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Title: Materials Data on TlTcO2 by Materials Project

Abstract

TcTlO2 crystallizes in the tetragonal I4_1/a space group. The structure is three-dimensional. Tc3+ is bonded in a distorted rectangular see-saw-like geometry to four equivalent O2- atoms. There are two shorter (2.06 Å) and two longer (2.07 Å) Tc–O bond lengths. Tl1+ is bonded to six equivalent O2- atoms to form edge-sharing TlO6 octahedra. There are a spread of Tl–O bond distances ranging from 2.67–3.03 Å. O2- is bonded in a 5-coordinate geometry to two equivalent Tc3+ and three equivalent Tl1+ atoms.

Authors:
Publication Date:
Other Number(s):
mp-1208055
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; TlTcO2; O-Tc-Tl
OSTI Identifier:
1740918
DOI:
https://doi.org/10.17188/1740918

Citation Formats

The Materials Project. Materials Data on TlTcO2 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1740918.
The Materials Project. Materials Data on TlTcO2 by Materials Project. United States. doi:https://doi.org/10.17188/1740918
The Materials Project. 2020. "Materials Data on TlTcO2 by Materials Project". United States. doi:https://doi.org/10.17188/1740918. https://www.osti.gov/servlets/purl/1740918. Pub date:Wed Apr 29 00:00:00 EDT 2020
@article{osti_1740918,
title = {Materials Data on TlTcO2 by Materials Project},
author = {The Materials Project},
abstractNote = {TcTlO2 crystallizes in the tetragonal I4_1/a space group. The structure is three-dimensional. Tc3+ is bonded in a distorted rectangular see-saw-like geometry to four equivalent O2- atoms. There are two shorter (2.06 Å) and two longer (2.07 Å) Tc–O bond lengths. Tl1+ is bonded to six equivalent O2- atoms to form edge-sharing TlO6 octahedra. There are a spread of Tl–O bond distances ranging from 2.67–3.03 Å. O2- is bonded in a 5-coordinate geometry to two equivalent Tc3+ and three equivalent Tl1+ atoms.},
doi = {10.17188/1740918},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}