pb2+ and one C+1.50+ atom.

Publication Date:
Other Number(s):
mp-1179835
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Pb(CO)4; C-O-Pb
OSTI Identifier:
1744092
DOI:
https://doi.org/10.17188/1744092

Citation Formats

The Materials Project. Materials Data on Pb(CO)4 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1744092.
The Materials Project. Materials Data on Pb(CO)4 by Materials Project. United States. doi:https://doi.org/10.17188/1744092
The Materials Project. 2020. "Materials Data on Pb(CO)4 by Materials Project". United States. doi:https://doi.org/10.17188/1744092. https://www.osti.gov/servlets/purl/1744092. Pub date:Sun May 03 00:00:00 EDT 2020
@article{osti_1744092,
title = {Materials Data on Pb(CO)4 by Materials Project},
author = {The Materials Project},
abstractNote = {(C)2PbC2O4 crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional and consists of four ethyne molecules and one PbC2O4 framework. In the PbC2O4 framework, Pb2+ is bonded to eight equivalent O2- atoms to form distorted edge-sharing PbO8 hexagonal bipyramids. There are four shorter (2.62 Å) and four longer (2.74 Å) Pb–O bond lengths. C+1.50+ is bonded in a bent 120 degrees geometry to two equivalent O2- atoms. Both C–O bond lengths are 1.27 Å. O2- is bonded in a distorted single-bond geometry to two equivalent Pb2+ and one C+1.50+ atom.},
doi = {10.17188/1744092},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}