Materials Data on Ce3W(ClO2)3 by Materials Project
Abstract
Ce3W(O2Cl)3 crystallizes in the hexagonal P6_3/m space group. The structure is three-dimensional. Ce3+ is bonded in a 10-coordinate geometry to six equivalent O2- and four equivalent Cl1- atoms. There are a spread of Ce–O bond distances ranging from 2.35–2.63 Å. There are a spread of Ce–Cl bond distances ranging from 3.00–3.07 Å. W6+ is bonded in a distorted pentagonal pyramidal geometry to six equivalent O2- atoms. All W–O bond lengths are 2.01 Å. O2- is bonded to three equivalent Ce3+ and one W6+ atom to form a mixture of distorted edge and corner-sharing OCe3W tetrahedra. Cl1- is bonded in a 4-coordinate geometry to four equivalent Ce3+ atoms.
- Authors:
- Publication Date:
- Other Number(s):
- mp-1213830
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Ce3W(ClO2)3; Ce-Cl-O-W
- OSTI Identifier:
- 1740345
- DOI:
- https://doi.org/10.17188/1740345
Citation Formats
The Materials Project. Materials Data on Ce3W(ClO2)3 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1740345.
The Materials Project. Materials Data on Ce3W(ClO2)3 by Materials Project. United States. doi:https://doi.org/10.17188/1740345
The Materials Project. 2020.
"Materials Data on Ce3W(ClO2)3 by Materials Project". United States. doi:https://doi.org/10.17188/1740345. https://www.osti.gov/servlets/purl/1740345. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1740345,
title = {Materials Data on Ce3W(ClO2)3 by Materials Project},
author = {The Materials Project},
abstractNote = {Ce3W(O2Cl)3 crystallizes in the hexagonal P6_3/m space group. The structure is three-dimensional. Ce3+ is bonded in a 10-coordinate geometry to six equivalent O2- and four equivalent Cl1- atoms. There are a spread of Ce–O bond distances ranging from 2.35–2.63 Å. There are a spread of Ce–Cl bond distances ranging from 3.00–3.07 Å. W6+ is bonded in a distorted pentagonal pyramidal geometry to six equivalent O2- atoms. All W–O bond lengths are 2.01 Å. O2- is bonded to three equivalent Ce3+ and one W6+ atom to form a mixture of distorted edge and corner-sharing OCe3W tetrahedra. Cl1- is bonded in a 4-coordinate geometry to four equivalent Ce3+ atoms.},
doi = {10.17188/1740345},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}
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