U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on SbHC2O5 by Materials Project
Abstract
Sb(COO)2(OH) crystallizes in the orthorhombic P2_12_12_1 space group. The structure is three-dimensional. there are two inequivalent C3+ sites. In the first C3+ site, C3+ is bonded in a bent 120 degrees geometry to two O2- atoms. There is one shorter (1.26 Å) and one longer (1.28 Å) C–O bond length. In the second C3+ site, C3+ is bonded in a bent 120 degrees geometry to two O2- atoms. There is one shorter (1.26 Å) and one longer (1.29 Å) C–O bond length. Sb3+ is bonded to six O2- atoms to form distorted corner-sharing SbO6 pentagonal pyramids. There are a spread of Sb–O bond distances ranging from 2.02–2.49 Å. H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.99 Å. There are five inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to one C3+ and one Sb3+ atom. In the second O2- site, O2- is bonded in a distorted single-bond geometry to one C3+ and one Sb3+ atom. In the third O2- site, O2- is bonded in a distorted single-bond geometry to one C3+ and one Sb3+ atom. In the fourth O2- site, O2- is bondedmore »
- Publication Date:
- Other Number(s):
- mp-1219550
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; C-H-O-Sb; SbHC2O5; crystal structure
- OSTI Identifier:
- 1740382
- DOI:
- https://doi.org/10.17188/1740382
Citation Formats
Materials Data on SbHC2O5 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1740382.
Materials Data on SbHC2O5 by Materials Project. United States. doi:https://doi.org/10.17188/1740382
2020.
"Materials Data on SbHC2O5 by Materials Project". United States. doi:https://doi.org/10.17188/1740382. https://www.osti.gov/servlets/purl/1740382. Pub date:Thu Apr 30 00:00:00 EDT 2020
@article{osti_1740382,
title = {Materials Data on SbHC2O5 by Materials Project},
abstractNote = {Sb(COO)2(OH) crystallizes in the orthorhombic P2_12_12_1 space group. The structure is three-dimensional. there are two inequivalent C3+ sites. In the first C3+ site, C3+ is bonded in a bent 120 degrees geometry to two O2- atoms. There is one shorter (1.26 Å) and one longer (1.28 Å) C–O bond length. In the second C3+ site, C3+ is bonded in a bent 120 degrees geometry to two O2- atoms. There is one shorter (1.26 Å) and one longer (1.29 Å) C–O bond length. Sb3+ is bonded to six O2- atoms to form distorted corner-sharing SbO6 pentagonal pyramids. There are a spread of Sb–O bond distances ranging from 2.02–2.49 Å. H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.99 Å. There are five inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to one C3+ and one Sb3+ atom. In the second O2- site, O2- is bonded in a distorted single-bond geometry to one C3+ and one Sb3+ atom. In the third O2- site, O2- is bonded in a distorted single-bond geometry to one C3+ and one Sb3+ atom. In the fourth O2- site, O2- is bonded in a distorted single-bond geometry to two equivalent Sb3+ and one H1+ atom. In the fifth O2- site, O2- is bonded in a distorted single-bond geometry to one C3+ and one Sb3+ atom.},
doi = {10.17188/1740382},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}